Solid phase compaction of polymeric powders: effects of compaction conditions on pressure and density variations

In a recent communication it was shown that the pressure losses during the solid phase compaction of a polymeric powder could be predicted from a simple relationship of the form:

$\text{P}{}_2\text{P}{}_1\text{=(K)}{}^{\mathrm{<mtext>h</mtext><mtext>d</mtext>}}$

where $\text{h}\text{D}$ is a function of the geometry of the compact. This has now been explored in more detail and it has been found that for PVdC and PVC the factor K is dependent on the rate of compaction and the die surface finish but is independent of compaction pressure and die diameter. To illustrate the effect of the pressure losses on the structural uniformity of the compacts, microhardness measurements were taken at a large number of points across a section of each sample. A computer plot of hardness contours provided a picture of the homogeneity of the sample which could be related to the compaction conditions and average density of the compact.     

Shear Strength of Pressure Sensitive Adhesives and its Correlation to Mechanical Properties

Correlations between shear resistance and the mechanical properties of pressure sensitive adhesives are studied by measuring the deformation behaviour in the static and the dynamic shear test and determining the dynamic shear modulus of the adhesive. For polymers with low or moderate viscosities, the shear strain vs. time characteristics in a static shear test and, accordingly, the static shear strength, can be evaluated from the master curves of the dynamic shear modulus or the dynamic viscosity. The dynamic shear strength also can be calculated. These exact calculations cannot be applied to highly viscous or slightly crosslinked polymers. On the basis of the model experiments, empirical correlations between shear strength and the dynamic shear modulus are established which seem to be generally valid.     

数字喷泉码及网络喷泉码的最新进展

数字喷泉码和网络编码都是提高网络传输效率的有效技术方法,两者的有机结合形成的网络喷泉码具有重要的理论意义和应用价值。本文首先对数字喷泉码的最新研究进展进行了综述,分别介绍了几类常见的数字喷泉码的相关研究工作;其次对当前网络喷泉码的研究现状进行了系统的总结,重点介绍了同构网络喷泉码、异构网络喷泉码和无线网络喷泉码的相关理论及其最新研究成果,并分析了研究中存在的问题;最后对网络喷泉码的相关理论及其应用的发展趋势进行了分析和展望。     

新型液压胀合有缝不锈钢管衬里复合管的制造技术

针对目前液压生产复合管方法的不足，研制开发了一种新型不锈钢衬里复合管液压胀合装置。介绍了该装置的工作原理和结构特点及液压胀合复合管的制造技术。     

Prediction of the hydraulic diffusivity from pore size distribution of concrete

A model is presented in this work through which variation of hydraulic diffusivity of concrete with relative water content can be obtained from pore size distribution as an input. The specific water capacity and hydraulic conductivity of concrete are expressed in terms of pore size characteristics, considering laminar flow due to capillary suction through tortuous elliptic tubes, oriented equally in three orthogonal directions. Hydraulic diffusivity being the ratio of hydraulic conductivity and specific water capacity is thus expressed in terms of pore size characteristics. The input pore size distributions have been determined experimentally for normal strength concrete mixes through mercury intrusion porosimetry. Using the model the variation of hydraulic diffusivity with relative water content is determined for three cases viz. 1) ideal continuous wetting, 2) ideal continuous drying and 3) random access of pores by water. These results are then compared with an experimentally obtained variation.     

基于溢出性原理的联盟结构生成算法

联盟结构的生成问题中由于搜索空间的联盟结构数目太大,因而搜索联盟结构的最底两层建立一个最坏情况下的边界值是必要的,边界值将最优的联盟结构限制在某个限界内,通过进一步的搜索可以在任意时间内得到一个较优值。根据联盟的溢出性质,文中提出了一种新的建立边界值的方法,即对任意不相交的联盟集合计算其上下边界的值,通过搜索特定的联盟结构集合建立最坏情况下的边界值。联盟的边界值建立以后,可以在任意时间内得到一个较优值,通过搜索剩余的联盟结构集合,可以对边界值和返回的联盟结构进一步优化。在此基础上文中提出了基于溢出性质的任意时间算法。实验结果表明,采用新的方法建立边界值,使得算法的收敛速度更快,效率更高。     

二氧六环在CA低压反渗透膜中的作用机理

在低压醋酸纤维素一丙酮－甲酰胺反渗船舶这膜铸膜液体体系中，加入二氧六环使膜具有较小的初始平均孔径和较窄的孔径分布，二氧六环起到了调节高分子网络尺寸变小和均一化的作用。在１．０ＭＰａ下进料液浓度为１０００ｍｇ／Ｌ时，膜对Ｎａ２ＳＯ４、ＭＧＳＯ４分离率〉９６％，对ＮａＣｌ为８０％，Ｃ（ＮＯ２）２为８０％，ＭｇＣｌ２为７９％。平均透水率〉１．２５ｍｌ／ｃｍ＾２．ｈ适用于中低盐度水的脱盐软化。     

钴基催化剂F-T合成的产物分布及稳定性研究

采用浸渍法制备了氧化锆改性γ-Al2O3负载Co-Ru双金属催化剂.在固定床反应器中考察了反应温度、压力、空速和合成气H2/CO比对烃产物分布的影响,进行了552 h的稳定性实验.结果表明,较低的反应温度、较高的压力和较低的空速有利于碳链增长,产物中柴油馏分C12～C18和蜡C19 的选择性高;原料气H2 / CO比提高,甲烷、C2～C4、C5～C11的选择性增加,C12～C18和C19 的选择性下降;在原料气H2/CO比1.58～2.0、反应温度453～513 K、压力1.0～2.5 MPa和空速500～1000 h(1催化剂具有较好的合成重质烃反应性能.在原料气H2 / CO比2.0、反应温度493K、压力1.5 MPa和空速800 h(1下,反应552 h,催化剂的稳定性较好,CO的转化率、C5 选择性分别大于80%和83%.运行时间对产物烃的分布影响不大,产物烃主要有烷烃组成,主要集中在C5～C18,选择性的平均值C1为6.94%,C2～C4 6.20%,C5～C11 33.04%,C12～C18 31.55%,C19 22.27%.     

合理选择裂隙岩体注浆方法的判据研究

根据弹性变形理论分析了巷道围岩裂隙开度在注浆过程中增大和恢复的机理 ,提出了采用稀水泥浆液注浆时 ,选择常量法和常压法的判断准则 ,给出了使用该判据选择合理注浆方法的步骤     

高压蒸汽发生系统的化学清洗

叙述了洞庭氮肥厂合成氨装置高压蒸汽发生系统以碱洗、酸洗、钝化为主要环节的首次化学清洗工艺，阐述了清洗机理，总结了清洗处理要点。