气相处理对碳纤维表面及其复合材料性能的影响

本文对气相表面处理碳纤维的新工艺进行了系统研究。处理后的碳纤维强度、模量不下降,且其表面能、表面化学官能团含量明显增加;表面微晶结构变小,与环氧树脂复合后,层间剪切强度(LLSS)提高47%左右。本文还对复合材料断口的形态结构进行了分析,说明这种表面处理方法能有效改善碳纤维增强环氧树脂复合材料(CFRP)的界面粘结。     

1477 nm LD泵浦掺铒光纤放大器的研究

报道了采用１４７７ｎｍ激光二极管（ＬＤ）泵浦的掺铒光纤放大器的实验结果。研究了放大器的增益和时域特性。对１５２０ｎｍ的信号光，获得了２３ｄＢ的增益，泵浦效率为２．２８ｄＢ／ｍＷ。低频脉冲信号经过放大器后未发生波形畸变。     

被动锁模复合环形腔掺饵光纤激光器的自启动分析

本文对被动锁模复合环形腔掺饵光纤激光器的自启动工作特性进行了分析，指出谐振腔内残余反射面的存在是阻碍激光器实现自启动锁模的主要原因。利用半导体激光器有源区的折射率随注入电流的变化而改变的特性，在谐振腔中获得了一个可移动腔镜，克服了腔内残余反射面的影响，实现了锁模的自启动。     

In-chain functionalization by alternating anionic copolymerization of styrene and 1-(4-dimethylaminophenyl)-1-phenylethylene

Anionic copolymerizations of styrene (M₁) with excess 1-(4-dimethyl-aminophenyl)-1-phenylethylene (M₂) were conducted in benzene at 25°C for 24h, using sec-butyllithium as initiator. Narrow molecular weight distribution copolymers with M?;_n = 16.1 × 10³ g/mol (M?_w/M?_n = 1.04) and 38.2 × 10³g/mol (M?_w/M?_n = 1.05), and 24 and 38 moles of M₂ per macromolecule, respectively, were characterized by size exclusion chromatography, ¹H NMR spectroscopy and DSC. The monomer reactivity ratio, r₁ = 5.6, was obtained from the copolymer composition at complete consumption of M₁, assuming that the rate constant k₂₂ =0,i.e. r₂ =0. The polymers exhibited T_g values of 128 and 119°C, respectively, which correspond to an estimated T_g = 217°C for the hypothetical homopolymer of M₂.     

Characterization of hollow fiber membranes in a permeator using binary gas mixtures

We have studied the CO₂/CH₄ mixed gas permeation through hollow fiber membranes in a permeator. An approach to characterize the true separation performance of hollow fiber membranes for binary gas mixtures was provided based on experiments and simulations. Experiments were carried out to measure the retentate and permeate flow rates and compositions at each outlet. The influences of pressure drop within the hollow fibers, non-ideal gas behavior in the mixture and concentration polarization were taken into consideration in the mathematics model. The calculation results indicate that the net influence of the non-ideal gas behavior, competitive sorption and plasticization yields the calculated CO₂ permeance in a mixed gas permeator close to that obtained in pure gas tests. Whereas the CH₄ permeance is higher in the mixed gas tests than that in the pure gas tests, as the plasticization caused by CO₂ dominates the permeation process. As a result, the CO₂/CH₄ mixed gas selectivity is smaller than those obtained in pure gas tests at equivalent pressures.The calculated membrane performance shows little changes with stage cut if the effect of concentration polarization is accounted for in the calculation. The integration method developed in this study could provide more accurate characterizations of mixed gas permeance of hollow membranes than other estimation methods, as our model considers the roles of non-ideal gas behavior and concentration polarization properly.     

Three‐dimensionally braided carbon fiber–epoxy composites,a new type of material for osteosynthesis devices. I. Mechanical properties and moisture absorption behavior

In recent years, three‐dimensionally (3D) braided composites have attracted a great deal of attention because of their high‐impact damage tolerance and fatigue life, superior fracture toughness, and so forth, and have been used in aeronautics, military, and transportation. These advantages make them strong candidates for osteosynthesis devices. In this study, 3D braided carbon fiber–epoxy (C_3D/EP) composites were produced via a simple vacuum impregnation technique. The load‐deflection curve, mechanical properties, and influence of fiber volume fraction, braiding angle, and axial reinforcing fibers were examined to determine their suitability for internal fixation devices. It is found that the C_3D/EP composites have excellent toughness and do not show brittleness when fractured because of their relatively high void content. The flexural, shear, and impact strengths of the C_3D/EP composites are excellent. It was shown that a C_3D/EP composite with a stiffness similar to load‐bearing bones can be made while maintaining enough strength. It is concluded that a relatively higher void content and braiding angle is more suitable for the C_3D/EP composites from the viewpoint of requirements of fracture fixation materials. The moisture absorption behavior and changes in mechanical properties caused by moisture uptake were evaluated. Results show that absorbed moisture slightly decreases mechanical properties of the C_3D/EP composites. Contrary to the unreinforced epoxy, the moisture absorption behavior of the C_3D/EP composites cannot be described with Fick's law of diffusion, probably because of the presence of voids and/or 3D fiber structure. The exact mechanisms should be proposed in further investigations. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1031–1039, 2002     

多模光纤出射的光通过透镜后的场分布

用部分相干光理论,研究了单模激光入射的多模光纤出射的光经透镜后,在菲涅尔衍射区内场的分布。     

碳纤维表面处理对铝电解用硼化钛阴极涂层性能的影响

硼化钛阴极涂层是铝电解用可润湿性阴极材料中的一种，具有优良的抗钠渗透性和对铝液润湿性，可以有效地延长铝电解槽寿命。碳纤维是硼化钛涂层材料的增强剂之一．对硼化钛阴极涂层的性能影响很大。本文研究了不同工艺的液相碳纤维表面氧化处理法对硼化钛阴极涂层抗拉强度和粘接强度的影响。采用PTIR检测碳纤维处理后表面含氧基团的变化，寻找影响硼化钛阴极涂层性能的原因，从而达到最有效地提高TiB2阴极涂层抗拉强度和粘接强度的目的。结果表明，采用工艺(1)(10％HNO3，80℃、恒温5min．超声波、5min)对碳纤维进行表面处理最合理，处理后碳纤维表面含氧基团的含量最高．用其制备硼化钛阴极涂层的抗拉强度、粘接强度最大。     

波分复用系统中的交错复用器(Interleaver)技术

鉴于波分复用技术已成为光纤通信的发展方向，介绍几种新型的交错复用器的原理、结构等情况，对各种器件进行了比较。     

钱塘江光缆管穿越施工技术

钱塘江光缆管穿越长度2454.15m,穿越深度为32m,穿越中采用了多项新技术、新工艺、新方法。文章介绍了导向孔对穿技术、套管技术、水下磁场电缆铺设技术、长距离泥浆回流技术、长距离穿越钻杆组合技术在钱塘江光缆管穿越施工中的应用。