Hydrothermal Synthesis and Crystal Structure of Lanthanum Orotate Supermolecule with A Honeycomb Structure Constructed from Mononuclear Molecules via Hydrogen Bonds

A new complex of lanthanum orotate [La（C5H3N2O4）2（OH）（H2O）6 ]·2（C5H4N2O4）·9H2O was synthesized using a hydrothermal method. The crystal structure was determined with help of single crystal X-ray diffraction analysis. The complex crystallized in orthorhombic system, Cmc2（1） space group. In the complex, the center lanthanum （Ⅲ） ion was nine-coordinated with coordination geometry of a distorted monocapped square antiprism, in which two of the nine coordinated oxygen atoms were from two orotate ligands in a monodentate mode, one oxygen atom from a hydroxyl, and the others from six coordinated water molecules. The mononuclear complex [La（C5H3N2O4）2（OH）（H2O）6 ]·2（C5H4N2O4）·9H2O was linked through the hydrogen bonds into an infinite supermolecular honeycomb structure.     

Crystal Growth and Properties of Co2+ doped Y3Sc2Ga3O12 Single Crystal

Single crystal of cobalt (Co)-doped Y3Sc2Ga3O12 (YSGG) with the dimensions up to φ20×40mm3 and undoped YSGG crystal with the dimensions up to φ28×60mm3 have been grown using the Czochralski technique. The structure of the crystal was characterized by the X-ray powder diffraction (XRPD) method. The absorbance spectra of the crystal shows that it has strong absorption bands at 606 and 1540nm. The results indicate that the crystal Y3Sc2Ga3O12 may be a kind of good Q-switch material.     

1W2A小角散射光束线的物理设计

本文主要介绍了目前北京同步辐射实验室正在建设的新的小角散射光束线--1W2A的设计方案,以及北京正负电子对撞机二期改造工程完成后该束线能够达到的性能指标.     

Carbon ion-implanted optical waveguides in Nd:YLiF4 crystal: Refractive index profiles and thermal stability

We report on the optical planar waveguides in Nd:YLiF₄ laser crystals fabricated by 6.0 MeV C³⁺ ion implantation at doses of 1 × 10¹⁵ or 2.5 × 10¹⁵ ions/cm², respectively. The refractive index profiles, which are reconstructed according to the measured dark mode spectroscopy, show that the ordinary index had a positive change in the surface region, forming non-leaky waveguide structures. The extraordinary index is with a typical barrier-shaped distribution, which may be mainly due to the nuclear energy deposition of the incident ions into the substrate. In order to investigate the thermal stability of the waveguides, the samples are annealed at temperature of 200–300 °C in air. The results show that waveguide produced by higher-dose carbon implantation remains relatively stable with post-irradiation annealing treatment at 200 °C in air.     

光子晶体光纤拉制参数对包层气孔结构的影响

分析了光子晶体光纤(PCF)拉丝工艺参数对光纤毛细管及最终结构的影响,结果表明,通过调节温度、送料速度和拉制速度等参数可以在一定程度上调整最终的气孔结构,但难以拉制出结构完善的PCF.为此提出了惰性气体施压法,实验表明,通过调节施压量的同时结合上述参数的调节,可有效控制光纤的结构参数,拉制出横纵向均匀性良好的PCF.     

基于PCF实现稳定输出的主动锁模光纤激光器

提出了一种利用高非线性光子晶体光纤(PCF)来稳定主动锁模光纤激光器的方法,理论分析了激光器中PCF的非线性偏振旋转效应(NPR),阐明了激光器稳定的短脉冲输出机理,获得了重复率为5 GHz、脉宽为44ps的稳定短脉冲输出.本文建议的激光器能用于如光码分多址(OCDMA)通信系统等诸多领域.     

催化剂晶体结构对碳纳米管生长影响的微观解释

通过对催化剂晶体结构的分析，讨论了温度对催化剂金属晶格结构的影响，温度对催化剂中碳的溶解度与扩散速度的影响；催化剂金属中其他元素的加入对碳活度的影响，以及析出能量、晶体界面等对碳纳米管生长的影响。温度在1000℃左右时，催化剂金属铁具有面心立方结构，碳管产量比在其它温度下高；催化剂金属中加入其他可提高碳原子活度的元素，可促使碳从催化剂金属中析出，有助于提高碳管的产量。     

Mechanism Oriented Steel Development

The paper discusses how physically based material models can contribute to the development and optimization of new materials. In combination with using enhanced simulation techniques such as density functional theory a true multi scale material development can be established.     

On the Mechanism of Natural Convection and Equiaxed Structure during Dendritic Solidification Processes

A new technique has been developed to generate dendritic‐equiaxed structures in aluminium alloy casting processes, not only to improve the mechanical properties but also to study the effect of crystal structure on the chemical and physical properties of alloys to be cast. The investigation combined laboratory experimental work, metallographic examination and mathematic modelling. The laboratory experimental work involved different superheats for Al‐4.5%Cu alloy in cast ingots. Measurements of temperature distributions were conducted to verify the solidification model. A metallographic study combined macro and micro structural evolution of cast ingot samples. Two‐dimensional mathematical models of fluid flow and heat transfer were developed to characterise the natural convection streams and thermal fields. The model predictions were compared to temperature and isotherms measurements where a good agreement was found. The formation of cast structure and columnar, equiaxed transition (CET) and macro segregation phenomena were studied and discussed, based not only on the theories of nucleation but also on the thermal effects in the mushy and liquid zones.     

用遗传算法搜索一维光子晶体带隙

利用遗传算法和传输矩阵法计算一维光子晶体能带结构,将一维光子晶体用像素填充法进行二进制编码模拟,结果找到全方位相对禁带宽度达42.54%的4层结构和43.75%的2层结构;给出了一维光子晶体4层最佳结构的能带图、20个原胞的反射率透射率频谱图.发现一维2层光子晶体的全方位禁带宽度对每层厚度的变化是不敏感的,但是随着两种介质折射率差的增大而增大.