Optical and surface properties of whey protein isolate coatings on plastic films as influenced by substrate,protein concentration,and plasticizer type

Composite film structures of common plastic polymers including polypropylene (PP) or poly(vinyl chloride) (PVC) with whey protein isolate (WPI) coatings may be obtained by a casting method. Optical and surface properties of the resulting WPI‐coated plastic films, as affected by protein concentration and plasticizer type, were investigated to examine the biopolymer coating effects on surface modification with polymeric substrates of opposite polarity. The measured properties involved specular gloss, color, contact angle, and critical surface energy. Regardless of the substrates, WPI‐coated films possessed excellent gloss and no color, as well as good adhesion between the coating and the substrate when an appropriate plasticizer was added to the coating formulations. The protein concentration did not significantly affect gloss of WPI‐coated plastic films. Among five plasticizers applied, sucrose conferred the most highly reflective and homogeneous surfaces to the coated films. The WPI coatings were very transparent and the coated films with various protein concentrations and plasticizers showed no noticeable changes in color. Experimental results suggest that WPI coatings formulated with a proper plasticizer can improve the visual characteristics of the polymeric substrate and enhance water wettability of the coated plastic films. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 335–343, 2004     

C_9 FK的表面活性测定

用吊片法和自制改进的最大泡压法分别测定了全氟庚氧基全氟亚乙基磺酸钾(C9FK)溶液的平衡和动态表面张力,计算得出该种表面活性剂形成胶束的标准热力学函数△Hmθ、△Smθ、△Gmθ分别为16．98 kJ／mol、218．29 J／mol·K、-48．22 kJ／mol。结合Word-Tordai方程,计算得到在不同条件下的表观扩散系数Da和吸附势垒Ea。实验证明,增大表面活性剂的浓度、降低温度、以及无机盐(NaCl)的加入都会使扩散系数减小,吸附势垒增大,从而不利于吸附的进行。当表面活性剂的浓度小于等于1×10-6 mol/L时,该体系属于扩散控制模型,而浓度大于 1×10-6 mol/L时,在吸附初期(t→O)属于扩散控制,后期均属于混合控制模型。     

跳-扩散环境下障碍期权及重置期权定价

在股票价格服从带跳几何布朗运动模型假设下,利用跳．扩散环境下欧式未定权益的一般Black—Scholes偏微分方程,讨论了下降敲出障碍期权和下降敲入障碍期权定价问题,获得了相应的定价公式．最后,运用障碍期权和重置期权的关系,给出了重置看涨期权定价公式．     

狭缝光栅自由立体显示器的立体图像串扰度

为了表征狭缝光栅自由立体显示器存在的左右眼视差图像的混叠程度,提出了立体图像串扰度C的概念。根据狭缝光栅自由立体显示器的结构和工作原理,应用几何光学知识,分析得出了立体图像串扰度C的计算公式,并给出了一个具体的狭缝光栅自由立体显示器的计算结果。通过观看实验,证明了所定义的立体图像串扰度C可以定量描述观看者在立体可视区域看到的立体图像的串扰程度。     

线性红利下带干扰的复合Poisson风险模型

在线性红利下将保单到达过程推广为Poisson过程,并通过添加Brownian运动来刻画保险公司不确定的收益和付款,建立线性红利下带干扰的复合Poisson风险模型.运用鞅方法得出了破产概率满足的Lundberg不等式和一般公式,并给出了生存概率满足的积分—微分方程。     

保健酒除浊工艺研究

文章比较了微孔膜过滤法和活性炭吸附法在保健酒除浊中的应用,结果表明：活性炭吸附法不适合保健酒的除浊,而且可能影响保健酒中的有效成分;微孔膜过滤法能有效除浊,且对有效成分、风味和色泽的影响较小,保健酒的静置时间也会影响除浊效果。保健酒粗滤后静置4周,然后用孔径为0．45μm醋酸纤维素膜过滤,除浊效果最佳。     

双排刚性桩屏障对平面SH波的隔离性状研究

基于Twersky的理论,引入圆柱体对声波和电磁波的多重散射解析解,对用排桩隔离环境振动的问题,提出了一种新的求解任意排列、任意直径刚性桩对平面SH波多重散射的理论方法,解决了传统的假设单重散射的计算方法中不考虑桩列作为整体屏障从而忽略桩间相互干涉关系的不足。随后,在数值计算分析中讨论了散射重数,排间距,桩间距等因素对双排刚性桩隔振效果的影响,对实际工程中利用排桩进行振动污染治理和屏障隔振的设计提出了有意义的结论。     

拉法基屋面施工技术

为解决传统坡屋面易渗漏、不耐久、易污染、保温性能差等问题,提出拉法基坡屋面系统所采用的防水、保温、隔辐射热、通风等较先进的施工工艺,使坡屋面工程在外观、使用年限以及节能减排等各方面效果均有显著提升.     

DBD等离子体反应器高频电源下的放热研究

通过实验监测DBD(dielectric barrier discharge)温度变化情况,探讨了温升所引起的热转移机理,得出DBD热变化表达式,并推导出相应的能量分配式及ΔTave计算式.实验结果表明:高频放电过程中,DBD反应器温度随电压升高和时间延长而上升,它们之间呈非线性关系;DBD反应器温度随频率提高和时间延长而升高,随气体速度的提高而降低,温度变化与时间、频率及气体速度均呈现出线性关系.     

Study on hydrogen atom adsorption and diffusion properties on Mg (0001) surface

Hydrogen atom adsorption and diffusion properties on clean and vacancy defective Mg (0001) surface have been investigated systematically by using a first-principles calculations method based on the density functional theory. The calculation results of adsorption energy and diffusion energy barrier show that hydrogen atom is apt to be adsorbed at fcc and hcp sites on clean Mg (0001) surface, and fcc adsorption site is found to be more preferred. The highest diffusion energy barrier is estimated as 0.6784 eV for the diffusion of hydrogen from clean Mg (0001) surface into its bulk. Surface effects, which affect hydrogen diffusion obviously, results in a slow diffusion velocity of hydrogen from surface to subsurface, while a fast one from subsurface to bulk, indicating the range of surface effects is only restricted within two topmost layers of Mg (0001) surface. Comparatively, Mg atom vacancy on Mg (0001) surface not only enhances the chemisorption interaction between H and Mg surface, but also benefits H atom diffusion in Mg bulk with relatively more diffusion paths compared with that of clean surface. Besides, hydrogen atom is found to occupy mostly the tetrahedral interstice when it diffuses into the Mg bulk. Further analysis of the density of states (DOS) shows that the system for hydrogen atom to be adsorbed at fcc site has a lower DOS value (N (E _F)) at Fermi level and more bonding electrons at the energy range blow the Fermi level of H/Mg (0001) system as compared with that at hcp site. On the other hand, the enhanced chemisorption interaction between hydrogen and defective surface should be attributed to the fact that the electronic structures of Mg (0001) surface are modified by an Mg vacancy, and the bonding electrons of the topmost layer Mg atoms are transferred from low energy range to Fermi level, which is in favor of improving the surface activity of Mg (0001) surface. Supported by the PhD Programs Foundation of Ministry of Education of China (Grant No. 200805321032), the Science and Technology Program Project of Hunan Province (Grant No. 2008GK3083) and the Program for Changjiang Scholars and the Innovative Research Team in university (Grant No. 531105050037)