Liquid phase sintering and characterization of SiC ceramics

The present study focuses on the sintering of silicon carbide-based ceramics (SiC) by liquid phase sintering (LPS) followed by characterization of the produced ceramics. AlN/Re₂O₃ mixtures were used as additives in the LPS process. In the first step, the LPS-SiC materials were produced in a graphite resistance furnace in the form of discs at different temperatures. The conditions with the best results regarding real density and relative density were taken as reference for sintering in the form of prismatic bars. In the second step, these samples were evaluated regarding fracture toughness (K_IC), by the Single Edge V Notch Beam – SEVNB – method, and flexural strength. K_IC behavior was evaluated according to the depth and curvature radius of the notches. Reliable K_IC values were presented when the ceramic displayed a small curvature radius at the notch tip. When the radius was large, it did not maintain the square root singularity of the notch tip. Tests were carried out to determine K_IC values in atmospheric air and water. K_IC results were lower in water than air, with a decrease ranging between 2.56% and 11.26%. The observations indicated a direct grain size correlation between K_IC values and fracture strength of the SiC ceramics.     

中频炉烧结钍钨坯条技术研究

为了解决中频炉烧结钍钨坯条密度偏低的问题，对中频炉进行了炉底、炉体、顶盖技术改造，改造后提高了工装的隔热效果，使中频炉耐热温度由2 300 ℃提高到2 800 ℃，然后进行钍钨坯条的烧结，研究了中频烧结钍钨坯条的工艺参数，结果表明：2 300 ℃烧结密度只有16.94 g?cm-3，提高烧结温度到2 800 ℃此时接近氧化钍的熔点（3 220 ℃），烧结后密度提升较大达到18.70 g?cm-3，达到后续加工要求，2 800 ℃烧结延长高温烧结时间和增加保温平台的方式对钍钨坯条的烧结密度影响不大。     

邢钢180 m2烧结机提高混合料温度的实践

介绍了邢钢180 m^2烧结机投产以来,在提高混合料温度方面所采取的主要措施.该厂通过提高生石灰质量、采用蒸汽预热混合料、在混合机中加热红泥浆等,改善了混合料的透气性,进而提高了烧结矿产、质量.     

Understanding silica-supported metal catalysts: Pd/silica as a case study

Supported metal catalysts, particularly noble metals supported on SiO₂, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO₂/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO₂ films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon.     

微波合成无机纳米材料的研究进展

微波加热作为一种合成纳米材料的新方法，近年来得到飞速发展。介绍了微波加热原理，阐述了微波合成无机纳米材料的一些研究进展，主要是液相微波加热在制备金属氧化物和金属硫化物纳米材料以及微波烧结在合成陶瓷材料的应用，并对该领域未来作了一些展望。     

马钢二烧结配料计算机控制系统

阐明了马钢二烧结配科计算机控制系统的目的、控制形式、控制原理；根据烧结配料控制对象的特点对信号采样和控制算法进行了探讨；提供了系统的主要硬件结构，软件功能和程序框图。     

片式多层陶瓷微波谐振器

介绍了片式陶瓷微波谐振器的工艺过程、谐振器的结构以及结构对谐振器参数的影响,谐振器与外电路的耦合采用耦合间隙的方法与谐振单元在同一层内实现,这种新结构既可给制备工艺带来方便,又可减少工艺所带来的误差。用多层陶瓷工艺技术,用高介电常数、低温烧结微波陶瓷实现了中心频率为1GHz,有载品质因数大于80的试验双端口多层微波谐振器。微波谐振器体积小,整个谐振器的尺寸为7mm×2mm×1mm,适用于表面贴装技术。     

微波辅助合成3,4-二氨基苯甲酸

以对氨基苯甲酸为原料,在微波辐射下经乙酰化、硝化、水解及还原反应制得3,4-二氨基苯甲酸(Ⅰ),总收率为67．6%(未用微波辐射时为40．7%),反应时间由6 h缩短为1 h,并探讨了合成条件。在n(p- H2NC6H4COOH):n(Ac2O)=1:2,微波功率800 w的条件下,回流5 min,对乙酰胺基苯甲酸(Ⅱ)的收率为93．8%;n(Ⅱ):n(Ac2O)=1:2,使用过量乙酸酐,在冰水浴中滴完浓硝酸后,在微波功率800 W,回流3 min后,4-乙酰氨基-3-硝基苯甲酸(Ⅲ)的收率为85．3%;在微波功率800 W条件下,Ⅲ与过量的w(KOH)= 50%乙醇溶液,回流5 min,3-硝基-4-氨基苯甲酸(Ⅳ)的收率为93．1%;在Ⅳ的乙醇溶液中,在回流温度下滴加w[(NH4)2S]=9%硫化铵溶液,然后,在微波功率800 W条件下,回流5 min,可得90．8%的目标产物Ⅰ。用IR、1H NMR对化合物Ⅰ～Ⅳ进行了表征。     

“锲而不舍 金石可镂”——上海秀派公司2．45GHz有源RFID标签技术的成功之路

上海秀派公司坚持自己的技术长项——2．45GHz有源RFID,充分发扬该种RFID的特长,记者采访该公司时了解到了开发方面的很多细节、成功案例和实施经验。我们不但非常推崇该公司的“锲而不舍”的意志,而且还意识到如果秀派公司的成功经验一旦辐射到中国的RFID行业中,一定会把这项在国外诞生的技术更好地植根于中国的土壤,使之更加适合中国的实用环境。     

微波陶瓷基印制板制造工艺性研究

对微波陶瓷基印制板的制造工艺流程进行了简单的介绍,对所采用的工艺技术的有效性进行了较为详细的论述。