Relationship between the microstructure and reaction performance of aluminosilicate

A systematic study was conducted to comprehend the mechanism of thermal activation of silica-alumina materials by using 29 Si and 27 Al magnetic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy.The reaction performance of silica-alumina-based materials with different molar ratios of Si/Al,which were thermally activated,was also investigated.With the increase in calcining temperature,the coordination of Al in metakaolin becomes four,five,and six firstly,and then transforms completely to four ...     

TE103单模谐振腔的计算模拟及优化

对TE103单模谐振腔中电磁波的分布进行了数值计算;推导出了麦克斯韦方程在谐振腔内电磁场分布的数学表达式;采用Ansoft软件对腔体中的电磁分布进行模拟并对腔体的尺寸进行优化．根据模拟的电场的形状以及其它相关的数据来判断此时反应器形状和性能．数值模拟结果表明,空腔有三个大小相近的电场均匀区域,在匹配情况下,谐振腔的固有品质因素相对较高．计算模拟结果与实验结果吻合较好,验证了计算和模拟的正确性,为设计高质量的谐振腔提供了参考依据．     

风力发电机锥筒型塔架的模态分析

应用SAP2000有限元分析软件对某定型风力发电机组塔架建模并进行模态分析,研究了有无门洞两种塔架的固有频率及其与风轮转动频率的关系,通过对塔架固有频率影响因素的探讨,得到了一些基础性结论.分析表明：塔架的固有频率每两阶基本相等;门洞对塔架固有频率的影响很小;塔架一阶固有频率与机头质量基本呈线性关系递减;能否引起塔架与风轮激励的共振主要取决于塔架的低阶频率.研究成果可为风力发电机锥筒型塔架的设计提供参考.     

一种基于线性系统随机共振的弱信号检测方法

从工程中经常碰到的噪声背景下弱信号检测的实际需求出发,提出一种基于线性系统随机共振的弱信号检测方法,与传统的非线性系统随机共振相比,此方法计算量小、检测速度快。采用MATLAB配用的SIMULINK软件,建立线性系统随机共振仿真模拟图,通过调节系统参数或噪声强度,使系统噪声及激励信号达到最佳匹配,从而实现弱信号的检测。仿真结果表明该方法具有可行性。     

Bifurcation analysis for an SMIB power system with series capacitor compensation associated with sub-synchronous resonance

In this paper,an introduction to the bifurcation theory and its applicability to the study of sub-synchronous resonance (SSR) phenomenon in power system are presented. The continuation and bifurcation analysis software AUTO97 is adopted to investigate SSR for a single-machine-infinite-bus power system with series capacitor compensation. The investigation results show that SSR is the result of unstable limit cycle after bifurcation. When the system exhibits SSR, some complex periodical orbit bifurcations, such as torus bifurcation and periodical fold bifurcation, may happen with the variation of limit cycle. Furthermore, the initial operation condition may greatly influence the ultimate state of the system. The time-domain simulation is carried out to verify the effectiveness of the results obtained from the bifurcation analysis.     

谐振式无线电能传输系统串联式模型仿真研究

谐振式无线电能传输系统具有高效率、远距离、大功率的特点.串联式模型负载反射阻抗为纯阻性,便于系统设计,且其模型结构适合小负载研究.为优化设计无线电能模型,提出以串联式模型(SSSS:Series Model)为分析对象,从等效电路的角度研究系统传输效率、输出功率与共振线圈距离、负载电阻、谐振频率之间的关系,理论分析了线圈之间的距离、负载电阻、谐振频率对输出功率和传输效率的影响,并直接利用电流推导出效率及功率的计算式,最后通过Matlab工具仿真验证了上述模型的正确性,并得出了在允许的频率范围内,谐振频率越大,效率、功率不断提高的结论,为谐振式无线电能传输系统仿真模型研究和设计提供了参考和借鉴.     

