NaEuF_4微米晶的水热合成与表征

以柠檬酸钠(Na3Cit)为螯合剂和形貌控制剂,通过水热方法成功合成了尺寸均匀的六角形NaEuF4微米晶.采用X-射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、能量色散X射线(EDX)和光致发光光谱(PL)对所得产物的结构、形貌以及发光性质进行分析.XRD和SEM分析表明:所得NaEuF4微米晶为六方相,颗粒较均匀.NaEuF4微米晶的尺寸和形貌可通过改变Na3Cit的量和反应时间进行调整.提出NaEuF4微米晶的可能形成机理,并研究其光致发光光谱性质.     

Preparation of zeolite NaA for CO2 capture from nickel laterite residue

Zeolite NaA was successfully prepared from nickel laterite residue for the first time via a fusion-hydrothermal procedure. The structure and morphology of the as-synthesized zeolite NaA were characterized with a range of experimental techniques, such as X-ray diffraction, scanning electronic microscopy, and infrared spectroscopy. It was revealed that the structures of the produced zeolites were dependent on the molar ratios of the reactants and hydrothermal reaction conditions, so the synthesis conditions were optimized to obtain pure zeolite NaA. Adsorption of nitrogen and carbon dioxide on the prepared zeolite NaA was also measured and analyzed. The results showed that zeolite NaA could be prepared with reasonable purity, it had physicochemical properties comparable with zeolite NaA made from other methods, and it had excellent gas adsorption properties, thus demonstrating that zeolite NaA could be prepared from nickel laterite residue.     

全电子式有源程控电阻器的设计

提出了一种具有量程程控转换和阻值预置功能的电阻器设计方法,其实现电路由量程转换电路、增益设置电路和控制电路三部分组成,内部无继电器,具有多量程、阻值连续可调、分辨力高、准确度高等优点,针对提高电阻器分辨力和量程转换速度,以及消除导通电阻误差和引线误差,提出了具体的电路实现方法,对系统的分辨力和准确度进行测试验证,并通过分析实测数据可知,当阻值在0~1 kΩ范围时,分辨力可达到0.1Ω,阻值超过1 kΩ时,分辨力可达到1Ω.     

超分子化合物(C_(10)N_4O_4H_6)(C_6N_4H_6)的水热合成及其结构表征

采用水热合成法,合成了三维超分子化合物(C10N4O4H6)(C6N4H6)(1),通过X-射线单晶衍射、元素分析和红外光谱对化合物1的结构进行了表征.并对化合物1进行了元素分析、红外光谱分析.结构解析表明,化合物1是由1,2,4,5-苯二酰肼(H4bbh)和2,2'-联咪唑(Bim)构成的共晶化合物.化合物1属于三斜晶系,P-1空间群,晶胞参数a=0.36735(7)nm,b=0.91550(18)nm,c=1.135 7(2)nm,α=88.94(3)°,β=81.25(3)°,γ=87.56(3)°,V=0.37714(13)nm3,Z=1,R1=0.053 5,ωR2=0.114 8.该化合物通过氢键作用和π…π堆积作用形成三维超分子结构.对该化合物的荧光性质进行了测试分析.     

Keggin型配合物[(CH_2)_5NH_2]_4SiMo_(12)O_(40)催化合成香兰素1,2-丙二醇缩醛的研究

以自制的Keggin型配合物[(CH2)5NH2]4SiMo12O40为催化剂,香兰素和1,2-丙二醇为原料,苯为带水剂,制备香兰素1,2-丙二醇缩醛.对物料配比、催化剂用量和反应时间等因素经行考察.表明:Keggin型配合物[(CH2)5NH2]4SiMo12O40具有较好的催化效果,且可重复利用.最佳反应条件为:香兰素15.2 g(0.1 mol),n(香兰素)n(1,2-丙二醇)n((CH2)5NH2]4SiMo12O40)=1 1.50 0.05,苯20 mL,反应时间2.0 h条件下,产品收率达到88%以上.     

基于TTS的中英文语音软件设计与实现

本文提出了一种基于TTS语音合成技术,利用Microsoft Speech SDK语音开发包、TTS引擎,采用VB平台开发了一个中英文语音软件,实现了从文本文件到语音并能把文本文件保存为语音文件的功能。     

2,4-二氯苯甲醛的合成研究

2,4-二氯苯甲醛是一种白色或近似白色棱柱结晶,是农药、医药、染料和电镀等行业中一种重要的化工原料。研究了2,4-二氯苯甲醛的合成方法。以2,4-二氯甲苯为原料,经芳甲基二氯化和水解两步反应合成得到2,4-二氯苯甲醛,总收率为79.3%。合成路线中氯化反应温度控制在(140±2)℃,氯化单步收率为96.5%。工艺路线具有原料简单、收率高、操作条件易于控制、三废少的特点。     

合成堇青石研究现状及进展

堇青石具有低的热膨胀系数、较好的抗热震性能等优点,广泛应用于耐火材料,电子封装材料,多孔陶瓷,催化剂载体及红外辐射材料.目前,工业上主要通过人工合成的方法制备堇青石.人工合成堇青石所用原料已在天然矿物原料的基础上,扩大到固体废物等原料,并且已有很多成功的合成实例.与天然产出的堇青石相比,合成堇青石的性能更加优越.从堇青石的合成原料、合成方法及机理、添加剂改性等方面,就其研究进展进行了介绍,并认为加强对其他合成方法及低温合成的研究,加强对改性添加剂及从固体废物中寻找原料的研究是未来的发展趋势.     

电场作用下电流大小对Fe-V-C体系燃烧合成的影响

采用Gleeble-1500D热模拟机,探讨电场下电流大小(1.0×104~2.3×104 A)对Fe-V-C体系燃烧合成的影响。结果表明,在电场作用下,采用此体系可以在较低温度(632~740 ℃)下燃烧合成VC/Fe复合材料,其硬度为60～67 HRC。随电流增大,体系点火温度降低,点火延迟时间缩短,试样的致密性提高,硬度提高。在1.0×104~1.6×104 A电流范围内,产物颗粒尺寸相差不大;在1.6×104~2.3×104 A电流范围内,随电流增大,产物颗粒变大。     

Heat exchanger network synthesis with detailed exchanger designs: Part 1. A discretized differential algebraic equation model for shell and tube heat exchanger design

A new method for the detailed design of shell and tube heat exchangers is presented through the formulation of coupled differential heat equations, along with algebraic equations for design variables. Heat exchanger design components (tube passes, baffles, and shells) are used to discretize the differential equations and are solved simultaneously with the algebraic design equations. The coupled differential algebraic equation (DAE) system is suitable for numerical optimization as it replaces the nonsmooth log mean temperature difference (LMTD) term. Discrete decisions regarding the number of shells, fluid allocation, tube sizes, and number of baffles are determined by solving an LMTD-based method iteratively. The resulting heat exchanger topology is then used to discretize the detailed DAE model, which is solved as a nonlinear programming model to obtain the detailed exchanger design by minimizing an economic objective function through varying the tube length. The DAE model also provides the stream temperature profiles inside the exchanger simultaneously with the detailed design. It is observed that the DAE model results are almost equal to the LMTD-based design model for one-shell heat exchangers with constant stream properties but shows significant differences when streams properties are allowed to vary with temperature or the number of shells are increased. The accuracy of the solutions and the required computational costs show that the model is well suited for solving heat exchanger network synthesis problems combined with detailed exchanger designs, which is demonstrated in Part 2 of the paper.