Viscoelastic behavior of poly(butyl methacrylate) densely grafted on silica nanoparticles

A series of poly(butyl methacrylate)s (PBMAs) with various molar masses (33 000–270 000 g mol^?1), which were densely grafted on fumed silica nanoparticles (PBMA–SiO₂), were synthesized by surface‐initiated atom transfer radical polymerization. The dynamic viscoelastic behavior of PBMA–SiO₂ was systematically investigated in the solid and molten states with oscillatory strains, and compared to that of a conventional nanocomposite (PBMA/SiO₂). The storage moduli of PBMA–SiO₂ and PBMA/SiO₂ are equivalent in the solid state, whereas the storage modulus of PBMA–SiO₂ is lower than that of PBMA/SiO₂ in the molten state, especially at high silica loading. This is because the formation of a network structure composed of the silica nanoparticles in PBMA–SiO₂ is strongly suppressed by the polymer brushes on the particles. In contrast, even at low silica loading, the PBMA–SiO₂ system exhibits a gel‐like behavior resulting from a steric repulsion between the composite particles, because all of the tethered polymers behave as bound polymers. Copyright © 2011 Society of Chemical Industry     

Viscoelastic properties of branched polyacrylate melts

The viscoelastic properties of poly(n‐butyl acrylate), poly(ethyl acrylate) and poly(methyl acrylate) melts have been studied using samples that varied in both molar mass and the mol% branched repeat units, these properties having been previously determined by gel permeation chromatography and ¹³C NMR spectroscopy, respectively. Poly(n‐butyl acrylate) was studied most extensively using seven samples; one sample of poly(n‐butyl acrylate), two samples of poly(ethyl acrylate) and one sample of poly(methyl acrylate) were used to study the effect of side‐group size. Storage and loss moduli were measured over a range of frequency (1 × 10^?3 to 1 × 10² rad s^?1) at temperatures from T_g + 20 °C to T_g + 155 °C and then shifted to form master curves at T_g + 74 °C through use of standard superposition procedures. The plateau regions were not distinct due to the broad molar mass distributions of the polyacrylates. Hence, the upper and lower limits of shear storage modulus from the nominal ‘plateau’ region of the curves for the seven poly(n‐butyl acrylate) samples were used to calculate the chain molar mass between entanglements, M_e, which gave the range 13.0 kg mol^?1 < M_e < 65.0 kg mol^?1. The Graessley–Edwards dimensionless interaction density and dimensionless contour length concentration were calculated for poly(n‐butyl acrylate) using the mean value of plateau modulus (1.2 × 10⁵ Pa) and three different methods for estimation of the Kuhn length; the data fitted closely to the Graessley–Edwards universal plot. The Williams–Landel–Ferry C₁ and C₂ parameters were determined for each of the polyacrylates; the data for the poly(n‐butyl acrylate) samples indicate an overall reduction in C₁ and C₂ as the degree of branching increases. Although the values of C₁ and C₂ were different for poly(n‐butyl acrylate), poly(ethyl acrylate) and poly(methyl acrylate), there is no trend for variation with structure. Thus the viscoelastic properties of the polyacrylate melts are similar to those for other polymer melts and, for the samples investigated, the effect of molar mass appears to dominate the effect of branching. © 2001 Society of Chemical Industry     

装有圆盘桨的表面更新釜中Boger流体的功率特性

本文测定了Boger流体在装有圆盘桨的双表面更新中的功耗,调查了操作参数:装桨个数,装料量等对功耗的影响,考察了弹性对搅拌功耗的影响,得到了广泛条件下的功率消耗关联式。     

层状土中考虑剪切变形的单桩水平振动解析解

针对桩基水平振动分析问题，建立了能够同时考虑桩体弯曲和剪切变形的桩土计算模型.采用与频率相关的刚度系数和阻尼系数来模拟土对桩的动反力，简化桩体为Timoshenko梁，得到了层状黏弹性地基中能同时考虑桩体弯曲和剪切变形的单桩的水平振动解析解.研究了桩土模量比、桩体长径比、地基成层性以及激振频率对桩基动力响应的影响.并且在给定桩土参数的情况下，把同时考虑桩体弯曲和剪切变形的解析解与只考虑弯曲变形的解进行了比较.结果表明，忽略桩体水平振动时的剪切变形可能会带来较大的误差.     

VED支承转子的模态频率及稳定性研究

为了研究两端黏弹性橡胶阻尼器（VED）支承单盘转子系统的动力学特性，建立了轮盘位于1/3轴跨处的转子系统有限单元模型。通过求解转子系统的复特征根问题，获得转子系统的模态振型。分析模态频率和阻尼比随转速的变化规律，讨论阻尼器支承刚度、损耗因子和质量参数对模态频率和阻尼比的影响。结果表明，转子系统的阻尼器支承刚度和损耗因子分别存在一个最优值，使得工作转速远离模态频率，并提高了转子系统的稳定性；质量参数对一阶模态阻尼比的影响较小；当质量参数超出某有效区间时，系统将失去对高阶模态响应的衰减作用。     

非线性粘弹性桩耦合运动中的混沌分析

研究轴向周期载荷作用下非线性粘弹性桩纵横向耦合运动中的混沌运动。桩体材料满足Leaderman非线性粘弹性本构关系和近似的非线性几何关系，考虑桩体发生纵横向运动的耦合，得到的方程为耦合的非线性偏微分一积分方程；利用Galerkin方法将方程简化并进行数值计算，揭示非线性粘弹性桩的混沌运动和分岔等动力学行为。     

高速光驱粘弹性阻尼减振框架结构的动力学方程及有限元数值解

对安装有粘弹性阻尼器的高速光驱框架结构进行了理论建模，粘弹性阻尼器采用分数Kelvin固体模型，建立了高速光驱粘弹性阻尼减振框架结构的分数阶动力学有限元方程，并利用Newmark数值积分法得到了数值解     

Relationship between rheological manufacturing process and optical performance of optical fiber coupler

Through theoretical analysis and experiments, the viscoelastic mechanical model of optical fiber coupler in the process of fused biconical taper was established, and the numerical analysis in non-uniform temperature field was made. The results show that the rheological parameters, such as drawing speed and fused temperature, have a tremendous influence on stress distribution and performance of optical fiber coupler, especially the influence of fused temperature. The change of fused temperature by 5 ℃ can lead to the change of the maximum stress by 30% and stress difference by 20% in the same cross section. The change of temperature gradient by 3% can result in the change of stress difference by 90%. In the present condition of rheological technology, rheological defects such as crystallizations and microcracks are easy to generate in the optical fiber coupler.     

设置F-Ved建筑结构空间协同工作控制研究

根据粘弹性阻尼器和摩擦阻尼器各自的特点，提出一种新型粘弹性－摩擦阻尼器（F－Ved）耗能装置，推导了粘弹性－摩擦阻尼器和人字型支撑的阻合层间单元刚度矩阵和控制力向量；并基于框架结构的空间特性，建立了设置（F－Ved）框架结构在考虑空间协同分析的基础上地震反应时程分析的控制方法，应用此方法，对设置F－Ved的钢筋混凝土框架结构进行了在罕遇地震和多遇地震作用下的时程分析，并根据计算结果与其减震效果进行了分析讨论。