一类非线性网络系统中噪声改善信号的相关性

基于相关系数研究了在一类非线性神经网络系统中加性和乘性噪声作用下的阈上随机共振现象。仅在加性噪声或者乘性噪声的作用下,对每一个固定的系统阈值,加性噪声下的阈上随机共振比乘性噪声下的阈上随机共振更容易发生,且相关系数所达到的峰值也比在乘性噪声下的峰值大,这说明加性噪声更有利于改善信号的相关性。系统阈值的增加会降低阈上随机共振的功效;而阈值单元数目的增多,会提高阈上随机共振的功效。加性和乘性噪声共同作用下的阈上随机共振现象同样存在,对系统阈值进行恰当选取和增加系统阈值单元数目使得阈上随机共振现象更加明显;给定乘性噪声而改变加性噪声比固定加性噪声而改变乘性噪声阈上随机共振更容易发生,且功效更好。     

磷改性ZSM-5分子筛物化性质和裂解制乙烯性能的研究

The physicochemical features of phosphorus-modified ZSM-5 zeolites (SiO2/Al2O3 molar ratio is 25) were characterized by XRD(X-ray diffraction), BET(Brunauer, Emmett and Teller spcific surface area measurement), NH3-TPD(ammonia temperature-programmed desorption) and MASNMR(magic angle spinning nuclear magnetic resonance), and the performance on catalytic pyrolysis to produce ethylene was investigated with a light hydrocarbon fixed bed micro-reactor with n-octane as feed. The results show that the acid site density, acid intensity and hydrothermal stability of ZSM-5 zeolite were improved by phosphorus modification. When P205 content in ZSM-5 zeolite is higher than 2.5%, phosphorus modification can prevent ZSM-5 zeolite crystal structure transformation from orthorhombic to monoclinic. In addition, the dealumination of ZSM-5 zeolite framework was moderated by phosphorus modification under high temperature hydrothermal treatment. The results of n-octane pyrolysis on phosphorus-modified ZSM-5 zeolites show that ethylene yields of zeolites with different phosphorus content are almost the same under the same n-octane conversion. However, the modified zeolites with higher pyrolysis activity give lower yield of propene, butene and total olefin than lower pyrolysis activity under the same n-octane conversion.     

Synthesis and photo-induced solution properties of new rigid-rod polyimides

A series of new, substituted pyromellitic dianhydrides were synthesized from 1,2,4,5-tetramethylbenzene. New soluble rigid-rod polyimides were obtained from the dianhydrides and 2,2′-bis(trifluoromethyl)-4,4′-biphenyl (PFMB) in phenolic solvents in the presence of isoquinoline as a catalyst. The polyimides are soluble in N-methyl-2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAc), m-cresol and other solvents, in spite of having no bending in their rigid structures.

UV irradiation changed color of the polyimide solutions and also their viscosity. We observed new absorbance in the 700-nm region and an ESR signal by UV irradiation. The new visible absorbance and the ESR signal are derived from the same origin. They are attributed to the anion radical of the diimide moiety in the polyimide as deduced from the hyper fine structure of the ESR signal. In addition, UV irradiation diminishes the solution viscosity.     

Structural characterization of 1,2-polybutadiene by 13C-n.m.r. spectroscopy: 2. Sequence distribution of 1,2-unit in hydrogenated polybutadienes

The configurational sequences of 1,2-unit in a series of hydrogenated syndiotactic 1,2-polybutadienes were determined in relation to the sequence distribution of 1,2- and 1,4-units on the basis of the ¹³C-n.m.r. signal assignment of the methyl carbons. The observed triad distributions of 1,2- and 1,4-units and configurational distributions of the 1,2-unit are in good agreement with the calculated distributions from transition probabilities. The number average sequence lengths of the 1,2-unit and the 1,2-unit in the racemic addition are 5.7 to 8.0 and 4.1 to 5.4, respectively. From the extrapolation of the plot of the number average sequence length against the crystallinity of the starting 1,2-polybutadienes, the minimum sequence length for crystallization is estimated to be 3.7 for the 1,2-unit in the racemic addition.