荷能束辐照致使Cu/Ag表面偏析的研究

本文研究了金属(Cu)/金属(Ag衬底)系统的荷能束辐照引起的表面偏析现象。观察到Cu在多晶Ag衬底上溅射淀积过程中,Ag原子在Cu膜表面的偏析,且淀积Cu原子能量越大,Ag原子偏析程度越大,即观察到了淀积Cu原子10~(-1)～1eV量级的平均能量差异对膜层表面偏析行为的影响。对溅射淀积所得膜层进行keV量级的离子束辐照,Ag原子的表面偏析程度更甚。     

既有钢筋混凝土框架结构抗震加固若干问题探讨

针对钢筋混凝土框架结构抗震加固问题的复杂性 ,本文深入分析了抗震加固结构的受力特征 ,探讨了卸荷对加固构件承载力的影响 ,并针对抗震加固后的“隐含危险转移”问题提出了相应的对策。最后 ,提出了抗震加固的基本原则 ,可供结构抗震加固时参考     

TiCl4-Mg(OC2H5)2催化乙烯聚合和形态学研究Ⅱ.预聚合对聚合物颗粒形态的修正

在较低的温度和乙烯分压下进行预聚合,然后提高温度和压力进行后续的聚合实验,考察了预聚合条件对催化剂聚合动力学和聚合物颗粒形态的影响.发现预聚合可以提高催化剂的活性,预聚合时间越长,催化剂活性提高越多.通过SEM分析发现,预聚合显著改善了聚合物的颗粒形态.由于聚合物颗粒中的线团状形态结构消失,聚合物粉体的堆密度显著上升.证明预聚合可以成功解决聚合速率提高与聚合物堆密度下降的矛盾.     

Skeletal Isomerization and Inter—molecular Hydrogen Transfer Reactions in Catalytic Cracking

Bimolecular hydrogen transfer and skeletal isomerization the important secondary reac-tions among catalytic cracking reactions,which affect product yield distribution and product quality,Catalyst properties and operating parameters have great impact on bimolecular hydrogen transfer and skeletal isomerization reactions .Bimolecular hydrogen transfer activity and skeletal isomrization activity of USY-containing catalysts are higher thn that of ZSM-5-containing catalyst.Coke deposition on the active sites of catalyst may suppress bimolecular hydrogen transfer activity and skeletal isomer-ization activity of catlys in different degrees.Short raction time causes a decrease of hydrogen trans-fer reaction,but and increase of skeletal isomerization reaction compared to cracking reaction in catalytic cracking process.     

NaBH4溶液的配制方法和保存时间对HVG—AAS测砷的影响

考察了在氢化物发生与原子吸收联用测量砷的过程中，NaBH4溶液的配制方法与保存时间对测量的影响。运用统计检验方法比较了各种不同的结果，对硼氢化钠的最佳配制方法与放置时间进行了探讨。     

原位插层聚合制备PVC/蒙脱土纳米复合材料

采用氯乙烯单体直接插层到蒙脱土中进行原位插层聚合，制备纳米复合材料，并用小角X射线衍射（XRD）、扫描电子显微镜（SEM）和电子探针技术对复合材料进行了结构表征。实验结果表明：采用原位插层聚合法制得的PVC／蒙脱土（MMT）复合材料为剥离型纳米复合材料。     

聚苯乙烯生产工艺及其产品性能的改善

介绍了苯乙烯单体热引发本体聚合的特点及美国FINA石油化学公司聚苯乙烯生产工艺的特点，探讨了影响HIPS产品质量的多种因素，并对HIPS产品质量的改善提供提出建议和看法。     

Ground-based investigation of atomic oxygen effects on naked Ag and Ag with protective organic coating

Protective behavior of organic coatinge of alkyd,epoxy,urethane and siloxance applied to silver solar cell interconnects and erosion of Ag were investigated by exposure experiments to ground simulation atomic oxygen(AO).Evaluations of their protective properties were made through assessing their mass cfhange characteristics,chemical and physical changes to Ao attack.The specimens,after exposure were analyzed with SEM/EDAX and XPS.The results indicated that the silver is heavily etched.some coatings such as epoxy,alkd,urethane are seriously degraded or removed as volatile oxides and morphology of coatings changes.It is evident that siloxane coatings have excellent properties for anti-AO attack.The erosion product consists of silicon dioxide layer of compact texture and is left on the surface to provide adequate protection fro further attack by the energetic AO.     

前向反冲分析和非卢瑟福背散射

介绍了弹性散射分析中的另外两种分析方法——前向反冲分析和非卢瑟福背散射分析。前向反冲分析适用于材料中H和He同位素分析。高能质子和He离子背散射分析可提高对重基体中C,N和O等轻元素分析的灵敏度。给出了这两种分析方法的应用实例。