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51.
Angela S. Rocha Arnaldo C. Faro Jr. Laetitia Oliviero Jacob Van Gestel Franoise Maug 《Journal of Catalysis》2007,252(2):321-334
The activity of NiMoS catalysts supported on niobia, alumina, and niobia/alumina was compared for the thiophene hydrodesulfurization (HDS) and 2,6-dimethylaniline (2,6-DMA) hydrodenitrogenation (HDN) reactions. To evaluate the acidity of the supports and identify the nature of the sulfide sites, adsorption of 2,6-dimethylpyridine, pyridine, and CO was performed and followed by IR spectroscopy. This study has shown that with niobia as a support, the activity of NiMoS catalysts in thiophene HDS and in HDN of 2,6-DMA was no longer promoted by the synergy between Ni and Mo. The absence of synergy between molybdenum and nickel on niobia can be explained by the strong interaction of each metal with niobia at the expense of interaction with each other. Moreover, it has been shown that on a niobia/alumina support, the formation of the NiMoS phase can be directly linked to the presence of alumina not covered by niobia. However, niobia is an interesting support for the HDN of 2,6-DMA, because it favors the formation of xylene through direct ammonia elimination involving low H2 consumption. The activity for xylene formation on niobia is linked to the electron-deficient nature of the Mo sulfide site, as demonstrated by CO adsorption followed by IR. 相似文献
52.
53.
单轴红外姿态测量系统在测量小型无人机姿态角时存在盲区,通过增加一组与原轴线相垂直的红外传感器,形成双轴姿态测量系统,对盲区进行补偿。两组红外传感器一定有一组位于倾角可测区域,通过测试目标轴的输出温差的大小,判断位于可测区域的轴线,可实现对目标轴姿态角的解算。首次采用数字式输出红外热电堆传感器设计实现了180°无盲区的姿态角测量模块,经过测试,其静态误差小于2°。 相似文献
54.
Jing Zhang 《Electrochimica acta》2006,51(20):4262-4270
A copolymer, poly(aniline-co-m-aminophenol), has been synthesized using repeated potential cycling. The monomer concentration ratio, acid concentration and applied potential strongly affect the copolymerization rate and the properties of the copolymer. The optimum conditions for the copolymerization are that the scan potential range is controlled between −0.10 and 0.95 V (vs.SCE), and a solution consists of 0.34 M aniline, 0.012 M m-aminophenol and 2 M H2SO4. The IR spectra of the copolymers demonstrate that the m-aminophenol units are included in the copolymer chains. The cyclic voltammograms of the copolymers in 0.3 M Na2SO4 solution with various pH values were performed at the potential ranges from −0.20 to 0.80 V and at a scan rate of 60 mV s−1. The results indicate that the copolymer still hold 41.7% of the electrochemical activity when the copolymer electrode was transferred from a solution of pH 5.0 to a solution of pH 11.0 in the potential range of −0.20 to 0.80 V. An impedance plot of the copolymer in a solution with pH 12.0 and at 0.40 V is constructed of a semicircle and a Warburg line with a slope of 1. This means that the electrode reaction of the copolymer at pH 12.0 is also under mass transfer control. The conductivity of the copolymer prepared under the optimum conditions is 1.42 S cm−1, and slightly depends on the pH value. Thus, the pH dependence of the electrical properties of the copolymer is improved compared with poly(aniline-co-o-aminophenol), and is much better than that of the parent polyaniline. 相似文献
55.
Keiji Kunimatsu Takahiro Senzaki Minoru Tsushima Masatoshi Osawa 《Electrochimica acta》2007,52(18):5715-5724
Hydrogen evolution reaction (HER) on a polycrystalline Pt electrode has been investigated in Ar-purged acids by surface-enhanced infrared absorption spectroscopy and electrochemical kinetic analysis (Tafel plot). A vibrational mode characteristic to H atom adsorbed at atop sites (terminal H) was observed at 2080-2095 cm−1. This band appears at 0.1 V (RHE) and grows at more negative potentials in parallel to the increase in hydrogen evolution current. Good signal-to-noise ratio of the spectra enabled us to establish the quantitative relation between the band intensity (equivalently, coverage) of terminal H and the kinetics of HER, from which we conclude that terminal H atom is the reaction intermediate in HER and the recombination of two terminal H atoms is the rate-determining step. The quantitative analysis of the infrared data also revealed that the adsorption of terminal H follows the Frumkin isotherm with repulsive interaction. 相似文献
56.
In addition to molecular interaction and physical entanglement of the molecular chains across the interface in poly (vinyl chloride)-nitrile rubber joints, at high temperatures and long contact times interfacial chemical bonds may be formed which seem to couple the two adherends thereby resulting in cohesive failure of the rubber matrix on peeling. This is verified by performing the peel tests at high temperatures, low peel rates and under swollen conditions. Infrared spectroscopic studies of the PVC/NBR blend reveal the formation of chemical bonds at the contact temperatures studied. The peel fracture energy is found to depend on the acrylonitrile content and presence of carboxylic content in the NBR, and the presence of stabilizer and plasticizer in the PVC phase, in addition to the molding and testing conditions. 相似文献
57.
为了减少非视距(NLOS)误差对基于到达时间(TOA)的无线定位系统性能的影响,本文提出一种采用接收信号强度(RSS)与TOA测量值相结合的方法对含有NLOS误差的TOA测量值进行检测并修正。在视距(LOS)传播的TOA与RSS之间关系已知的前提下,利用定位基站得到的TOA与RSS测量值,计算TOA测量值中含有NLOS误差的可能性,并利用该可能性对TOA测量值进行修正。该方法在不增加通信次数的情况下,大大提高了定位精度。本文最后在一个无线定位系统上实现了该算法,并进行了对比实验。实验结果表明,该算法不需对多次定位结果进行统计,即可有效降低NLOS误差对系统性能的影响,适用于对功耗要求苛刻的场合。 相似文献
58.
考察了苯乙烯类嵌段共聚物对IR/CR二元共混物相态结构及粒子尺寸的影响。结果表明,加入苯乙烯类嵌段共聚物可有效改善IR/CR共混物的分散状态,在任何组成下均可降低分散相粒子尺寸,促进体系均匀分散,其中苯乙烯-异戊二烯共聚物的效果最为理想,其最佳用量为3~7份。 相似文献
59.
The interaction of nitric oxide with Ce0.75Zr0.25O2 solid solution were investigated by means of EPR and IR spectroscopies. The influence of adsorption parameters such as adsorption temperature and pressure, presence of the O2 co-reactant on the nature and relative surface abundance of the resultant mono- and dimeric NO species was elucidated. The thermal stability of the surface nitrosyl complexes and their reactivity toward dioxygen were also examined. 相似文献
60.
本文通过多种分析测试手段,详细研究了环型聚苯乙烯(RPS)分子链结构、聚集态结构、热性能及稀溶液性质,并与线型聚苯乙烯(LPS)作了对照。结果表明:RPS链结构确为环状结构,由于链结构不同于LPS,因此链刚性及其随分子量的变化关系也不同于LPS,这是导致其性质与LPS存在很大差异的根本原因。RPS链堆积较LPS松散,由于线团密度RPS大于LPS,所以宏观上二者比容并无多大差异,但RPS比容受分子量影响较LPS大。RPS的Tg随分子量变化关系受自由体积和构象熵即链刚性两种因素的影响。动态光散射及小角X光散射实验结果说明,RPS的扩散行为、流体力学半径和无扰分子尺寸与LPS相比有很大不同。 相似文献