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41.
新型煤填充高分子复合材料的研制与应用 总被引:4,自引:0,他引:4
根据煤的结构特点,对煤进行闭环的超细粉碎,脱除部分挥发分,表面傅-克烷基化化学改性,与塑料经强制排气式共混,研制了一种新型的煤填充高分子复合塑料母料.将该母料用于聚丙烯,可制得具有较好强度、韧性和优良电绝缘性能的复合材料,在煤含量为20%(质量分数)时,复合材料的拉伸屈服强度大于24.0MPa,缺口冲击强度不小于8.0 kJ/m2;同时,煤/聚丙烯复合材料在较大的煤含量范围内(0%~50%,质量分数),直流绝缘电阻率保持在1014 Ω·cm以上.新型煤填充高分子复合材料在电线电缆中的应用表明,加工性能良好,成品绝缘层力学性能满足标准要求,绝缘性能优良,并可有效降低材料的成本. 相似文献
42.
煤巷锚杆支护技术的探讨 总被引:1,自引:0,他引:1
从巷道围岩强度,原岩自重应力,地质构适应力,煤柱留设宽度和巷道断面形状等方面对影响煤巷稳定性的因素进行了分析,提出了煤巷锚杆支护注意的6个问题。 相似文献
43.
44.
This paper reports the results of current fundamental research at the Department of Process Engineering, University of Miskolc on the processing of clean coal from Mecsek bituminous coal, Southern Hungary. The theoretical possibility of the separation of different petrographic components was proven experimentally and their liberation degree was determined based on the petrographic composition, flotation kinetic study of isolated components (groups of components), scanning electron microscopy and microprobe analyses. The mill with stirred ball media was chosen for the ultra-fine liberation of the coal components. It was revealed that along with the liberation of coal components, their surface oxidation and spontaneous agglomeration, entrapping the mineral impurities take place in ultra-fine grinding. This paper discusses the interfacial phenomena occurring in the ultra-fine grinding process and their influence on the flotation. The concept for the advanced preparation of clean coal was developed, tested and proved. The main steps of this concept are the ultra-fine liberation in the stirred-media mill, the de-agglomeration of flocs spontaneously formed during the ultra-fine grinding and the induced (hydrophobic) flocculation with the following two-step flotation in a flotation column. 相似文献
45.
Inertinite concentrates from three Australian bituminous coals were hydrogenated at various temperatures ranging from 350 to 475 °C in the presence of tetralin without any added catalyst. Both conversion yields and microscopic observations of the benzene-extracted hydrogenation residues have revealed that the hydrogenation of the inertinite macerals becomes significant only > 400 °C, whereas the dissolution-hydrogenation of the accompanying vitrinite macerals occurs mainly between 350 and 400 °C. The major reaction pathway for the inertinite particles in the hydrogenation process appears to be one of initial mild carbonization followed by hydrogenation. A simplified reaction scheme is proposed which describes the reaction pathway involved in the hydrogenation of inertinite. 相似文献
46.
The development of porosity in the course of carbonization of a flame coal, original and pre-oxidized, was studied by means of the adsorption of benzene and carbon dioxide. The results were compared with corresponding data for cokes from a xylitic brown coal. The influence of coal oxygen content on the formation of coke porosity and its thermal dependence is discussed. 相似文献
47.
The technique of analytical pyrolysis has been used to characterize 40 similar mid-rank western Kentucky coals of widely differing ASTM Gieseler plasticity. Certain pyrolysis/g.c. variables were shown to correlate well with both ASTM Gieseler and isothermal plasticity. Highly plastic coals were shown to exhibit certain characteristic peaks in the 450 °C pyrogram which were absent in the pyrogram of the non-plastic coals. Two coals, representing the two extremes in plasticity, were selected for further study. After extraction with solvents such as DMF the characteristic peaks were absent in the 450 °C pyrogram of the extraction residue of the highly plastic coal. These peaks were also shown to decrease with increasing severity of air oxidation of the plastic coal. This technique appears to be a useful tool for the analysis of mid-rank plastic coals and supports the view that the substances contained in the bitumen fraction of these coals are involved in the development of the plastic state. 相似文献
48.
Studies of elemental distributions within discrete coal macerals: Use of secondary ion mass spectrometry and X-ray photoelectron spectroscopy 总被引:3,自引:0,他引:3
N.Stewart Mclntyre Ronald R. Martin William J. Chauvin C.Gordon Winder James R. Brown J.Anthony MacPhee 《Fuel》1985,64(12):1705-1712
Secondary ion mass spectrometry has been used to measure qualitatively the distributions of many trace and minor elements within some well-characterized coal macerals: vitrinite, fusinite and exinite. Complementary information was obtained by using X-ray photoelectron spectroscopy. Within the vitrinite specimens studied, a widely-dispersed largely inorganic aluminosilicate phase was identified, which contained a number of other trace elements. By contrast, within the organic-rich phase of this macerai, titanium was detected in a very even distribution; this suggests that some titanium may be bonded in an organic complex. The fusinite was shown to contain elevated concentrations of calcium, magnesium and fluorine, dispersed over a large portion of the maceral. The high fluorine content could be identified as an organo-fluoro compound using XPS. Exinite was found to contain lower concentrations of most elements, compared to other macerals. The organic composition of this maceral was significantly different from that of surrounding macerals; this could be seen from the enhanced emission of the C2H2-secondary ion and images of this ion thus clearly outlined the position of such macerals. 相似文献
49.
本文研究了具有典型分解特征的Al-Zn-Ce非晶合金的形成和晶化过程,探讨了各种相的生成顺序。XRD和DSC测试结果表明强烈的化合物短程序有利于Al-Zn-Ce非晶合金的形成。在Al-Zn-Ce非晶合金的晶化过程中存在复杂的相选择行为,多种相的竞争形核和有限生长使其具有复杂的结构特点。同时,结果也表明冷速对该体系非晶的形成有很大影响。 相似文献
50.