气相色谱法检测消毒产品中的正丙醇与乙醇

使用HP-Plot Q色谱柱与FID检测器检测消毒剂中复配的正丙醇与乙醇含量,最大方法相对偏差(RSD)为2.14%,最小方法回收率为100.0%,乙醇与正丙醇的检出浓度为0.025%,是一种快速准确的一针检测法。     

电力配电网单相接地故障选线技术的发展

作为供电系统中的重要部分,电力配电网的重要性毋庸置疑。从实际情况来看单相接地故障是配电网建设与使用过程中经常出现的问题,要求专业人员提高对选线环节的重视,选择应用多种科学的选线方法以从根本上降低单相接地故障的发生风险。本文阐述了常见的几种故障选线方法,并就每一种线型的特性进行了分析。     

燃机余热锅炉排烟酸露点温度计算研究

整理分析天然气燃烧产生的烟气酸露点的影响因素,并通过多种方法计算某燃气—蒸汽联合循环机组余热锅炉排烟酸露点温度,总结出一套适用于燃机电厂余热锅炉排烟酸露点温度的可靠计算方法,以降低余热锅炉排烟温度、优化燃机电厂运行方式以及提高机组效率提供计算依据和参考。     

断路器合闸电阻运行可靠性分析及故障诊断技术研究

合闸电阻作为断路器合闸过程中合闸涌流、操作过电压抑制的重要部件,主要应用在800 kV及以上电压等级输电线路与换流变电站交流滤波器场,其特殊的应用环境导致其故障率较均压电容、支撑绝缘件等其他电气部件高。然而,在合闸电阻日常运维与故障诊断过程中,无相应的标准与系统的方法对其是否存在缺陷以及故障后的故障原因进行分析。本文首先对合闸电阻特性参数与工作原理进行介绍,之后对串联结构断路器与并联结构断路器分别进行运行可靠性与故障诊断技术研究。提出了动态电阻拟合、声振信号检测、绝缘性能测试、热容量测试等断路器运行过程中合闸电阻状态监测方法,以及基于ICP的合闸电阻堆拼接、应力特性分析、电场仿真等合闸电阻故障诊断方法,最后通过设备解体验证了所提方法在合闸电阻运行状态检测过程中的可行性。     

配电网弧光接地故障建模仿真与实验研究综述

弧光接地故障是配电网中最常见的故障,不易被发现且危害巨大,产生机理复杂,特征具有随机性。针对上述问题,从配电网弧光接地故障产生的原因和危害、弧光接地故障数学模型、弧光接地故障抑制和保护策略、弧光接地故障识别和定位技术、以及弧光接地故障的物理模拟实验与仿真测试等方面进行了阐述,对国内外的研究现状进行了总结和分析。并对配电网弧光接地故障的研究方向进行了展望,提出了从故障模型研究和数字仿真软件的开发、抑制策略研究和装置的研发、故障识别定位和保护策略、物理模拟和数模混合仿真测试技术4个方面建立配电网弧光接地故障研究框架。     

Radiation-absorption,chemical reaction,Hall and ion slip impacts on magnetohydrodynamic free convective flow over semi-infinite moving absorbent surface

The investigation of radiation-absorption,chemical reaction,Hall and ion-slip impacts on unsteady MHD free convective laminar flow of an incompressible viscous,electrically conducting and heat generation/absorbing fluid enclosed with a semi-infinite porous plate within a rotating frame has been premeditated.The plate is assumed to be moving with a constant velocity in the direction of fluid movement.A uniform transverse magnetic field is applied at right angles to the porous surface,which is absorbing the fluid with a suction velocity changing with time.The non-dimensional governing equations for present inves-tigation are solved analytically making use of two term harmonic and non-harmonic functions.The graphical results of velocity,temperature and concentration distributions on the analytical solutions are displayed and discussed with reference to pertinent parameters.It is found that the velocity profiles decreased with an increasing in Hartmann number,rotation parameter,the Schmidt number,heat source parameter,while it increased due to an increase in permeability parameter,radiation-absorption param-eter,Hall and ion slip parameters.However,the temperature profile is an increasing function of radiation-absorption parameter,whereas an increase in chemical reaction parameter,the Schmidt num-ber Sc or frequency of oscillations decrease the temperature profile on cooling.Also,it is found that the concentration profile is decreased with an escalating in the Schmidt number or the chemical reaction parameter.     

