One-step synthesis of high purity ZnO micro/nanostructures from pure Zn and pre-alloyed brass powders by vapor phase transport

In this research, vapor phase transport (VPT) was introduced as a facile, inexpensive method to produce ZnO micro/nanostructures from various Zn sources such as pure Zn and alpha brass pre-alloyed powders (Cu–20Zn and Cu–28Zn) at different processing temperatures of 930 °C–1050 °C. Simultaneous thermal analysis (STA) was carried out to investigate Zn evaporation and ZnO micro/nanostructure formation. STA results showed an exothermic peck at 711 °C and 728 °C for Cu–20Zn and Cu–28Zn, respectively, due to oxidation of the evaporated Zn element and formation of ZnO micro/nanostructures. X-ray diffraction results showed that high purity ZnO micro/nanostructures were successfully synthesized via VPT process and the crystallite size was increased from ~60 nm to ~100 nm with increasing processing temperature. Field emission scanning electron microscopy observations showed morphology (e.g. rods, column, tetrapods, and combs) and size of the synthesized micro/nanostructures were dependent on the Zn sources and processing temperature, in which average diameter of the synthesized ZnO structures was increased with increasing the processing temperature. The smallest (98 nm) and largest (603 nm) average diameters of synthesized ZnO micro/nanostructures were attained from the pure Zn and Cu–28Zn brass powders at 930 °C and 1050 °C, respectively.     

A first-principles investigation on mechanical and metallic properties of titanium carbides under pressure

The titanium carbides are potential candidates to achieve both high hardness and refractory property. We carried out a structural search for titanium carbides at three pressures of 0 GPa, 30 GPa and 50 GPa. A phase diagram of the Ti-C system at 0 K was obtained by elucidating formation enthalpies as a function of compositions, and their mechanical and metallic properties of titanium carbides were investigated systematically. We also discussed the relation of titanium concentration to the both mechanical and metallic properties of titanium carbides. It has been found that the average valence electron density and tractility improved at higher concentrations of titanium, while the degree of covalent bonding directionality decreased. To this effect, the hardness of titanium carbide decreases as the content of titanium increases. Our results indicated that the titanium content significantly affected the metallic properties of the Ti-C system.     

数字储频及其性能分析

文章介绍了3种宽带数字储频的基本结构，分析了宽带数字储频的一个重要指标——量化噪声，根据输出信号频谱的杂散电平比较了三种结构的优劣。     

小断块单元油藏单井多周期CO2吞吐强化采油研究

低渗小断块油藏控制单元井间连通性差、边界封闭、地层能量有限、开采中地层能量下降很快，难以采用早期注水等方式大规模开采。用CO2吞吐强化采油对此类油藏可能是一种有效的方法，为此进行了相关研究：首先对油井目前流体进行相态研究，然后对油藏流体进行CO2膨胀实验，再将注气前、后的地层流体的物性进行对比，确定CO2增产机理；在此基础上建立单井CO2吞吐的数值模拟模型并对注气前生产历史进行拟合，用拟合好的模型对CO2吞吐强化采油过程中周期注入量、注气速度、焖井时间和生产速度等因素进行敏感性分析，从而得出适合于小断块单元油藏单井CO2吞吐强化采油的优选方案，并对第一周期生产指标进行了预测，在此基础上，对第二周期的周期注入量进行了分析，得出相关油井已不适合进行第二周期吞吐的结论，为油井CO2吞吐强化采油可行性的工艺方案设计提供了技术依据。     

Microstructures and Phase Transition Points of As-Cast Mg-Zn-Y System Alloys

As-east mierostruetures and their distribution of Mg-Zn-Y ternary alloy with high magnesium, low zinc and yttrium were examined using Nikon Epiphot optical microscopy （OM）, RigakuD/max-3C X- ray diffraetion （XRD）, and JEOL JSM-6700F scanning electron microscopy （SEM） equipped with an energydispersive X-ray spectroscopy （EDS）. In the as-east mierostructures, Yttrium and zinc tend to segregate at grain boundaries,     

人工颅骨用复合材料中微量甲基丙烯酸甲酯的气相色谱法测定

采用氢气焰离子化检测器(FID),以正丁醇为外标物,PEG-20M为固定相,甲醇作为溶剂,气相色谱法测定复合材料人工颅骨中微量MMA的含量。其相对标准偏差<0.022,平均回收率(n=4)为98.0％～99.1％。此方法操作简便,用于实际样品分析可得到满意的结果。     

Lake Chivero: A management case study

Lake Chivero in Zimbabwe was shown to be hypereutrophic. Historical data showed that the eutrophication process had been arrested in the late 1970s. However, a combination of poor planning, multiplicity of jurisdiction, mismatch between rate of urbanization and waste management investment, recent changes in the local climate and a permissive, immature political system that called for no public accountability resulted in environmental management breakdown leading to hypereutrophication of the lake. The case of Lake Chivero is presented as an example of a wider global issue regarding the status of environmental management in competition with other priorities in emerging democracies.     

综合高速效应的凝析气藏流入动态

当井底压力低于露点压力时,凝析液在近井地带开始析出并不断聚集产生凝析油堵塞现象。因此,在制定凝析气井工作制度时,通常以控制生产压差为指导思想,往往忽略高速流动下凝析气液相变的非平衡特征。对于凝析气体系,当外界温压变化速度超过凝析气液的相平衡速度时,凝析气体系相变滞后,开始呈现非平衡特征,即凝析液的析出量随着压降速度的增加而减小。凝析气在向井筒流动的过程中,近井区高速流动使凝析气产生非平衡相变,凝析气在比较高的压降速度下流入井筒,使得凝析液来不及析出。在分析非平衡相变规律与近井地带凝析气渗流参数分布的基础上,评价凝析气液流动过程中的非平衡特征,给出了考虑非平衡相变的凝析液饱和度分布计算公式,并进行了产能预测结果对比。实例分析表明,可以通过适当放大生产压差,增加凝析气液相变非平衡特征,减小井筒附近的凝析液饱和度,提高气井产能与气藏开发效果。     

王庄油田粘土矿物转化对储层的影响

王庄油田是水敏性稠油油藏的典型代表，其水敏性在热采过程中的变化直接关系到油田开发方式的选择。针对这一问题，从直接影响水敏性变化的储层粘土矿物入手，在模拟地层环境的基础上通过室内高温高压静态和动态物模实验，并结合X衍射、扫描电镜、元素分析、粒度检测等多种分析测试手段，研究了粘土矿物在100-300℃之间的变化过程，从而找到水敏性的变化规律，进而从机理上解释了渗透率的变化原因，为数值模拟和开发方案制定提供室内研究依据。     

SO4^2-／ZrO2固体超强酸的制备及其催化合成ETBE的研究

采用沉淀一浸渍法制备了负载型SO4^2-／ZrO2固体超强酸催化剂，运用IR、XRD等方法表征所制备催化剂的物化性质。结果表明，所制备的催化剂具有固体超强酸催化剂的特征，酸性与焙烧温度有关，适当提高焙烧温度有利于样品酸强度的提高，但焙烧温度过高会导致脱硫；浸渍液H2SO4浓度高有利于提高催化剂的硫含量，但是浓度过高，会在催化剂上形成硫酸盐，从而降低催化剂的比表面积和酸性。采用制备的催化剂气相催化乙醇与叔丁醇合成乙基叔丁基醚反应，乙基叔丁基醚的选择性为54．71％。