印制板蚀刻、微蚀刻废液的再生和铜回收的技术及设备

传统的印制板蚀刻废液处理方法存在着工艺落后、操作不便、二次污染、效益不高等问题,本工艺采用特殊的萃取电解、吸附电解技术,使蚀刻废液得以再生循环利用,铜得以100%回收,低含铜废水铜得到98%回收,整个系统不产生二次污染,获得的铜为高纯度铜板,在实现污染控制的同时,废液废水得到了资源化利用。     

草酸二甲酯加氢合成乙二醇反应的研究

在微型管式反应器中,采用Cu/SiO2催化剂,在温度190～210℃、压力1～3MPa、草酸二甲酯(DMO)与氢气的摩尔比(氢酯比)40～120、DMO空速6.0～25.0mmol/(g.h)的条件下,对DMO加氢制乙二醇的反应进行了研究。实验结果表明,高温、高压、高氢酯比和低DMO空速都能提高DMO的转化率和乙二醇的收率,但同时也增加了副产物的选择性。较适合的反应条件为:压力2MPa,温度205～210℃,氢酯比80～100,DMO空速10.0mmol/(g.h)。动力学研究表明,DMO加氢反应符合Langmuir-Hinshelwood吸附反应动力学模型,表面反应为速率控制步骤,氢气不解离吸附,由此得到了相应的动力学方程及参数。统计检验结果表明,该模型对DMO加氢反应高度适定。     

应用遥感图像分析九江瑞昌地区构造与金铜成矿的关系

九瑞地区是长江中下游重要的金铜成矿区,遥感图像分析认为,北东东向断裂是主要的控矿构造,与北西向断裂的交汇部位是金铜成矿的有利地段。此外,环形构造又是另外一种控矿构造,目前所发现的金铜矿床均有物化探异常显示,并形成于环形构造的边缘。     

高铅硫化铜精矿的二段焙烧

高铅硫化铜精矿进行湿法铜铅分离时，焙烧过程因有低熔点组份产生，使培砂中铜浸出率仅为73％～82％，达不到工艺要求。经二段焙烧后消除了上述影响，铜浸出率达到97．4％，实现了铜铅分离。     

A review of the linear term in the low-temperature specific heat of La2CuO4 and La2?xMxCuO4 (M = Ba, Ca, Sr)

In this report I will summarize the results of an extensive review of the low-temperature specific heat of the La-based high-temperature superconductors, withT _c between 30 and 40 K, and the related nonsuperconducting compound La₂CuO₄. There have been two previous studies by Fisheret al. [1] and Fischeret al. [2] which also reviewed the low-temperature specific heat of these materials. This work was undertaken to extend a similar study of the 90 K superconductor YBa₂Cu₃O_7– which we recently completed [3]. This review will focus exclusively on the low-temperature specific heat and will update the previous studies by including recent results.     

Advantages of high-field tokamaks for fusion reactor development

High-field designs could reduce the cost and complexity of tokamak reactors. Moreover, the certainty of achieving required plasma performance could be increased. Strong Ohmic heating could eliminate or significantly decrease auxiliary heating power requirements and high values of n_E could be obtained in modest-size plasmas. Other potential advantages are reactor operation at modest values of , capability of higher power density and wall loading, and possibility of operation with advanced fuel mixtures. Present experimental results and basic scaling relations imply that the parameterB ²a, where B is the magnetic field and a is the minor radius, may be of special importance. A superhigh-field compact ignition experiment with very high values ofB ²a (e.g.,B ²a=150 T² m) has the potential of Ohmically heating to ignition. This short-pulse device would use inertially cooled copper plate magnets. Compact engineering test reactor and/or experimental hybrid reactor designs would use steady-state, water-cooled copper magnets and provide long-pulse operation. Design concepts are also described for demonstration/commercial reactors. These devices could use high-field superconducting magnets with 7–10 T at the plasma axis.     

Inhibition behavior for copper corrosion by photoelectrochemical methods

wavelengthofmono chromatelightwas 4 2 0nm .3　RESULTSANDDISCUSSION3.1　ApplicationofphotoelectrochemicalmethodtoevaluatetheeffectsofinhibitorsforcoppercorrosionThestructuresoftheinhibitorsforcoppercorro sionshownintextareasfollows:Theinhibitioneffectsofdifferentinhibitorsforcoppercorrosioncanbeevaluatedby photoelec trochemicalmethod .AsshowninRef .[12 ],onanegativepotentialscan ,thepotentialcorrespondingtothecathodicphotocurrentJph=0isdefinedasΦV,atwhichCu2 Oontheelectrodesurfaceisc…     

Novel technology of purification of copper electrolyte

The effects of arsenic with different valence states on the purification of copper electrolyte were studied and a novel technology of purification of copper electrolyte by copper arsenite was proposed. The results show that the purification performance of As（Ⅲ） compounds is better than that of As（Ⅴ） compounds. The purification technology by copper arsenite has the advantages of simple operation, high purification performance and low cost in comparison with other technologies and its appropriate purification conditions are that copper arsenite concentration is 18 g/L, reaction temperature is 65 ℃ and reaction time is 8 h. The removal rates of Sb and Bi are 53.22% and 58.67% respectively under these conditions. The purification principle show that a kind of yellow precipitate mainly composed of arsenic, antimony （ Ⅴ ）, bismuth and oxygen forms in electrolyte after copper arsenite is added, and consequently antimony and bismuth are removed from electrolyte.     

从铜镉渣中回收镉的试验研究

本文介绍了从铜镉渣中回收镉的试验研究情况，采用酸浸-铜镉渣中和-锌粉除铜法处理铜镉渣，工艺简单合理，镉直收率高，有一定的推广价值。     

天然沸石与纳滤组合工艺处理铜突发污染的应用

纳滤工艺被广泛应用于分散式饮用水深度处理,能解决饮用水苦咸化,盐碱化或微污染等常规水处理工艺无法规避的用水风险,在长时间运行过程中还能有效应对重金属等突发污染风险。但重金属污染易加重纳滤膜污染,需要增设预处理装置加以缓冲,实现纳滤装置的长久稳定运行。而天然沸石具有良好的筛分性能和吸附性能,能够有效缓冲重金属对纳滤装置的冲击。试验以重金属铜为例,证明水中铜离子会造成纳滤不可逆污染比例增加,不利于系统稳定运行;天然沸石对铜离子有很好的吸附效果,静态吸附试验表明天然沸石对水中铜离子的最大吸附量为3.03 mg/g,通过正交试验合理设计吸附预处理,能够有效为纳滤工艺提供安全进水,保证纳滤进水铜离子浓度低于10 mg/L。实践工艺中,吸附预处理能有效缓解纳滤膜不可逆污染,而且吸附-纳滤组合工艺对铜离子及部分其他重金属离子表现出良好的处理效果。