Combination of nuclear magnetic resonance spectroscopy and nonlinear methods to analyze the copolymerization of phosphonic acid derivatives

We demonstrate in this study that the combination of modern inline monitoring methods [here: inline nuclear magnetic resonance (NMR)] with simulations gains more exact and profound kinetic results than previously used methods like linearization without that combination. The ¹H-NMR spectroscopic data (more than 100 data points) are used to construct the copolymerization diagram. The reactivity ratios are obtained applying the van Herks nonlinear least square method. The examination of the radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) with (2-{[2-(ethoxycarbonyl)prop-2-en-1-yl]oxy}ethyl) phosphonic acid (ECPPA) as important adhesive monomer used in dentistry yields reactivity ratios of r_HEMA = 1.83; r_ECPPA = 0.42. The copolymerization diagram reflects nonideal, non-azeotropic copolymerization. The sequence distribution of the obtained by Monte Carlo simulation indicates the generation of statistical copolymers. As an important finding, it is demonstrated that the repeating units responsible for etching and adhesion are arranged over the whole polymer chain, which is necessary to achieve proper functionality. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48256.     

注采比对“二三结合”开发模式渗流特征的影响

大庆油田的开发逐渐进入高含水阶段,厚油层动用程度低,"二三结合"开发模式是有效的提高厚油层动用程度,改善水驱开发效果,提高油田采收率的有效手段。在"二三结合"开发模式注聚阶段中注采比对井间压力、含水饱和度等变化有重要影响。为了探究注采比对开发层位的井间压力及饱和度的影响,利用油藏数值模拟方法,模拟了相同的开发模式不同注采比的生产情况,绘制了不同注采比情况下,不同层位的井间压力及含水饱和度变化情况,为维持地层压力平衡,保持油田稳定生产提供有力的依据。     

Annular‐ring slot antenna designs with circular polarization radiation

The design of a microstrip‐fed annular‐ring slot antenna (ARSA) with circular polarization (CP) radiation is initially studied. To obtain CP radiation with broad 3‐dB axial ratio (AR) bandwidth that can cover the WiMAX 2.3 GHz (2305–2320 MHz, 2345–2360 MHz) and WLAN 2.4 GHz (2400–2480 MHz) bands, a novel technique of extending an inverted L‐shaped slot from the bottom section of the annular‐ring is proposed. To suppress the harmonic modes induced by the CP ARSA, the technique of integrating a defected ground structure into the annular‐ring slot is further introduced. From the measured results, 10‐dB impedance bandwidth and 3‐dB AR bandwidth of 44.86 and 9.68% were achieved by the proposed harmonic suppressed CP ARSA. Furthermore, average gain and radiation efficiency of ～4.7 dBic and 71%, respectively, were also exhibited across the bands of interest. © 2014 Wiley Periodicals, Inc. Int J RF and Microwave CAE 25:337–345, 2015.     

A Multiscale-Porous Anion Exchange Membrane for Convenient and Scalable Electrokinetic Concentration of Cationic Species

A device able to electrokinetically concentrate cationic samples has many potential medical and industrial applications, but until now has remained undeveloped due to the lack of a commercial anion-permselective material leading to a prohibitively complex fabrication procedure. Herein, a novel multiscale-porous anion exchange membrane (MP-AEM) that enables the convenient and scalable electrokinetic concentration of cationic species is proposed. A mechanically enhanced multiscale-porous structure with a solid framework is realized by adopting polyester resin as an additive to overcome the intrinsic limitations of the AEM material. The scalable MP-AEM-embedded electrokinetic concentrator is devised based on the peculiar properties of the MP-AEM that for allow both ion and fluid transport. With the MP-AEM, the concentrator is fabricated in a highly streamlined manner consisting only of a simple insertion and assembly. The concentration performance of the MP-AEM-embedded electrokinetic concentrator is demonstrated with a positively charged fluorescent dye and a fluorescein-labeled protein, and the results show enrichment factors of 250 and 500, respectively. The MP-AEM makes cationic electrokinetic concentration more accessible and scalable, thereby enabling further progress in a wide range of fields.     

