有机氟改性丙烯酸酯树脂研究新进展

综述了有机氟改性丙烯酸酯树脂的化学改性制备方法(如常规乳液聚合、核壳乳液聚合和无皂乳液聚合等)及其研究新进展,总结了有机氟改性丙烯酸酯树脂在外墙涂料、防腐防污涂料等领域的应用现状,并展望了该研究领域的发展前景。     

Molecular modeling guided isotope separation of gadolinium with strong cation exchange resin using displacement chromatography

Molecular modeling was carried out using DFT to identify the suitable displacing agent for carrying out Gd isotope separation using displacement chromatography. EDTA was identified as the best eluting agent among EDTA, malic acid and citric acid. Displacement chromatography of Gd adsorption band in cation exchange resin was performed to observe the isotope effects in the Gd ion exchange processes involving complex forming reagent – EDTA. The heavier isotope of ¹⁶⁰Gd was found to be enriched at the front boundary of Gd adsorption band, while the lighter isotopes of ¹⁵⁵Gd and ¹⁵⁷Gd were enriched at the rear boundary.     

光谷大桥桥面铺装设计及施工

介绍了武汉光谷大桥（庙湖段）防水粘结体系的选择及Eliminator体系的防水设计,详细阐述了该桥面喷砂除锈、防水粘结体系和浇注式混合料GA10的施工工艺流程,并提出了相关施工控制重点.     

Preparation of pressure-sensitive adhesives from tung oil via Diels-Alder reaction

In this study, tung oil was polymerized with a dimaleimide (4,4’-methylene-bis(N-phenylmaleimide) (MPMI) and two diacrylates (poly(propylene glycol) diacrylate (PPGDA) and bisphenol A glycerolate diacrylate (BPAGDA) via Diels-Alder reaction (DA reaction) to prepare pressure-sensitive adhesives (PSAs). On the one hand, the polymer of tung oil and MPMI was readily prepared however it was too rigid to serve as a PSA. On the other hand, the polymerization of tung oil with PPGDA or BPAGDA resulted in PSAs with peel strengths ranging from 0.1 to 0.2 N cm⁻¹ and loop tacks ranging from 0.4 to 0.5 N. Nevertheless, tung oil reacted readily with acrylic acid to form adducts (TOAA) with lower content of conjugated diene groups than those of tung oil. The use of TOAAs instead of tung oil to polymerize PPGDA failed to increase the peel strength of the resulting PSAs. However, polymerizations of TOAAs with BPAGDA resulted in PSAs with much higher peel strengths and much higher loop tacks than the polymerization of tung oil with BPAGDA. In addition, the introduction of a small amount of MPMI in the polymerization of TOAA and PPGDA significantly shortened the curing time.     

改性环氧树脂浆材(SK-E系列)在挡水坝段渗漏处理中的应用

近年来,随着社会的不断进步以及经济的迅猛发展,水利行业获得深化进步,改性环氧树脂浆材由于具有良好的综合性能,在水利工程建设中有着较为广泛的有效应用,其重要性不容忽视。在此,将针对改性环氧树脂浆材(SK-E系列)在挡水坝段渗漏处理中的实践进行简要探讨。     

About the creep-fatigue interaction on the fatigue behaviour of off-axis woven-ply thermoplastic laminates at temperatures higher than Tg

The influence of plasticity and viscous effects on the fatigue behaviour of off-axis C/PPS laminates was investigated at temperatures higher than glass transition temperature. The obtained results clearly show that creep and fatigue are mutually influencing phenomena. Compared to the reference fatigue behaviour (with no prior loading), the fatigue life can be significantly extended with prior creep depending on loading conditions. Indeed, the strain accumulation seems to slow down after a long time creep preload, as if the time-dependent mechanisms were “evacuated” during this preload. The same conclusion can be drawn for the damage accumulation when the prior creep stresses are higher than the damage threshold or when the hold time is long enough, inducing significant plastic deformations. In angle-ply laminates, such deformations are associated with the reorientation of fibres. They contribute to the reduction of stress intensities, which results in increasing both fatigue life and maximum strain ɛ_max at failure during fatigue loadings.     

Elimination of Perfluorinated Surfactants – Adsorbent Evaluation Applying Surface Tension Measurements

The adsorption of perfluorooctane sulfonate (PFOS) onto activated carbons, nonfunctionalized polymeric adsorbents, and anion exchange resins was evaluated in batch as well as column experiments. It was found that the total PFOS capacity, adsorption kinetics, breakthrough times, and minimum effluent concentrations were highly dependent on the material properties, such as the inner surface area, pore size, functionalization, and hydrophobic character of the material, and on process parameters like temperature and ionic strength of the solution. The experiments furthermore revealed that surface tension measurements are a suitable method for online determination of PFOS concentrations above a defined value.     

The modelling technology of protective silicone coatings in terms of selected physical properties: Hydrophobicity,scrub resistance and water vapour diffusion

This paper deals with an analysis of the simultaneous influence of the factors of the silicone coating manufacturing process, such as the contents of the organic and silicone resins used in the paint formulations, on selected physical parameters determining the quality of the coatings: hydrophobicity, resistance to wet scrubbing and the ability to diffuse water vapour through the coatings. This analysis was performed using statistical models based on multiple regression analysis. The proposed statistical models proved to be useful for the optimization of the recipe configurations for silicone coatings. Combining the analysis results enabled the selection of the optimal ranges of values for the analysed factors, from a physical as well as an economic point of view.     

输送带用钢丝绳生产及技术进步

介绍输送带用钢丝绳的主要生产控制及使用要求。从捻制质量、结构选择、力学性能以及粘合力和镀层质量控制等方面介绍输送带用钢丝绳的生产工艺控制以及各生产工序质量控制的注意事项,指出钢丝绳弯曲疲劳、输送带张紧装置造成胶带张力过大和张力分布不均匀、外力过大、腐蚀、异物损伤以及接头抽丝是输送带用钢丝绳使用过程中断裂的主要原因,保证钢丝绳储存质量和改善钢丝绳接头工艺有助于减少输送带生产过程中的钢丝绳消耗。对输送带用钢丝绳的技术进步做了展望。     

Geckoprinting: assembly of microelectronic devices on unconventional surfaces by transfer printing with isolated gecko setal arrays

Developing electronics in unconventional forms provides opportunities to expand the use of electronics in diverse applications including bio-integrated or implanted electronics. One of the key challenges lies in integrating semiconductor microdevices onto unconventional substrates without glue, high pressure or temperature that may cause damage to microdevices, substrates or interfaces. This paper describes a solution based on natural gecko setal arrays that switch adhesion mechanically on and off, enabling pick and place manipulation of thin microscale semiconductor materials onto diverse surfaces including plants and insects whose surfaces are usually rough and irregular. A demonstration of functional ‘geckoprinted’ microelectronic devices provides a proof of concept of our results in practical applications.