固相缩聚共聚酯的熔融行为和结晶速率研究

通过固相缩聚合成了两种不同结构的高分子量共聚酯，研究了样品的熔融行为和结晶速率。研究发现，共聚酯的熔融峰随着固相聚合温度和时间的变化而与纯ＰＥＴ有明显的差别，共聚酯泊结晶速率与慢于纯ＰＥＴ的结晶速率。     

织物弹道贯穿性能分析计算

纤维织物增强复合材料由于轻质和高冲击损伤容限而在防弹装甲设计及制造中逐渐得到应用,如人体防弹衣和车辆防护装甲。但是尚无较好的方法直接计算复合材料防弹特性,其中困难在于复合材料弹道冲击过程中的应变率效应和冲击破坏机理至今没有被揭示。解决问题的第一步是建立复合材料增强相(即织物)防弹特性计算方法。提出基于纤维力学性质应变率效应的织物弹道冲击破坏分析模型,计算不同面密度织物靶体在弹道贯穿过程中的弹体剩余速度,由此反映靶体防弹特性。用本文中提出的简单算法预测的结果与实测结果在靶体厚度不大时极为接近,而且也有可能将其扩展到纤维织物增强复合材料防弹性质的计算。     

涡轮钻具在高陡构造的应用及展望

介绍了涡轮钻具在秋参1井的应用情况,详细叙述了涡轮钻具在山前高陡构造快速钻进及防斜打直方面的优点,与常规钻井相比,机械钻速明显提高,钻井周期明显缩短,钻井成本明显下降,经济效益显著。     

国产延迟树脂在腈纶溶剂NaSCN除杂装置的应用

叙述了国产的延迟树脂与进口DOWEX-11-A8树脂在腈纶厂NaSCN回收模拟装置上的比较试验,由试验数据可得出;国产的延迟树脂NVI脱除率性能略优于美国DOWEX-11-A8树脂,并可替代DOWEX-11-A8树脂应用于腈纶厂延迟装置中。     

内循环好氧三相流化床处理造纸中段废水

本实验采用内循环好氧三相流化床处造纸中段废水，经过一段时间的驯化，获得了稳定的出水。CDO去除经保持在65％以上，系统对进水污染负荷的变化具有较大的承受能力。出水Cl^-的浓度有所增加，说明驯化后的微生物可能对有抽氯化物具有一定的降解作用。水气比在1／120至1／140之间可获得最好的COD去除效果。后进行絮凝处理后，出水COD降为60－80mg/L,BODo 50-60/L，色度为100－150CU，挥发性酚的质量浓度小于0．0265mg／L。     

提高自蔓延高温合成陶瓷内衬钢管性能的研究

在概括了自蔓延高温合成陶瓷内衬钢管的制备原理基础上，从降低陶瓷层孔隙率，减少陶瓷层裂纹和提高陶瓷层结合强度等方面，论述了提高自蔓延高温合成陶瓷内衬钢管性能的措施，对自蔓延高温合成陶瓷内衬钢管的应用现状及展望进行了评述。     

氧化铝生产过程结疤溶解的研究

针对氧化铝生产过程结疤现象。研制出一种新型清洗溶剂，溶垢率可达95%，清洗效果达到《工业设备化学清洗质量标准》要求。     

NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar

Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H₂/CO₂/Ar have been numerically simulated with detailed chemistry. The combination of H₂, CO₂ and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO₂. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO₂, N₂O and Fenimore are taken into account to separately evaluate the effects of CO₂ addition on NO emission characteristics. The increase of added CO₂ quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO₂ produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N₂O and NO₂ mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO₂ quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd.     

Nondestructive evaluation of the characteristics of degraded materials using backward radiated ultrasound

The frequency dependency of Rayleigh surface wave is investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in two kinds of degraded specimens by scuffing or corrosion. Then, the frequency dependency is compared with the residual stress distribution or the corrosion-fatigue characteristics for the scuffed or corroded specimens, respectively. The width of the backward radiation profile increases with the increase of the variation in residual stress distribution for the scuffed specimens. In the corroded specimens, the profile width decreases with the increase of the effective aging layer thickness and is inversely proportional to the exponent, m, in the Paris’ law that can predict the crack size increase due to fatigue. The result observed in this study demonstrates high potential of backward radiated ultrasound as a tool for nondestructive evaluation of subsurface gradient of material degradation generated by scuffing or corrosion.     

屏蔽人体模型对电磁波吸收的数值模拟研究

本文用时域有限差分法计算了三类电磁特性不同的材料屏蔽下三层无限长椭圆柱人体模型对电磁波的吸收。结果表明 ,功率密度相同 ,频率在 0 .2～ 6GHz之间的平面电磁波照射下 ,模型吸收的能量、能量在体内的分布及两者对入射电磁波频率的敏感程度严重地受到外加屏蔽的影响。考察了屏蔽材料的电磁特性与其屏蔽效能之间的关系。三类材料的比较显示 ,对人体电磁辐射防护 ,耗散材料优于非耗散材料 ,导电材料优于非导电材料。