Si衬底上横向外延GaN材料的微结构和光学性质的研究

用氢化物气相外延 (HVPE)方法在Si(III)衬底上成功横向外延生长出晶体质量较好的GaN薄膜材料。透射电子显微镜 (TEM )的研究结果表明 ,横向外延区域GaN的位错密度明显减小。由于SiO2 掩膜腐蚀角的不同 (分别为 90°和 6 6°) ,导致了横向外延GaN材料一些独特的微观形貌。微区拉曼光谱由数百条拉曼散射曲线组成 ,每一条曲线有三个振动模 ,分别对应Si振动模式 (5 2 0cm- 1) ,E2 模式 (5 6 6cm- 1)和E1(LO)模式(732cm- 1)。在垂直条纹方向 ,峰位和峰宽没有明显的变化 ,而峰强约 5 μm会发生周期性变化     

迫零对Turbo码的性能影响

从距离谱的角度对迫零在Turbo码中的作用进行了理论分析。通过仿真，研究了迫零对Turbo码性能的影响。仿真结果表明，Turbo码编码器迫零处理有助于改善Turbo码的性能。     

数字放大器—3G无线基站的助推器

为了构筑第三代无线网络,人们需要对现有基础设施进行彻底改造,包括网络的发射基站。配置在无线基站中的新型数字控制功率放大器能够改善频谱利用率和功率效率,从而提高系统容量。PMC-Sierra公司的数字控制功率放大器采用了数字校正信号处理器(DCSP)以及自适应控制处理器和补偿估值器(ACPCE),该放大器可改善无线基础设施的可靠性,同时降低系统成本、规模及复杂性。     

The Effect of Polymer Optoelectronic Properties on the Performance of Multilayer Hybrid Polymer/TiO2 Solar Cells

We report a study of the effects of polymer optoelectronic properties on the performance of photovoltaic devices consisting of nanocrystalline TiO₂ and a conjugated polymer. Three different poly(2‐methoxy‐5‐(2′‐ethylhexoxy)‐1,4‐phenylenevinylene) (MEH‐PPV)‐based polymers and a fluorene–bithiophene copolymer are compared. We use photoluminescence quenching, time‐of‐flight mobility measurements, and optical spectroscopy to characterize the exciton‐transport, charge‐transport, and light‐harvesting properties, respectively, of the polymers, and correlate these material properties with photovoltaic‐device performance. We find that photocurrent is primarily limited by the photogeneration rate and by the quality of the interfaces, rather than by hole transport in the polymer. We have also studied the photovoltaic performance of these TiO₂/polymer devices as a function of the fabrication route and device design. Including a dip‐coating step before spin‐coating the polymer leads to excellent polymer penetration into highly structured TiO₂ networks, as was confirmed through transient optical measurements of the photoinduced charge‐transfer yield and recombination kinetics. Device performance is further improved for all material combinations studied, by introducing a layer of poly(ethylene dioxythiophene) (PEDOT) doped with poly(styrene sulfonic acid) (PSS) under the top contact. Optimized devices incorporating the additional dip‐coated and PEDOT:PSS layers produced a short‐circuit current density of about 1 mA cm^–2, a fill factor of 0.50, and an open‐circuit voltage of 0.86 V under simulated AM 1.5 illumination (100 mW cm^–2, 1 sun). The corresponding power conversion efficiency under 1 sun was ≥ 0.4 %.     

Head-to-head polymers: 33. Bromination of cis-1,4-polybutadiene to head-to-head poly(vinyl bromide)

Cis-1,4-polybutadiene (PB) in a 0.5% solution of a solvent mixture of dichloromethane and 1,2-dibromoethane or tetrahydrofuran was quantitatively brominated with elemental bromine at 0°C under careful exclusion of oxygen to head-to-head poly(vinyl bromide). Partially brominated PB has a structure of random or block sequences of butadiene units in the polymer depending on the bromination solvent but shows no stereospecificity in the CHBrCHBr-dyads. Partially brominated PB with block structure showed a microphase-separated morphology over a wide range of composition. Microphase separation is less pronounced for the more random structure of butadiene units. I.r and ¹³C n.m.r. spectroscopy of the partially brominated PB was used to follow the progress of the bromination.     

Melting and crystallization behaviour of elastoplastic semicrystalline copolymers: poly(ether ester)

The melting and crystallization behaviour of an elastoplastic semi-crystalline poly(etherester) has been studied by differential scanning calorimetry. The shape of the melting endotherm is strongly dependent on heating rate and annealing time and results from the sum of simultaneous melting and crystallization phenomena. Samples prepared by different techniques, i.e. by solvent evaporation or by melt extrusion, behave very differently owing to specific crystal morphologies. By applying the Hoffman-Weeks plot, the equilibrium melting temperature has been extrapolated. The Avrami treatment allows the calculation of the index n and of the rate constant K from the isothermal kinetic data.     

改进的用于半导体器件综合系统的遗传算法

本文对应用于器件综合系统的遗传算法GENOCOP进行了改进.将实数设计空间根据参数的工艺精度影响转换为整型空间,并加入适应性复合算子利用已经得到的点来扩展和开发准可行空间.使其保持有效搜索到可行解的特性的同时,在同等的算法设置下,提高了对可行空间的覆盖率(约2.87倍),可以帮助设计人员更有效的设计可工作的器件.     

修正步冷温度曲线试验研究

按修正步冷温度曲线对经步冷脆化的 2 .2 5Cr 1Mo和在加氢反应器内运行 5a的 2 2 5Cr 1Mo试块进行了修正步冷试验 ,评定了材料的回火脆性。结果表明 ,按修正步冷曲线进行修正步冷试验能使已经脆化的材料进一步脆化 ,为加氢反应器材料损伤的研究提供了一条途径。     

HAT循环构成热电冷三联产总能系统的可行性分析

对国内外在提高能源利用率方面的研究现状和发展趋势进行了综述，在前人研究的基础上提出以湿空气透平湿空气透平（HAT）循环构成热、电、冷三联产总能系统的能量利用形式，详细分析了构成该系统的相关技术、可行性及需要加以解决的几个问题。     

平纹织物复合材料的弹性模量预测

利用细观力学的代表体积元(RVE)法,预测了平纹织物复合材料的弹性模量。建立了表征RVE形态的数学模型,分析了细观结构与宏观性能之间的关系,编制了从组分材料的弹性性能推测复合材料的弹性性能的预测程序。对理论预测进行了实验验证,理论值与实测值在一定误差范围内能较好吻合,说明此预测方法具有一定的可靠性。