ZK60镁合金表面滚压强化试验研究

试验研究了ZK60镁合金表面滚压加工中工艺参数对试件表面粗糙度、表面形貌、表面残余应力和表层显微硬度的影响,结果表明滚压力和重复滚压次数对试件的表面粗糙度、表面形貌以及表面残余应力和表层硬度影响程度较大,滚压速度影响较小。对精车ZK60镁合金试件进行滚压加工,试件表面粗糙度R a、R z最大减小了50.3%和48.1%;残余压应力最大可达-54.55 MPa;显微硬度从试件表层到内部基体材料逐渐降低,表层硬度值最大为92.83 HV 0.25,比基体材料硬度提高了15.32%。     

Corrosion behaviour of AA2024 aluminium alloy in different tempers in NaCl solution and with the CeCl3 corrosion inhibitor

The paper analyses the corrosion behaviour of naturally and artificially aged AA2024 alloy in NaCl solution and in the presence of an environment-friendly corrosion inhibitor, CeCl₃. On the basis of the values of polarisation resistance and corrosion current density, the corrosion resistance of the protective inhibitor film is established as well as the general corrosion resistance of this aluminium alloy. Resistance to pit formation is determined based on the difference in pitting and corrosion potentials while resistance to pit growth is determined based on the amount of charge consumed during pit growth. A scanning electron microscope is used to examine the morphology of the pits formed during the pitting corrosion testing, as well as to determine the cerium content on intermetallic particles and the matrix AA2024 alloy. The corrosion behaviour of AA2024 alloy is investigated after different test periods in NaCl solution and in the same solution with the CeCl₃ inhibitor. The corrosion resistance of both tempers of AA2024 alloy is more than one order of magnitude higher in the presence of CeCl₃. An explanation of the observed differences in the corrosion behaviour of the naturally and artificially aged AA2024 alloy is proposed. Different corrosion behaviour of the alloy after different test periods is also explained.     

雕刻技术的研制和应用

在对铝合金铸件进行X射线实时探伤时，由于采集回来的许多图像的目标物体的轮廓比较模糊，这样在评片时容易造成对铸件的误判和漏判。针对这种现象并结合这类图像噪声源多的特点，在研究常用卷积算法的基础上，采用特殊卷积（特殊的卷积核）操作，同时根据雕刻的艺术底色为灰色，最后给卷积结果加上灰度值128，实验结果表明图像中目标物体的轮廓变得更清楚，同时处理后的图像具有比较好的三维效果，这给工作人员在看图时带来了方便。     

Microstructures and Phase Transition Points of As-Cast Mg-Zn-Y System Alloys

As-east mierostruetures and their distribution of Mg-Zn-Y ternary alloy with high magnesium, low zinc and yttrium were examined using Nikon Epiphot optical microscopy （OM）, RigakuD/max-3C X- ray diffraetion （XRD）, and JEOL JSM-6700F scanning electron microscopy （SEM） equipped with an energydispersive X-ray spectroscopy （EDS）. In the as-east mierostructures, Yttrium and zinc tend to segregate at grain boundaries,     

半导体传感器在生物分析科学中的应用(英文)

回顾了半导体生化传感器 (ISFET 和 LA PS)在医学监测、免疫检测、免疫分析、D N A 杂交以及细胞培养等方面应用的进展。为使半导体器件适用于生化检测,对其中所采用的检测手段和取得的研究结果进行了分析。展望了通过与微流体网络相结合,基于半导体传感器的实验室芯片化的可行性。     

Oxidation of Hastelloy-XR Alloy for Corrosion-Resistant Glass-Coating

The oxidation behavior of Hastelloy-XR alloy was investigated to obtain the optimum surface condition for corrosion-resistant glass-coatings. The surface morphology of oxide scales changed significantly with variation of temperatureand oxygen partial pressure (po2 ). The oxidation kinetics was mainly parabolic independent of oxidation conditions.The oxide scales were consisted of inner Cr2O3 and outer spinel layers. The phase component of spinel layers wereMn1.5Cr1.5O4 and (Mn,Ni)(Cr,Fe)2O4 for the oxygen partial pressures po2<10 kPa and po2>10 kPa, respectively.The optimum oxidation condition to obtain an oxide scale for well-adhered glass-coating to the substrate was 1248 Kand po2 =0.01 kPa for the oxidation time of 43 ks.     

噻吩在镍基非晶态合金上的吸附和脱附

应用静态吸附、动态吸附、程序升温脱附和程序升温还原等实验方法，考察了噻吩在Ni基非晶态合金上的吸附和脱附行为。常温下，噻吩分子首先吸附在清洁的Ni表面，并立刻被活化，发生氢解反应，C-S键断裂，释放出烃类部分，S留在Ni原子上。噻吩可以在Ni基非晶态合金表面发生强度不同的化学吸附。弱化学吸附的噻吩可以脱附；强化学吸附的噻吩不会脱附，而在高温下发生氢解反应。     

催化裂解多产丙烯新技术

介绍了国内外利用蜡油或常压渣油等重质原料的增产丙烯技术CPP,ARGG FDFCC和TSRMP;还介绍了利用富含烯烃的混合碳四和催化裂化汽油等轻质原料的增产丙烯技术OCP,Propylur,Superflex,OCT,Meta-4和BASF公司的丁烯歧化工艺技术.     

反凝析现象对雅克拉凝析气处理工艺的影响

雅克拉凝析气田位于塔里木盆地北部，地处新疆维吾尔自治区阿克苏地区境内，它是中国石化集团公司西北分公司探明并投入开发的最大凝析气田，采用衰竭式开采。通过对井口物流的相态研究，认识了凝析气的反凝析规律，采取了提高凝析气中C^＋₃收率的方法，以确保外输干气的烃露点达到管输要求，并提高该气田开发的经济效益。在工艺方案设计过程中，通过多种工艺方案比选，确定选用膨胀机进口压力为6.0 MPa的膨胀机制冷工艺， C^＋₃收率达到92％以上，外输干气烃露点满足管输要求。     

Studies on high density polyethylene (HDPE) functionalized by ultraviolet irradiation and its application

The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m^?2 and 45 W m^?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m^?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m^?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m^?1 to 30.2 MPa and 158 J m^?1, respectively. Copyright © 2003 Society of Chemical Industry