海面油膜的偏振反射特性仿真实验

为了给海面溢油污染识别检测提供理论基础,根据菲涅尔反射公式的偏振反射系数,结合偏振双向反射率因子和粗糙海面的概率密度分布函数,建立了完善的pBRDF模型,仿真在不同太阳入射角度、不同探测器观测角度以及不同海面风速风向等条件下海水和油膜的偏振反射分布函数。结果表明:海水和油膜太阳天顶角为53°和56°时P偏振反射率分别为1.0×10^-5和2.5×10^-5,S偏振反射率随着太阳天顶角的增加而增加;海面风速越大偏振反射率峰值越小;海面风向只改变pBRDF的空间位置;海水和油膜线偏振度空间分布有明显差异。搭建实验平台相机以40°拍摄时,得出海水和油膜的线偏振度分别在0.2~0.4, 0.5~0.7之间,同时表明利用偏振探测获取目标场景的偏振度和偏振角图可提高图像质量。     

Stability and thermophysical properties of fly ash nanofluid for heat transfer applications

Improving the performance of heat transfer fluids is altogether significant. The best approach for improving the thermal conductivity is the addition of nanoparticles to the base fluid. In the present study, specific heat, dynamic viscosity, and thermal conductivity of water-based Indian coal fly ash stable nanofluid for 0.1% to 0.5% volume concentration in the temperature range of 30 to 60°C has been investigated. To evaluate an average particle diameter of 11.5 nm, the fly ash nanoparticles were characterized with scanning electron microscopy and dynamic light scattering. Using zeta potential, the stability of nanofluid in the presence of surfactant Triton X-100 was tested. Thermal conductivity and viscosity of fly ash nanofluid increased, while specific heat decreased as volume concentration increased. The effect of temperature on the fly ash nanofluid was directly proportional to its thermal conductivity and specific heat and inversely proportional to viscosity.     

多带OFDM-UWB系统峰均功率比降低方法研究

针对多带OFDM—UWB信号存在高峰均功率比的问题，提出了利用扩展与交织降低系统信号峰均功率比的方法。该方法通过对传输数据进行正交扩展与交织，使得进入多载波调制的数据趋于高斯分布，减小了传输数据自相关函数的旁瓣峰值，降低了OFDM-UWB信号的峰均功率比。由于采用正交矩阵进行扩展，扩展前后的数据传输速率保持不变。仿真结果表明，扩展与交织可以有效地降低信号峰均功率比2-5dB左右。同时该方法还具有抗窄带干扰的鲁棒性。     

ZnO基薄膜晶体管的研究

ZnO是一种宽带隙的光电半导体材料,能应用于很多领域,如可用在压敏变阻器、声表面波器件、气敏元件、紫外光探测等。ZnO也可以作为有源层应用于薄膜晶体管(TFT)中。ZnO基薄膜晶体管具有以下突出优势:对于可见光部分平均具有80%以上的透射率,迁移率可以高达36cm2/V·s,开/关电流比大于106,可在较低温度(甚至室温)下制备。基于这些优点,ZnOTFT具有取代有源矩阵液晶显示器中常规a-SiTFT的趋势。同时对ZnOTFT的研究也推动了透明电子学的发展。本文阐述了ZnOTFT优越的电学性能,指出了其目前尚存在的不足,并对其发展前景进行了展望。     

提高催化裂化装置(FCCU)柴汽比措施

为了满足市场的需要,中石化天津分公司炼油厂根据FCCU自身特点采取了一系列提高柴汽比的措施,包括:调节反应系统和分馏的操作条件及采用MGD技术,以提高柴油产率。实施后,FCCU的柴汽比从0.5提高到0.9,创造了良好的经济效益。     

一种用于微波射频识别卡的圆极化微带天线

本文设计了一种用于微波非接触式射频识别卡的圆极化微带天线 ,采用AnsoftEnsemble7.0和Optimetrics模块分别进行仿真和优化 ,使输入、输出端口驻波比 ,左、右旋圆极化隔离度等参数满足系统性能要求。对加工的样品进行测试 ,结果显示 ,天线中心谐振频率为 5 .8GHz,左、右旋圆极化隔离度约 2 0dB ,天线有效方向角6 0° ,天线增益为 5dBi,达到实用化要求