超临界乙醇制备TiO_2/石墨烯纳米复合材料及其表征

以氧化石墨为载体、钛酸异丙酯为前驱体,利用超临界乙醇的超临界性能和还原性,制得了晶型完善的锐钛矿TiO2/石墨烯纳米复合材料。通过红外光谱(FTIR)、X射线光电子能谱(XPS)对采用Hummers法制得的氧化石墨(GO)进行表征;同时利用透射电子显微镜(TEM)、X射线衍射仪(XRD)对TiO2/石墨烯纳米复合材料进行研究。结果表明:成功制得了氧化石墨(GO)和晶型完善的锐钛矿TiO2/石墨烯纳米复合材料,并且发现二氧化钛在石墨烯纳米片层上呈现为有规则的颗粒,分散均匀,平均粒径为8.24nm。     

Effect of expandable graphite and ammonium polyphosphate on the thermal degradation and weathering of intumescent fire-retardant coating

This research aims to study the effect of ammonium polyphosphate and expandable graphite on the intumescent coating formulations (ICF). The coating presented in this research article is based on carbon source expandable graphite (EG), blowing agent melamine, acid source ammonium polyphosphate (APP), epoxy resin as a binder with polyamide amine. The stability of the developed coating was verified at 950°C for 1-hour fire test. The results showed that the coating is stable and well bond with the steel substrate. The char was characterized by using FESEM, XRD, FTIR, DTA, TGA, XPS, Py-GCMS and Weathering Test. The morphology of the char was studied by SEM of the coating after furnace fire test. XRD and FTIR show the presence of graphite, borophosphate; boron oxide and sassolite in the residual char. TGA and DTG disclosed that EG improved the residual mass of coating. XPS analysis showed the char residue of IF5-APP-EG contains carbon and oxygen contents 47.50 and 40.70, respectively. Py-GCMS analysis described that the IF5-APP-EG released less gaseous compounds. The weathering test illustrated that's the char expansion of coatings samples was decreased due to the presence of a humid environment and UV light. The IF5-APP-EG showed the maximum char expansion, lower substrate temperature and high residual weight among the studied formulations.     

提高离心球墨铸铁管水泥内衬质量的方法

分析影响离心球墨铸铁管水泥内衬质量的因素,对水泥内衬质量不稳定,内衬层厚度不均匀,水泥中间起泡,衬层密实度不够,内裂、离鼓严重,衬层内壁有泪痕等质量缺陷,针对性地采取措施,加强人力资源管理和考核,对承口挡轮、托压轮、搅拌机等相应设备进行改造,对养生池进行扩建,攻关后水泥衬层一级品率由原来的64%提升到99%,取得了预期的效果。     

用含Pb、As、Sn地方生铁砂型铸造生产D型石墨铸铁的研究

基于Ph、As、Sn等元素有增大铁液过冷倾向的作用，利用含Ph、As、Sn的地方生铁，采用合金化和砂型铸造可以获得D型石墨铸铁，对其工艺方案进行了研究。用正交试验法设计试验方案，得到最佳工艺方案为：在亚共晶成分（WB％：3．2C，2．1si）的铁液中加入适量的铝（0．6％）和钛（0．8％），可以得到含有100％D型石墨的铸铁，其抗拉强度最高可达276MPa。     

稀土对D型石墨铸铁强化机理的研究

通过试验研究,发现微量稀土能促进D型石墨铸铁中初晶奥氏体骨架的生长,对强化基体组织有一定的作用。微量稀土能细化D型石墨,石墨数量增多,石墨生长前端钝化、分枝、花瓣状形态也有所改善,大大减轻了石墨对基体的破坏作用,从而提高D型石墨铸铁的力学性能。     

球铁铝锭模材料热疲劳性能的研究

模拟铝锭模的使用条件,研究了不同基体组织球墨铸铁的热疲劳性能.结果表明,退火铁素体铝铸锭模使用寿命最长.该铝锭模安装在包头铝业公司的2台铝锭连续铸造机上使用,平均每天铸锭48t/台,连续使用410天.而普通材质的球铁铝锭模使用寿命仅为120到150天左右.     

Characteristics of graphite felt electrode electrochemically oxidized for vanadium redox battery application

The graphite felt was oxidized at a positive electrode potential in sulfuric acid solution.The electrochemical performance of the treated graphite felt served as electrode for vanadium redox battery was investigated with FT-IR,SEM,XPS,BET,cyclic voltammetry and testing VRB system,respectively.The results show that the molar ratio of O to C increases from 0.085 to 0.15 due to the increase of—COOH functional groups during electrochemical oxidation treatment,and the GF surface is eroded by electrochemical oxidation,resulting in the surface area increase from 0.33 m2/g to 0.49 m 2/g.The VRB with modified GF electrode exhibits excellent performance under a current density of 30 mA/cm 2 .The average current efficiency reaches 94%and average voltage efficiency reaches 85%.The improvement of electrochemical activity for the electrode is ascribed to the increase of the number of—COOH group and the special surface of GF.     

蠕墨铸铁CA6110柴油机缸体的试验研究

在现有汽缸体高压造型生产线上进行大马力柴油机蠕墨铸铁缸体的试验,试验铁液化学成分w为3.6%~3.9%C;2.2%~2.4%Si;0.2%~0.5%Mn;P≤0.06%;S≤0.03%,采用自行研制的成分为8%~10%Mg,2%~3%RE的蠕化剂进行冲入法蠕化处理,同时加入0.8%~1.0%Cu和0.03%~0.05%Sn,成功的铸造出蠕墨铸铁CA6110柴油机缸体。对附铸试样和铸件本体进行了金相组织和力学性能检测,结果表明,试样的的蠕化率可达80%~85%,珠光体含量达80%~85%,力学性能σb>480 MPa,δ=1.0%~1.5%,180~200 HBS;缸体铸件本体的蠕化率同样为80%~85%,硬度可达197~214 HBS。试验结果表明:采用的铸造工艺方案是合理的,在铁液中加入的Cu和Sn可明显增加蠕墨铸铁的珠光体数量,提高抗拉强度和硬度,满足大马力柴油机对性能的要求。     

铸铁中微量元素分布规律的异化及应用

Pb、As、Sn等微量元素在不同形态的石墨区域中有不同的分布规律；在A型石墨区偏聚在基体中，在D型石墨区偏聚在石墨上。利用这两种分布规律，制取含Pb、As、Sn D型石墨铸铁，使Pb、As、Sn主要聚集在石墨上，微量残留在基体中，可以获得良好的力学性能。     

新型Ni3Al/石墨高温固体自润滑材料的制备及其性能

采用熔炼法, 制备出新型Ni3Al/石墨抗高温、耐腐蚀固体自润滑材料.结果表明: Al不仅是强化合金基体的元素, 而且是一种使片状石墨转变为球状石墨的球化剂; 铝与氧结合成渣降低了氧在石墨表面的吸附.建立了界面能和过冷度对石墨生长形态影响的动力学模型; 分析表明, 石墨在洁净的液态金属中结晶, 由于(1010)棱面与(0001)基面的温度回升速率的差异, 促使石墨球状生长.石墨经球化处理后, 材料的冲击韧性得到提高; 将该材料与GCr15轴承钢及45﹟退火钢进行干摩擦磨损时, 摩擦因数分别为0.36和0.40.