Nickel-Carnosine complex:A new carrier for enzymes immobilization by affinity adsorption

Immobilization is an effective method to promote the application of enzyme industry for improving the stability and realizing recovery of enzyme.To some extent,the performance of immobilized enzyme depends on the choice of carrier material.Therefore,the development of new carrier materials has been one of the key issues concerned by enzyme immobilization researchers.In this work,a novel organic-inorganic hybrid material,nickel-carnosine complex (NiCar),was synthesized for the first time by solvothermal method.The obtained NiCar exhibits spherical morphology,hierarchical porosity and abun-dant unsaturated coordination nickel ions,which provide excellent anchoring sites for the immobiliza-tion of proteins.His-tagged organophosphate-degrading enzyme (OpdA) and ω-transaminase (ω-TA)were used as model enzymes to evaluate the performance of NiCar as a carrier.By a simple adsorption process,the enzyme molecules can be fixed on the particles of NiCar,and the stability and reusability are significantly improved.The analysis of protein adsorption on NiCar verified that the affinity adsorp-tion between the imidazole functional group on the protein and the unsaturated coordination nickel ions on NiCar was the main force in the immobilization process,which provided an idea way for the develop-ment of new enzyme immobilization carriers.     

 基于混合模型的优化低频低压减载方法研究

文中以低频低压情况下保证电压稳定的前提下减载为研究内容,提出了一种基于混合模型的优化低频低压减载方法。该混合模型将遗传算法与人工神经网络相结合,在保证电压稳定的情况下选择合适的节点进行负荷切除。实验结果表明,该方法可以在低频低压情况下使负荷减载量达到最小。     

MRD减振控制系统的后备混合储能电源设计与仿真

针对磁流变阻尼器MRD(magnetorheological damper)减振控制系统后备电源采用单一蓄电池供电存在响应时间慢和稳定性差问题,提出锂电池/超级电容的后备混合储能电源。首先进行储能系统供电方式的选择及容量配置,然后设计了锂电池和超级电容分别串联双向DC/DC变换器进行功率分配的混合储能结构,再将负载端电流滤波后的高频分量和低频分量用来实现变换器电压电流闭环控制,最后在Matlab/Simulink中搭建混合储能仿真模型,进行输出响应和脉冲功率扰动仿真,对单一锂电池储能和混合储能电源进行性能比较。结果表明,混合储能电源的输出响应时间可达毫秒级;超级电容能提供80%起始功率,并且在脉冲功率扰动下补偿波动功率,以维持母线端稳定,满足MRD减振控制系统的实际工程需求。     

大容量可控关断的直流输电用电流源型换流器研究综述

可控关断的电流源型换流器（current source converter,CSC）相较于LCC和VSC具有较好的技术优势,逆阻型大功率可关断半导体器件的快速发展为CSC在高压直流输电领域的应用提供了发展契机。针对现有CSC的拓扑、调制方法的优缺点进行调研和对比,分析总结出适用于高压直流输电的LCC-CSC拓扑和特定谐波消除调制方法。将基于LCC-CSC的混合直流输电系统与LCC和VSC进行多方位的对比分析,对LCC-CSC的技术优点、存在的问题及未来研究的方向进行了总结,为CSC在高压直流输电的工程应用提供前期研究基础。     

基于混合型Chopper电路的MMC-UPFC故障渡越方案

当交流系统发生短路时,基于模块化多电平控制器的统一潮流控制器(MMC-UPFC)串、并联侧MMC均会受到故障冲击,存在两侧换流器过流闭锁,MMC-UPFC完全退出运行的风险.对此,以交流系统发生最严重的三相短路故障为例,分析了MMC-UPFC串、并联侧MMC故障特性;在此基础上,借鉴风电场交流故障渡越的Chopper电路,并结合MMC-UPFC不同运行方式对故障特性的影响,提出了基于混合型Chopper电路的MMC-UPFC故障渡越方案.该方案能够在交流系统发生故障后隔离并联侧MMC与串联侧MMC之间的联系,从而抑制串联侧馈入并联侧MMC的故障电流.仿真结果表明在MMC-UPFC的不同运行方式下,所提方案均能避免故障后并联侧MMC闭锁,MMC-UPFC将切换至静止同步补偿器(STATCOM)工作模式,为交流系统提供无功功率支撑.     

