A comparison of backpropagation and general regression neural networks in quantative trace metal analysis using anodic stripping voltammetry and cybernetic instrumentation

A comparison is made between backpropagation and general regression neural networks for the prediction of parts per billion lead concentration when used to process data obtained from digested curry powder by the electrochemical analysis method of differential pulse, anodic stripping at a thin film mercury electrode (TFME). Two data sets are used, one requiring the net to classify an unknown analytical data vector into one of a number of previously learnt concentrations, and one requiring the net to predict the probable concentration of an unknown sample by interpolation of the already learnt concentrations. For both of these data sets the general regression neural network is shown to train faster and to provide results superior to those obtained by backpropagation.     

以废钡渣为原料制取氯化钡的研究

本文研究了以直接耐晒黑Ｇ染料生产中的废钡渣为原料制取氯化钡的方法，氯化钡的得率达到废钡渣量的７０．９９％，产品质量达到一级品的标准。     

Graphite formation on Ni film by chemical vapor deposition

Thin film formation of graphite by chemical vapor deposition using 2-methyl-1,2′-naphthyl ketone as a starting material was carried out on Ni film substrates. On Ni films directly deposited on quartz glass, the graphite films were obtained when the Ni film thickness was above 1 000 Å and above 5 000 Å at 700 °C and 1 000 °C, respectively. Depositions on thinner Ni film substrates comprise amorphous carbon (a-C) or graphite tubes which was owing to the thermal coagulation of the Ni film into droplets. On the other hand, graphite film was obtained on the Ni film with thickness 10 Å when a-C was inserted between the Ni film and the quartz glass. The coagulation of the Ni film is considered to be avoided by inserting a-C layer.     

金属蒸气法制备聚合物固载Pd－Cu双金属原子簇

为了不使用任何还原剂而获得聚合物固载高分散零价双金属加氢催化剂，利用金属蒸气法制备了３种不同Ｐｄ／Ｃｕ质量比的聚合物固载双金属原子簇。透射电镜（ＴＥＭ）和Ｘ衍射（ＸＲＤ）测定表明，Ｐｄ－Ｃｕ原子簇粒度很小，平均直径小于３．０ｎｍ。Ｘ射线光电子能谱（ＸＰＳ）表明，Ｐｄ和Ｃｕ均为零价态。Ｐｄ－Ｃｕ原子簇在异丙叉加氢反应中具有很高的活性和选择性。这些结果提供了令人信服的证据，即金属蒸气法可用于在聚合物孔穴内直接而温和地置入小的零价金属原子簇，而且这样制备的聚合物固载金属原子簇很适合于催化应用。     

在教学中推行微型化学实验势在必行

微型化学实验是当今化学教学中的重要变革之一。本文简单介绍了微型化学实验的特点和当前国内外发展的概况，倡议在我省的化学中尽快推行微型化学实验     

Improvement of the optical properties of electrodeposited CuInSe2 thin films by thermal and chemical treatments

Cu, In and Se have been codeposited in thin films by potentiostatic one-step electrodeposition. The as-deposited material has shown direct optical transitions attributable to the CuInSe₂ semiconductor, but also additional absorption corresponding to another semimetallic phase. The secondary phases are selenium and copper selenide compounds which have been determined by composition measurements. In order to eliminate the semimetallic phases and to improve the semiconductor behaviour of the electrodeposited material, thermal and chemical treatments have been performed. After heat-treatment of the samples at 400°C in flowing argon, elemental selenium loss has been detected together with an enhancement of the allowed direct optical transition. The subsequent chemical etching of the layers in a KCN solution has showed to be successful in eliminating the copper selenide phases which were responsible of the remaining sub-bandgap absorption.     

美国高能激光技术2005年主要进展

高能激光武器技术在2005年取得了重大进展。介绍了机载兆瓦级化学氧碘激光器的关键试验和束控-火控系统的飞行试验。评论和讨论了高功率固体激光器、光纤激光器、超高效率二极管源和中继镜技术的重大进展。     

Analysis of trace mercury in water by solid phase extraction using dithizone modified nanometer titanium dioxide and cold vapor atomic absorption spectrometry

A new method for analysis of trace mercury in water samples was developed, based on the combination of preconcentration/separation using dithizone-modified nanometer titanium dioxide (TiO2) as a solid phase extractant and determination by cold vapor atomic adsorption spectrometry (CVAAS). Dithizone was dissolved with alcohol and loaded on the surface of nano-sized TiO2 powders by stirring. The static adsorption behavior of Hg2 on the dithizone-modified nanoparticles was investigated in detail. It was found that excellent adsorption ratio for Hg2 could be obtained in the pH range of 7-8 with an oscillation time of 15 min, and a 5 mL of 3.5 mol·L-1 HCl solution could quantitatively elute Hg2 from nanometer TiO2 powder. Common coexisting ions caused no obvious influence on the determination of mercury. The mechanisms for the adsorption and desorption were discussed. The detection limit (3σ) for Hg2 was calculated to be 5 ng·L-1. The proposed method was applied to the determination of Hg2 in a mineral water sample and a Zhujiang River water sample. By the standard addition method, the average recoveries were found to be 94.4%-108.3% with RSD (n = 5) of 2.9%-3.5%.     

引渤济锡海水输送工程

引渤济锡海水输送工程是内蒙古锡林郭勒盟恢复草原生态和实施以发展电力和煤化工为主体的褐煤开发战略的基础工程。该工程是从渤海引海水，通过辽宁省的葫芦岛市、朝阳市和内蒙古的赤峰市到锡林浩特，本阶段设计年输海水3．65亿甜。该工程将与锡林格勒盟地区待建的煤化工、海洋化工、生态工程形成新型的循环经济发展产业链。长距离输送海水是一个世界性的新课题。现研究了长距离海水输送的特点，提出了应对海水强腐蚀、海生物附着所引起的污损问题和输送过程中防泄漏和渗漏问题的工程措施，采用一条夹砂玻璃钢管管线结合隧洞和一座在线调节水库的输送海水方案，包括：设9座泵站，设计总扬程1147m海水水头，线路全长607km左右，其中玻璃钢管全长290km，直径3．2km，隧洞全长317km，输海水总成本为4．1元／m左右。引渤济锡海水输送工程的建立，标志着我国海水综合利用进入一个新的历史阶段，工程本身具有下述特点：输送海水流量、距离、扬程综合指标，世界第一；内径3．2m夹砂玻璃钢管是国内目前采用的最大管径的玻璃钢管。此外，引渤济锡海水输送工程的建设不仅能够促进锡林郭勒盟地区经济的持续发展，而且具有下述重大战略意义：一是通过“盐田置换”方式促进环渤海经济区建设；二是为发展制盐工业提供了新的发展模式；三是为我国开发内蒙古、新疆维吾尔自治区巨大的煤炭资源、恢复生态系统提供了一条新的思路。     

计算机软件在多媒体化学教育中的应用

本文阐述了计算机软件在多媒体化学课件开发中的应用，着重介绍了一些普通软件及专业化学软件的特点及功能。