Immobilization of a cyclodextrin glucanotransferase (CGTase) onto polyethylene film with a carboxylic acid group and production of cyclodextrins from corn starch using CGTase‐immobilized PE film

Carboxylic acid groups were introduced onto polyethylene (PE) film by radiation‐induced graft copolymerization. Subsequently, the clodextrin glucanotransferase (CGTase) was immobilized on the PE film with a carboxylic acid group. The activity of the immobilized CGTase on PE film was in the range of 0.40–1.04 U/cm² per min. The production of cyclodextrins (CDs) from corn starch was examined using the CGTase‐immobilized PE film. The production ratios of CDs using CGTase‐immobilized PE film was in the following order: α–CD > β–CD > γ–CD. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2451–2457, 2002     

Specially elaborated thermally induced phase separation to fabricate poly(L‐lactic acid) scaffolds with ultra large pores and good interconnectivity

Poly(L ‐lactic acid) (PLLA) scaffolds with pore diameters from several micrometers to ～300 μm were fabricated by a specially elaborated thermally induced phase separation technique. Two different coarsening protocols, i.e., normal coarsening and multi‐step coarsening were compared in consideration of phase separation and domain growth. A normal coarsening route produced scaffolds with pore size from several micrometers to 150 μm depending on the coarsening time after phase separation, accompanying with the emergence of isolated pores at long time coarsening. Scaffolds with large pores with size up to ～300 μm were fabricated by the two‐step coarsening technique, e.g., the PLLA‐solvent (dioxane/water) system was coarsened at a temperature after phase separation for a period, followed by coarsening at a lower temperature for another period. In parallel with formation of the large pores, the interconnectivity between pores was also improved, which was evidenced by scanning electron microscopy, gelatin solution pervasion, and collagen entrapment. The present technique provides the ability to produce scaffolds with high purity, controllable microstructures, and ease of modification, and hence can be widely used in tissue engineering field. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3336–3342, 2006     

Effect of polymer density on polyethylene hollow fiber membrane formation via thermally induced phase separation

Microporous high‐density polyethylene (HDPE) and low‐density polyethylene (LDPE) hollow fiber membranes were prepared from polyethylene–diisodecyl phthalate solution via thermally induced phase separation. Effect of the polyethylene density on the membrane structure and performance was investigated. The HDPE membrane showed about five times higher water permeability than the LDPE membrane because it had the larger pore and the higher porosity at the outer membrane surface. The formation of the larger pore was owing to both the initial larger structure formed by spinodal decomposition and the suppression of the diluent evaporation from the outer membrane surface due to the higher solution viscosity. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 471–474, 2004     

超支化树脂的合成及在聚氨酯涂料中的应用

以超支化聚合物作为基料与脂肪酸等单体合成了超支化树脂,并利用红外光谱,GPC等仪器对超支化树脂进行表征;同时研究了超支化树脂在聚氨酯哑光面漆中的应用,研究表明:实验所制备的超支化树脂虽然消光效果较差,但是采用超支化树脂部分代替商业哑光树脂,可以改善漆膜的透明性及耐冲击性。     

不同缝面形态下诱导缝开裂效果对比研究

一些采用径向扭缝的碾压混凝土拱坝工程中,出现了诱导缝周边坝体混凝土开裂而诱导缝本身未张开的现象,因此需定量分析不同空间形态缝面对诱导缝开裂的影响效果。根据碾压混凝土拱坝应力变化特点以及诱导缝开裂变化规律,本文拟定含不同缝面空间形态的有限大平板和圆筒拱坝算例,利用虚拟裂纹闭合法和Richard脆性断裂准则获取空间缝面等效应力强度因子,研究缝面应力强度因子随缝面夹角的变化规律;通过对归一化后的应力强度因子求倒数,获取不同缝面夹角条件下诱导缝等效强度的修正系数即缝面空间形态影响因子,以反映不同缝面空间形态下诱导缝开裂效果。研究表明,随着缝面夹角的不断增大,缝面越不容易张开,这就意味着缝面的等效强度在逐渐增大。因此,在实际碾压混凝土拱坝设计中,诱导缝应尽量采用竖向垂直缝布置;若要布置成径向扭缝,则缝面夹角最大不宜超过10°。     

Preparation of microporous chlorinated poly(vinyl chloride) membrane in fabric and the characterization of their pore sizes and pore‐size distributions

Chlorinated poly(vinyl chloride) (CPVC)/poly(vinyl pyrrolidone) (PVP) membranes were prepared by using the solvent system tetrahydrofuran (THF)/n‐butyl alcohol (n‐BA) to investigate the possibility of pore size and pore‐size distribution control. The coagulation of CPVC/PVP solution was induced by the exposure to water vapor at 25 (±0.5)°C. The average pore diameter, d_p, and the size distribution of pores on the surface of the membrane were quantified through the image analyzer from the images visualized by field emission scanning electron microscope (FE‐SEM). Surface pore size and distribution of the prepared CPVC/PVP membrane were strongly affected by the relative humidity (RH) in the environment and the content of PVP used as an additive. Particularly, in the case of CPVC membrane without PVP, the mean pore size was 0.15–0.2 μm, depending on the RH. The pore distribution became broad with the increase of the RH. The membranes had open pores as confirmed by the hydraulic permeation experiment. In addition, the water flux and membrane resistance (R_m) were greatly affected by the composition of polymer solution and the RH. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1195–1202, 2002     

聚丙烯微孔膜研究进展

聚丙烯（PP）是一种价格低廉的塑料，是目前最主要的制备高分子微孔膜的材料之一。笔者综述了近年来PP微孔膜制备方法的研究进展，重点介绍了熔纺拉伸法（MSCS）、热致相分离法（TIPS）、共混拉伸法、熔融烧结法等PP微孔膜的常用制备方法，并对相关的影响因素进行了讨论。     

异构流媒体平台间服务透明化设计与应用

论文主要介绍异构平台服务透明化实现模型.针对两种具体异构流媒体平台进行分析,结合行业服务要求,提出同级异构交互模型与异级同构交互模型,给出一种分层融合设计,以XML[1]作为基础语言进行业务数据交流,通过私有协议识别与转换及ocx内嵌,在保证平台独立性上实现与业务强关联的流媒体数据互用.通过实践表明,采用这种设计完全可以打通异构平台间的数据壁垒,达到服务透明化的目的.     

变速直驱开关磁阻风力发电系统雷电防护技术研究

根据风力发电机组防雷保护的研究成果和相关行业防雷标准,分析雷电的形成、破坏机理及其破坏形式。结合开关磁阻风力发电系统特征,划分雷电防护区域;按照风力发电机组防雷设计应该遵循的原则,通过外部防护和内部防护相结合,提出开关磁阻风力发电系统各部件防雷保护措施。为工程实践中开关磁阻风力发电系统的雷电防护提供一定的参考。     

呼吸感应体积描记系统中弱信号锁相放大模块的设计

在呼吸感应体积描记呼吸测量系统中,需要测量nV~μV级的微弱感生电压信号,而且在测量过程中,做为传感器的电感线圈容易受到测量环境,呼吸运动以外的其他运动和电子噪声等影响。为适应系统测量范围并降低噪声的影响,设计了一种基于AD630锁相放大电路微弱生理信号检测模块。该模块的锁相放大器具有大于0.96的良好线性度,能检测出传感器的感生电压信号,并分离出直流分量,有效地降低噪声对系统的影响,提高了系统测量的精度,并有望应用于其他微弱生理信号检测。