阿根廷Φ139.7mm套管探伤缺陷的解剖分析

中原油田所用的阿根廷套管大量不合格，对其进行无损探伤和解剖分析后发现，主要缺陷是折叠和大型非金属夹杂物。     

用电生的Fe(Ⅱ)-EDTA络合物在Fe(Ⅲ)-EDTA-ClCH2COOH-NaOAc缓冲溶液中精密库仑滴定金

提出了在Fe(Ⅲ)-EDTA—ClCH2COOH—NaOAc缓冲溶液中利用电生Fe(Ⅱ)-ED-TA络合物精密库仑滴定Au的方法。采用电位法检测终点，测定范围在5．2～17．0mg Au时，相对平均误差和标准偏差≤0．03％。方法可用于纯金、金合金和首饰等材料中Au含量的精密分析，选择性很好。讨论了电生Fe(Ⅱ)-EDTA络合物作库仑滴定剂的理论基础，获得了有益的结论。     

铸钢件裂纹与钢中夹杂物关系及减少措施

钢中夹杂物是铸钢裂纹产生的主要原因,同时对钢的质量和力学性能等有很大影响,必须严格控制.外来夹杂物可以根据其来源采取相应措施加以去除,而内生夹杂物却需通过脱氧工艺及钙处理工艺新技术加以控制.在冶炼过程中,要加强时脱氧、脱硫、去夹杂物、去气体等冶炼操作,并在炉后钢包内采取必要的措施,如加稀土进行变质处理等来改变夹杂物的形状,减少夹杂物,以降低铸钢裂纹倾向.     

Ar^39／Ar^40 dating of three typical gold deposits in southern Qinling and its implication

1　ＩＮＴＲＯＤＵＣＴＩＯＮＱｉｎｌｉｎｇｏｒｏｇｅｎｉｃｂｅｌｔａｂｕｔｓＮｏｒｔｈＣｈｉｎａ ｐｌａｔ ｆｏｒｍｗｉｔｈＳｈａｎｇｚｈｏｕ ＤａｎｆｅｎｇｇｅｏｓｕｔｕｒｅｉｎｔｈｅｎｏｒｔｈａｎｄｎｅｉｇｈｂｏｒｓＹａｎｇｔｚｅ ｐｌａｔｆｏｒｍｗｉｔｈ     

Effects of gold plating on the resistance to high temperature discoloration of the cavity for ceramic packages

The effects of thickness and types of gold plating on the resistance to high temperature discoloration of gold plating on cavity surface of ceramic package were investigated. It was found that the thicker gold plating, the less discoloration degree for ceramic packages. Non-cyanide gold plating performed better resistance to high-temperature aging than cyanide gold plating. The relationship between the gold plating thickness and the amount of diffused Ni to the gold plating of ceramic packages with Au/Ni and Au/Ni-Co platings after heating at 420℃for 15 min was also studied. When the gold plating thickness reach 2.0 μm and 1.6 μm for Au/Ni and Au/Ni-Co plating systems, respectively, no discoloration was observed on the gold plating surface of cavity, and the corresponding diffused Ni amounts (mass fraction) are 1.0% and 0.4%, while the diffused Co to the gold plating is 0.04%.     

晋东北金矿床石英流体包裹体与找矿

晋东北各种类型金矿中都广泛发育热液型石英脉，与矿化有关的石英流体包裹体的特征反映了不同的矿床类型。对该区石英脉型、蚀变岩型及磁铁石英岩型金矿床的研究表明，石英中流体包裹体的成分、温度和红外吸收光谱等特征可以作为划分矿床类型和作为金矿找矿评价的标志     

XPS characteristics of sulfur of bio-oxidized arsenic-bearing gold concentrate and changes of surface nature of bio-oxidation residue

During bio-oxidation of sulfides, the chemical state change of sulfur is a complex and key factor. It is not only an indicator of the extent and intensity of the bio-oxidation, but also controls the property of bio-leaching medium and the period of oxidation. The chemical state of sulfur in sulfides oxidized by leaching bacteria was studied with XPS. Sulfide minerals in the arsenic-bearing gold concentrate consist of pyrite, arsenopyrite, chalcopyrite, galena, sphalerite and so on. In order to probe the pattern of the chemical state change of sulfur in the bio-oxidation residue of arsenic-bearing gold concentrate, the structure of the grains, and the surface nature of the residue, XPS test was carried out through different sputtering duration. The study of XPS clearly shows that: sulfides is progressively oxidized from the surface of minerals to the core by leaching bacteria; the chemical valence of sulfur changes from S^2- or [S2]^2- to [SO4]^2- ; sulfur in the core is in a reduction state, S^2- or [S2]^2- , but exists in an oxidation state S^6 on the surface; due to the chemical state change of sulfur, mineral phase of the bio-oxidation residue is also changed(sulfides inside, while sulfates outside); the layered structure is found in the grains of the bio-oxidation residue.     

内壁激冷气缸套的组织研究

离心铸造气缸套采用内壁激冷新方法，可细化气缸套的内层组织：使硬质相的网孔直径从３级提高到１～２级，石墨片长度从４级提高到６级。实践证明，这种方法不会出现中间夹杂层现象。     

Gold leaching with elemental sulfur in alkaline solutions under oxygen pressure

1　ＩＮＴＲＯＤＵＣＴＩＯＮＣｙａｎｉｄａｔｉｏｎｐｒｏｃｅｓｓ ,ｃｈａｒａｃｔｅｒｉｚｅｄｂｙｅｆｆｅｃｔｉｖｅｎｅｓｓａｎｄｌｏｗｏｐｅｒａｔｉｎｇｃｏｓｔ,ａｓａｃｏｎｖｅｎｔｉｏｎａｌｔｅｃｈｎｏｌｏｇｙｆｏｒｇｏｌｄｅｘｔｒａｃｔｉｏｎｆｒｏｍｏｒｅｓ ,ｈａｓｂｅｅｎｕｓｅｄｉｎｉｎｄｕｓｔｒｙｆｏｒｏｖｅｒ 10 0ｙｅａｒｓ .Ｈｏｗｅｖｅｒｔｈｅｃｙａｎｉｄｅｉｓａｈｉｇｈｌｙｔｏｘｉｃｃｈｅｍｉｃａｌ,ａｎｄｃｏｍｍｅｒｃｉａｌｃｙａｎｉｄａｔｉｏｎｐｒｏｃｅｓｓｉｓｌｉｍｉｔｅｄｉｎｔ…     

热轧辊轴承失效分析

通过对热轧辊轴承失效件的化学成分，金相组织，夹杂物观察，表层碳浓度和表面硬度测量，剥落块显微形貌分析，结果表明轴承工作面产生早期失效的原因是：较大尺寸的夹杂物在切应力的作用下萌生微型纹成为疲劳源，疲劳裂纹倾斜扩展至表面从而导致轴承圈工作面产生剥落损伤。