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91.
ABSTRACT: The content of phenolic acids in strawberries was determined before and after gamma-irradiation in the dose range 1 to 10 kGy. Fresh whole strawberries were irradiated, acid-base-hydrolyzed, and purified on polyamide columns. The compounds were analyzed by reversed-phase chromatography and detected with a diode-array detector. Dose/concentration relationships were obtained for gallic acid, 4-hydroxybenzoic acid, cinnamic acid, p-coumaric acid, and caffeic acid. Whereas radiolysis of the individual acids in aqueous solutions led to their efficient degradation and to a notable hydroxylation, in the complex matrix of food no hydroxylation products were formed and only the amount of 4-hydroxybenzoic acid was affected by irradiation (build up: 0.68 ± 0.04 mg kg−1 kGy−1 ). 相似文献
92.
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94.
The heterogeneous enantioselective hydrogenation of activated ketones over chirally modified platinum is reviewed with emphasis on identifying the role of the various species observed in this catalytic system. The past years have witnessed a continuous broadening of the scope of this catalytic system including new reactants and modifiers affording over 97% ee. New reaction pathways have been uncovered and the kinetic and mechanistic studies have been faced with a number of complicating factors caused by spectator species and interactions in solution and on the Pt surface. The previously proposed mechanistic models are critically assessed in the light of these new findings. 相似文献
95.
文章研究了三水草酸铀酰(UO_2C_2O_4·3H_2O)在兆瓦脉冲二氧化碳激光辐照下的红外激光化学反应,它与草酸铀酰的热分解反应不同,反应产物是二氧化铀和二氧化碳。反应的量子效率随激光波长不同而变化。 相似文献
96.
功能化的介孔分子筛碱催化性能的研究 总被引:3,自引:0,他引:3
以苯甲醛与氰乙酸乙酯的Knoevenagel缩合为模型反应,研究了用γ-氨丙基三乙氧基硅烷或γ-乙二胺丙基三甲氧基硅烷功能化的纯硅介也分子筛HMS(Hexagonal mesoporous silica)的碱催化性能。结果表明,除个别碱基负载量高的样品外,功能化样品对反应显示很高的催化活性,反应的初期活性不仅取决于催化剂上活性中心的密度,而且与载体的孔道结构有关。大孔径载体有利于反应物、产物的扩散,故在高负载量时,大孔径样品比小孔样品有更高的活性。此外,还考察了反应温度、溶剂、反应物配比和催化剂用量等条件的影响以及催化剂的重复使用情况。结果表明,反应可在低于100℃的温和条件下进行,有明显的溶剂效应,反应物配比和催化剂用量存在一最佳值;随使用次数的增加,催化剂逐渐中毒而失活。 相似文献
97.
98.
Yueling Dai Peng Yang Lianzang Chen Kejian Liao 《Petroleum Science and Technology》2002,20(5):621-632
The boron heteroatom zeolite catalyst has been modified with silicon compound by Chemical Surface Deposition of Liquid-phase (CLD) technique and the catalytic property of the modified catalyst is studied. Meanwhile, the acidity of the modified zeolite catalysts is characterized through TPD and IR technique, and the fluid adsorption method is used to determine its pore structure. The relationship between the catalytic property of the zeolite catalyst and its pore structure, its acidity has been found. The results of toluene-ethylene alkylation reaction indicate that the selectivity of p-ethyltoluene on the modified zeolite catalyst is higher than that on the zeolite catalyst before silanizated, reaching 94.14%. 相似文献
99.
The interfacial reactions between liquid In and Cu substrates at temperatures ranging from 175°C to 400°C are investigated
for the applications in bonding recycled sputtering targets to their backing plates. Experimental results show that a scallop-shaped
Cu16In9 intermetallic compound is found at the Cu/In interface after solder reactions at temperatures above 300°C. A double-layer
structure of intermetallic compounds containing scallop-shaped Cu11In9 and continuous CuIn is observed after the Cu/In interfacial reaction at temperatures below 300°C. The growth of all these
intermetallic compounds follows the parabolic law, which implies that the growth is diffusion-controlled. The activation energies
for the growth of Cu16In9, Cu11In9, and CuIn intermetallic compounds calculated from the Arrhenius plot of growth reaction constants are 59.5, 16.9, and 23.5
kJ/mole, respectively. 相似文献
100.