关注区可变的实时仿真方法与平台

交直流混合电网的实时仿真既要考虑电力电子设备的开关特性,又要保证适应较大的电网规模,在实际工程中面临诸多困难.给子网络赋予动态可变的关注标志,对关注子网络采用存储压力小的节点消去法,对非关注子网络采用计算量少的线性组合法,从而保证骨架型节点电压法的实用性.在Xilinx公司的Virtex-7 FPGA VC709开发板中,采用无缝的并行化仿真计算程序对接方式和灵活的结构参数查询方法解决了现场可编程逻辑门阵列资源的紧缺问题,设计了一种关注区可变的实时数字仿真平台.以典型的交直流混合电网为例,仿真验证了所提方法的可行性与所研发平台的有效性.     

微电网跟踪调度计划双层双时间尺度实时控制策略

为了提升微电网跟踪调度计划的能力,并降低分布式电源和负荷的功率波动对跟踪效果的影响,提出一种利用由超级电容和电池储能组成的混合储能系统跟踪调度计划的双层双时间尺度实时控制策略。上层基于模型预测控制方法建立日内滚动优化模型,结合分布式电源和负荷的超短期功率预测结果,综合考虑一段时域内的跟踪偏差及混合储能系统的功率和荷电状态对跟踪调度计划进行滚动优化;下层在上层优化结果的基础上,采用基于荷电状态的混合储能系统实时控制策略对超级电容和电池储能的实时功率进行协调分配,进一步降低分布式电源和负荷的实时功率波动对跟踪效果的影响。通过仿真算例对所提控制策略进行验证,结果表明:所提策略不但实现了良好的实时跟踪调度计划的控制效果,而且优化了超级电容和电池储能的荷电状态。     

多子微电网型交直流混合配电系统灵活功率控制与电压抑制策略

为了解决多子微电网型交直流混合配电系统功率分配以及交流子微电网母线电压偏差大的问题,提出一种灵活功率控制与电压抑制策略.首先分别推导了单个交流子微电网频率、直流子微电网电压与公共直流母线电压的关系,然后分析多个交直流子微电网之间的频率与电压关系,并利用此关系对交直流子微电网中储能单元的下垂控制进行改进,实现整个系统的功率互助及分配.另外,对双向AC/DC变换器电流内环控制进行改进,利用扩张状态观测器对扰动电流进行跟踪,并将跟踪得到的扰动电流引入双向AC/DC变换器电流内环中进行补偿消除,以抑制交流子微电网的电压波动.最后,在MATLAB/Simulink仿真平台中建立多子微电网型交直流混合配电系统模型,仿真结果表明所提控制方法可以实现交直流混合配电系统中子微电网间的功率互助,较好地维持交流子微电网母线电压和频率、直流子微电网电压与公共直流母线电压的稳定.     

Processing of yttria partially stabilized zirconia thermal barrier coatings implementing a high-power laser diode

Several studies have been undertaken recently to adapt yttria partially stabilized zirconia (YPSZ) thermal barrier coating (TBC) characteristics during their manufacturing process. Thermal spraying implementing laser irradiation appears to be a possibility for modifying the coating morphology. This study aims to present the results of in situ (i.e., simultaneous treatment) and a posteriori (i.e., post-treatment) laser treatments implementing a high-power laser diode. In both cases, the coatings underwent atmospheric plasma spraying (APS). Laser irradiation was achieved using a 3 kW, average-power laser diode exhibiting an 848 nm wavelength. Experiments were performed to reach two goals. First, laser post-treatments aimed at building a map of the laser-processing parameter effects on the coating microstructure to estimate the laser-processing parameters, which seem to be suited to the change into in situ coating remelting. Second, in situ coating remelting aimed at quantifying the involved phenomena. In that case, the coating was treated layer by layer as it was manufactured. The input energy effect was studied by varying the scanning velocity (i.e., between 35 and 60 m/min), and consequently the irradiation time (i.e., between 1.8 and 3.1 ms, respectively). Experiments showed that coating thermal conductivity was lowered by more than 20% and that coating resistance to isothermal shocks was increased very significantly.     

基于一类混合PSO算法的函数优化与模型降阶研究

为了克服传统微粒群优化(PSO)算法容易早熟收敛和陷入局部极小的缺点,通过对PSO算法特点和行为的分析,提出一类有机结合模拟退火(SA)算法和PSO算法的混合算法.混合算法不仅利用PSO的机制进行群体全局搜索,而且利用模拟退火的思想恰当地选择微粒的最好历史位置,保障了群体多样性,并有效平衡了算法的探索和趋化能力,进而改善了算法的优化性能.基于典型复杂函数优化问题和模型降阶问题的仿真结果表明,所提混合算法具有很好的优化质量、搜索效率和鲁棒性.