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581.
Ze-Da Meng Lei Zhu Shu Ye Shou Qing Liu 《Fullerenes, Nanotubes and Carbon Nanostructures》2016,24(7):415-422
Reactive oxygen species (ROS) can be produced by interactions between sunlight and light-absorbing substance in natural water environment and can completely destroy various organic pollutants in wastewaters. In this study, a novel Ag2Se-C70 heterojunction photocatalysts were successfully prepared. Surface area and pore volumes of the Ag2Se-C70 samples showed decrease due to deposition of Ag2Se. The generations of ROS were detected through the oxidation reaction from DPCI to DPCO. The photocurrent density and the PGO effect increase in the case with the modified C70. The PGO effect of the C70 modified with Ag2Se composites is increased significantly due to the synergetic effect between the C70 and the Ag2Se nanoparticles. 相似文献
582.
红外光谱法(FT IR)测定了(C60X)载体钕系催化剂引发不同丁二烯 异戊二烯摩尔比所得共聚物的组成变化规律,提出了球碳973cm-1吸收带可能与共聚物主链上双键与C60分子骨架间存在π π相互作用有关的解释。 相似文献
583.
A. Zettl Li Lu X. -D. Xiang J. G. Hou W. A. Vareka M. S. Fuhrer 《Journal of Superconductivity》1994,7(3):639-642
The normal-state transport properties of alkali-metal-doped fullerene crystals are explored. The Hall effect has been measured in KxC60 from room temperature toT
c
. The electrical resistivity for K3C60 and Rb3C60 has been measured over a wide temperature range (20–650 K), and notable differences are observed for the materials at both low and high temperatures. The electrical resistivity of Rb3C60 has been measured in hydrostatic pressures up to 9 kbar. The resistivity is highly pressure sensitive. The transport results give an insight into the normal-state conduction mechanism and thus have consequences for the superconductivity mechanism. 相似文献
584.
W?odzimierz Kutner Krzysztof NoworytaRenata Marczak Francis D'Souza 《Electrochimica acta》2002,47(15):2371-2380
Thin-solid films of higher fullerenes, viz. C76, C78 and C84, were prepared by the drop coating technique and characterized by simultaneous cyclic voltammetry and piezoelectric microgravimetry with the use of an electrochemical quartz crystal microbalance. Properties of the films were compared with those reported earlier for the C60 and C70 thin-solid films. The effect of nature of the counter cation on electrochemical properties of the films has been probed by employing acetonitrile solutions of two different 0.1 M supporting electrolytes, namely tetra(n-butyl)ammonium (TBA+) hexafluorophosphate and potassium hexafluorophosphate. Stability of the films with respect to dissolution depends on the fullerene oxidation state as well as on the nature of both the fullerene in the film and the counter cation in the supporting electrolyte. The TBA+ counter cation ingress to the film for compensation of the negative charge of the reduced fullerene is accompanied by the acetonitrile solvent intake. The number of acetonitrile molecules per TBA+ counter cation entering the film is higher the higher the fullerene. Also, the Langmuir films of higher fullerenes were prepared at the air-water interface and the film morphology was characterized by the Brewster angle microscopy. 相似文献
585.
C60‐bonded polystyrene was produced with a novel initiator system, C60Cln/CuCl/2,2′‐bipyridine (where the average value of n is 20). The molar ratio of styrene/C60Cln/CuCl/bpy was 100:1/20:1:2, and the polymerization temperature was 130°C. Gel permeation chromatography detected with an ultraviolet detector demonstrated that C60 was chemically bonded to polystyrene. The linear increase in the number‐average molecular weight (by gel permeation chromatography) with the conversion indicated that this novel initiator system had some characteristics of living polymerization. A possible polymerization mechanism was examined. The photoconducting properties of C60‐bonded polystyrene were better than those of polystyrene initiated with CCl4. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3001–3004, 2002 相似文献
586.
《Fullerenes, Nanotubes and Carbon Nanostructures》2007,15(3):195-205
Relative stabilities of six C74 fullerene cages are evaluated: one species obeying the isolated pentagon rule (IPR), three isomers with a pentagon-pentagon junction, two structures with one pentagon-pentagon pair and one heptagon. The computations are carried out using the Gibbs energy in a broad temperature interval. It is shown that the IPR cage (D3h symmetry) prevails throughout. As low-lying electronic excited states are possible for the cages, their electronic partition functions are included into consideration. It is argued that for the special conditions of the fullerene synthesis/isolation, the electronic partition function based on the singlet excited states only should better reproduce the experimental population findings. The computations indicate that isolation of other C74 cage, in addition to the IPR isomer, is less likely though not impossible. 相似文献
587.
588.
Antonio Cravino 《Polymer International》2007,56(8):943-956
Conjugated polymers are of increasing interest as semiconductors for soft (opto)electronic devices, including photovoltaic elements. A promising conversion of solar energy into electrical energy is possible with blends of soluble electron donor‐type conjugated polymers and fullerenes as electron‐acceptor, transporting component. This approach, called bulk‐heterojunction, suggested the preparation of intrinsic ambipolar materials to control simultaneously the electronic and morphological properties. On these bases, the covalent grafting of acceptor moieties onto conjugated backbones seemed attractive for the preparation of intrinsically ambipolar polymeric materials (‘double‐cable’ polymers) as an alternative to donor–acceptor composites. The design, characterisation and application of this novel class of polymers are reviewed taking into account the current understanding of organic photovoltaics. Copyright © 2007 Society of Chemical Industry 相似文献
589.
以 3种高变质程度的中国煤为原料 ,用电弧等离子体蒸发法制备富勒烯 .富勒烯产品的表征采用质谱、紫外光谱和红外光谱等技术 .采用碱法脱灰技术对 3种煤进行脱灰处理 ,考察了脱灰前后煤样的灰分和相应炭棒中碳含量对富勒烯产率的影响 .结果表明 ,由实验所用煤种均可制得富勒烯 .原料煤本身的化学结构和组成对富勒烯的产率有明显影响 ,表现为富勒烯的产率随炭棒中碳含量的增加而增大 .煤中的矿物质对富勒烯的形成有很强的抑制作用 ,表现为富勒烯的产率随原料煤中灰分的增加而降低 ,这一变化趋势通过对介休焦煤进行不同程度的脱灰处理而得到进一步证实. 相似文献
590.