Exploring the methods on improving CH4 delivery performance to surpass the Advanced Research Project Ageney-Energy target

CH_4 storage associated with adsorbed natural gas(ANG) technology is an issue attracting great concern.Following the Advanced Research Project Agency-Energy(ARPA-E) targeted deliverable capacity of 315 cm~3·cm~(-3)(STP), hundreds of thousands of materials have been experimentally or theoretically evaluated,while the best results still show a 35% gap from the target. Moreover, recent theoretical research reveals that the target is beyond the possibility that real materials can be designed. To get rid of the awkward situation, we make attempts on investigating the CH_4 delivery performance under other operation conditions. Methods of raising the discharge temperature(to infinite high) or elevating the storage pressure(to 25 MPa) have been proved to show limited effectiveness. In this work, it is found that the ARPA-E target can be achieved by using a decreasing storage temperature strategy. By taking 280 Co RE(computation-ready, experimental) COFs(covalent organic frameworks) as ANG materials, when reduce the storage temperature to 190.6 K, the highest deliverable capacity can reach 392 cm~3·cm~(-3)(STP), and16.1% Co RE COFs can surpass the target. The target is also achievable when storage at 220 K. Structure performance relationships study shows strong correlation between deliverable capacity and void fraction. Hence, 120 hypothetical COFs are generated to ascertain the optimum void fraction. In addition,the performance of 2 D-COFs can be greatly enhanced by increasing the interlayer spacings, e.g. CH_4 deliverable capacity(storage at 190.6 K) of ATFG-COF can be improved from 239 to 411 cm~3·cm~(-3)(STP) when interlayer spacing is enlarged to 1.65 nm.     

多回路冷凝法技术在聚丙烯装置尾气回收中的应用

陕西延长石油集团炼化公司延安石油化工厂,结合其20万t/a聚丙烯装置实际,自主开发出了一种多回路冷凝装置尾气的回收工艺技术,并成功工业化应用于该装置的3路丙烯尾气的冷凝回收系统。近5年的运行结果表明:经多种措施及操作优化后,该3路冷凝丙烯尾气回收系统,不仅实现了长周期连续平稳、安全运行,还可有效回收丙烯、丙烷分别约为2660,140 t/a。     

集成行波测距功能的高压输电线路保护装置的技术探讨

以集成行波测距功能的高压线路保护装置为目标,提出了装置的总体硬件架构设计方案和行波测距软件的整体实现方案,并利用线路保护的判别信息提高了行波测距功能的可靠性,在不影响继电保护性能的基础上实现了行波测距功能与保护功能的整体融合,为提高输电线路保护装置的测距性能提供了技术保证,仿真结果验证了该集成技术的可行性。集成了行波测距的线路保护装置能实时精确定位线路故障点,大大减少人工巡线的工作量,缩短了故障修复时间,提高了供电可靠性。     

一种基于图计算的电力系统故障建模方法

故障建模是电力系统仿真分析的重要基础,如何快速准确对某类（N-1、N-2等）故障进行建模一直困扰电网分析人员。首先,分析了电力系统故障建模需要考虑的故障发展路径、故障动作时序两个要素,其中故障发展路径的搜索是故障建模的难点;其次,结合电力系统数据结构特征,提出了基于图计算的电力系统故障建模方法;最后,通过一个规模较大的省级电网验证了所提方法的有效性。在未来“双碳”“双高”电力系统发展的背景下,所提方法为电力系统在线、离线仿真分析所依赖的全网故障建模提供了新的思路和工具。