Scrolls and nested tubes in multiwall carbon nanotubes

Recent high-resolution transmission electron microscopy (HREM) studies of multiwalled carbon nanotubes (MWCNTs) reveal a class of defects analogous to edge dislocations in a crystal. These defects are believed to mark the transition from scrolls on one side to nested tubes on the other. On the tube side, layer spacing becomes irregular. Analysis of the helicity of the tubes shows a strong correlation between diameter and helicity. This suggests that the organizing principle for the tubes is not Van der Waals forces, as in the case of graphite or turbostratic carbon, but preservation of helicity. Based on these observations and total energy calculations, the authors speculate that graphene monolayers initially form scrolls and subsequently transform into multiwall nanotubes through the progression of defects. Scrolls and nested tubes thus coexist within a single MWNT.     

Word的高级应用——制作表单

通过实例,详细讲解用Word的窗体工具建立表单,以解决行政部门制作电子文档的空白表格时,让填写的人员方便、快捷地填写内容,又不随意修改(破坏)原有格式和原文。     

对计算机网络信息教育教学的反思

计算机教育的发展,为社会输送了具备较高理论素养及较强操作技能的新型网络技术人才,同时,针对新时期网络信息教育,在面向信息技术时代仍凸显一些问题。通过分析计算机网络信息教育教学中存在的若干问题,对教育教学的继续发展进行深入反思。     

磺酰胺类除草剂阔草清的合成研究

以5-氨基-3-巯基-1，2，4-三唑和2，6-二氟苯胺为主要原料，经苄基化、环合、酰化、胺解4步反应合成阔草清，总收率46．5％。该方法可以降低成本，提高反应速度，简化分离步骤，降低能耗和减少污染，是一种较清洁的生产工艺，适合工业化生产。     

Corrosion and mechanical behavior of fusion bonded epoxy (FBE) in aqueous media

In recent years there have been many reported cases of corrosion failure in cement concrete pipelines. In the majority of cases, the failures have been attributed to rebar corrosion which is caused by the permeability of chloride from low resistivity soil and subsequent attack on a passive layer on an iron bar in the structure. As a possible alternative to cementitious materials, some organic coatings based on olefin, vinyl or epoxy-based polymers have been considered. However, due to a paucity of data on the behavior of these coatings in aqueous media— particularly product water—the possibility of their application in water transmission systems in the Kingdom has not been fully exploited. This paper deals with the studies carried out on the corrosion and mechanical behavior of fusion bonded epoxy (FBE) coating on steel in aqueous media which include product water, distilled water and saline water. The mechanical testings on coating include adhesion, bending and cathodic disbondment testings. The corrosion studies include immersion testing under static and dynamic conditions, autoclave tests and accelerated (salt-fog) tests. The analysis of results indicates chemical inertness of FBE coating in either of the aforementioned water used during testing, good adhesion and no damage to the coating during bending. Cathodic disbondment tests indicate that FBE coating sustains under cathodic protection (CP) conditions. In general, the results of mechanical and corrosion tests indicate that FBE is a promising material for internal coating on steel in water transmission systems.     

Stochastic Optimal Design for Unknown Linear Discrete‐Time System Zero‐Sum Games in Input‐Output form Under Communication Constraints

In this paper, stochastic optimal strategy for unknown linear discrete‐time system quadratic zero‐sum games in input‐output form with communication imperfections such as network‐induced delays and packet losses, otherwise referred to as networked control system (NCS) zero‐sum games, relating to the H_∞ optimal control problem is solved in a forward‐in‐time manner. First, the linear discrete‐time zero sum state space representation is transformed into a linear NCS in the state space form after incorporating random delays and packet losses and then into the input‐output form. Subsequently, the stochastic optimal approach, referred to as adaptive dynamic programming (ADP), is introduced which estimates the cost or value function to solve the infinite horizon optimal regulation of unknown linear NCS quadratic zero‐sum games in the presence of communication imperfections. The optimal control and worst case disturbance inputs are derived based on the estimated value function in the absence of state measurements. An update law for tuning the unknown parameters of the value function estimator is derived and Lyapunov theory is used to show that all signals are asymptotically stable (AS) and that the estimated control and disturbance signals converge to optimal control and worst case disturbances, respectively. Simulation results are included to verify the theoretical claims.     

基于贪婪路由协议的动态单/多链路故障恢复策略

针对现有的贪婪方法不能有效处理拓扑结构中链路故障的问题,提出单链路故障和多链路故障本地化恢复策略。首先,通过利用克莱因伯格的贪婪嵌入给出单链路故障恢复策略;然后,将其扩展到多链路故障的情况;最后,在基于Python/C++的仿真环境下对提出的技术进行评估。实验结果表明,该技术仅需要非常有限的资源,且造成的路由质量损耗也有限,可以实现快速切换,可依网络生成树中链路数目扩展。该技术的可扩展性、简单性和低开销使其适合于大型网络。     

电子封装用环氧树脂的增韧和提高耐热性研究

用α,ω 二氯聚二甲基硅氧烷(DPS)或α 氯聚二甲基硅氧烷(CPS)来改性普通双酚A环氧树脂(BPAER)和四溴双酚A环氧树脂(TBBPAER),目标是制备出一系列可用于电子封装的高韧性高耐热性的环氧基料。通过对固化物的冲击强度、拉伸强度、断裂伸长率和玻璃化转变温度(Tg)以及断裂面形态的测定,探讨了改性方法、有机硅组成与含量等对材料性能的影响。结果表明,当m(BPAER)∶m(DPS)=100∶10时,树脂固化物的冲击强度达到30 5kJ/m2,拉伸强度达46 95MPa,断裂伸长率达到60 23%,Tg达到141 3℃;分别比未改性BPAER提高了19 7kJ/m2,1 69MPa,54 29%以及5 9℃。而当m(TBBPAER)∶m(CPS)=100∶10时,固化物的冲击强度达到17 2kJ/m2,拉伸强度达39 89MPa,断裂伸长率达到5 60%,Tg达到147 0℃;分别比未改性TBBPAER提高了12 8kJ/m2,28 26MPa,4 29%以及7 9℃。     

基于辅助学习与富信息策略的Tri-training算法

针对Tri-training算法利用无标记样例时会引入噪声且限制无标记样例的利用率而导致分类性能下降的缺点,提出了AR-Tri-training(Tri-training with assistant and rich strategy)算法.提出辅助学习策略,结合富信息策略设计辅助学习器,并将辅助学习器应用在Tri-training训练以及说话声识别中.实验结果表明,辅助学习器在Tri-training训练的基础上不仅降低每次迭代可能产生的误标记样例数,而且能够充分地利用无标记样例以及在验证集上的错分样例信息.从实验结果可以得出,该算法能够弥补Tri-training算法的缺点,进一步提高测试率.     

P＆T／GC／MS／SIS法在加氯消毒饮用水中痕量挥发性氯代烃测定中的应用

以吹扫捕集-气相色谱-质谱联用选择离子存储法(P&T/GC/MS/SIS)测定自来水中微量挥发性氯代烃,确定了最佳定性定量操作条件,同时探讨了改变原水中加氯量对三氯甲烷形成量的影响。当进样量为5.00mL时,四种氯代烃的线性范围为0～50ug/L,相关系数达0.9991以上;相对标准偏差RSD<9.8%;相对误差<7.6%,样品加标回收率为88%～128%,检测限在0.0006～0.26μg.L-1。方法操作方便,结果令人满意。