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71.
Dushyant Kumar 《分离科学与技术》2020,55(15):2844-2854
ABSTRACT In this study, electrocoagulation (EC) was used to determine the optimum conditions on the basis of maximum chemical oxygen demand (COD) and color removal. At the optimum conditions chlorophenols (CPs), biological oxygen demand and total organic carbon (TOC) were determined. The biodegradability of wastewater was increased significantly with 63% COD, 98% color, 61% TOC and overall 65.51% reductions in CPs. Further, the electro-coagulated sludge was characterized by using different analytical techniques to assist the physicochemical and elemental phases, to find-out better management option, reusability for plant growth and safe disposal. Additionally, aluminum content (70.62%) was successfully recovered from sludge. 相似文献
72.
《Ceramics International》2020,46(7):9240-9248
The effects of Sr2+ substitution for Ba2+ on phase structure, microstructure, dielectric and electric properties for Ba4-xSrxSmFe0.5Nb9.5O30 (x = 0, 1, 2, 3 and 4) ceramics were systematically researched. X-ray diffraction patterns show that Ba4-xSrxSmFe0.5Nb9.5O30 (x = 0, 1, 2 and 3) ceramics are tetragonal tungsten bronze compound with a space group of P4bm, while the sample for x = 4 is an orthorhombic structure compound. The result can be corroborated by the analysis of Raman spectroscopy. As the Sr2+ contents increase from 0 to 3, the full width at half maximum of Raman lines of all samples increase gradually, indicating that the degree of lattice distortion increase. All tetragonal tungsten bronze ceramics exhibited a broad permittivity peaks, accompanied by frequency dispersion, indicating all samples are relaxor. The electrical properties of BSSFN ceramics were further studied by complex impedance spectroscopy. XPS spectrum shows that Fe2+ and Fe3+ coexist in Ba4-xSrxSmFe0.5Nb9.5O30 ceramics, and their proportion varies with the concentration of Sr2+. 相似文献
73.
电化学储能器件的性能很大程度上决定于其电极材料。碳材料具有来源广泛、化学稳定性好、易于调控、环境友好等优点,被广泛应用于各类能量存储系统,但仍存在能量密度低、倍率性能差等问题。本文从碳材料孔结构调控、杂原子掺杂、与金属氧化物复合三个角度,综述了构建高性能碳基储能材料的设计合成策略,介绍了其在锂/钠离子二次电池、超级电容器等领域的研究进展,对几种方法策略的优缺点进行了总结,并对未来的研究方向进行了展望。本文对高性能碳基储能电极材料的设计开发具有积极意义。 相似文献
74.
Rong Zhang Hailong Hu Hai Chen Siqi Li Cheng Ying Shuai Huang Qingting Liu Xudong Fu Shengfei Hu Ching-Ping Wong 《应用聚合物科学杂志》2020,137(39):49186
Recently, thermal interface materials (TIMs) are in great demands for modern electronics. For mechanically mixed polymer composite TIMs, the thermal conductivity and the mechanical properties are generally lower than expected values due to the sharply increased viscosity and poor filler dispersion. This work shows that addition of a small amount of polyester-based hyperbranched polymer (HBP) avoided the trade-off in mechanically mixed ABS/hexagonal boron nitride (h-BN) composites. After adding 0.5 wt% HBP, the maximum h-BN content in the composites increased from 50 to 60 wt%. The out-of-plane, in-plane thermal conductivity, and tensile strength of ABS/h-BN with 50 wt% h-BN were 0.408, 0.517 W/mK, and 18 MPa, respectively, and were increased to 0.729, 0.847 W/mK, and 32 MPa by adding 0.5 wt% HBP, while 0.972, 1.12 W/mK, and 29.5 MPa were achieved for ABS/h-BN/HBP with 60 wt% h-BN. The morphological and rheological results proved that these enhancements are due to the improved h-BN dispersion by decreasing viscosity of composites during mixing. Theoretical modeling based on the modified effective medium theory confirmed such results and showed that the interfacial thermal resistance also decreased slightly. Thus, this work demonstrates a facile and scalable method for simultaneously improving the thermal conductivity and mechanical properties of thermoplastic-based TIMs. 相似文献
75.
Somnath Karmakar 《Polycyclic Aromatic Compounds》2019,39(2):159-171
Eigensolutions of {X( = C,B,N),Y( = C,B,N)}-cyclacene graphs with next nearest neighbor (nnn) interactions have been obtained in analytical forms by adapting n-fold rotational symmetry followed by two-fold rotational symmetry (or a plane of symmetry). Expressions of eigensolution indicate the subspectral relationship among such cyclacenes with an even number of hexagonal rings e.g., eigenvalues of {X,Y}-di-cyclacene are found in the eigenspectra of all such even cyclacenes. Total π-electron energies and highest occupied molecular orbital and lowest unoccupied molecular orbital (HOMO–LUMO) gaps are calculated using the analytical expressions obtained and are found to vary negligibly with the variation of nnn interactions in such cyclacenes. Total π-electron energy is found to increase due to increase in restriction intensity of nnn interactions, whereas the HOMO–LUMO gap of polyacenecs having the even number of hexagonal rings and with one electron at each site (atom) decreases with increase in the restriction intensity since such systems contain degenerate half-filled HOMO (bonding or nonbonding) that are much more vulnerable for perturbations imposed through nnn interactions. 相似文献
76.
针对某乘用车发动机转速在1 573 r/min,压缩机开启时车内噪声异常的问题,对样车进行试验分析与诊断,对压缩机-支架系统进行仿真分析,提出改进方案并验证改进效果。利用LMS声振信号采集系统采集振动噪声数据,采用频谱分析、阶次追踪等方法,并结合压缩机-支架系统模态仿真结果,确定车内异常噪声是压缩机轴频21阶与压缩机-支架系统3阶模态频率接近发生共振造成的。通过优化支架结构来提高压缩机-支架系统3阶模态频率以此来避免共振,并换装橡胶驱动盘缓和压缩机输入扭矩波动。将改进结构进行整车试验,结果表明:匀速工况空调开启时问题转速下,车内噪声降低了2.5 dB(A);匀加速工况空调开启时发动机转速1 500~1 650 r/min区间,车内噪声无峰值,其余转速空调开启时改进前/后车内噪声基本不变,噪声波动趋势平缓。 相似文献
77.
78.
79.
《International Journal of Hydrogen Energy》2019,44(5):2905-2917
In this study, a multi-tubular thermally coupled packed bed reactor in which simultaneous production of ammonia and methyl ethyl ketone (MEK) takes place is simulated. The simulation results are presented in two co-current and counter-current flow modes. Based on this new configuration, the released heat from the ammonia synthesis reaction as an extremely exothermic reaction in the inner tube is employed to supply the required heat for the endothermic 2-butanol dehydrogenation reaction in the outer tube. On the other hand, MEK and hydrogen are produced by the dehydrogenation reaction of 2-butanol in the endothermic side, and the produced hydrogen is used to supply a part of the ammonia synthesis feed in the exothermic side. Thus, 30.72% and 31.88% of the required hydrogen for the ammonia synthesis are provided by the dehydrogenation reaction in the co-current and counter-current configurations, respectively. Also, according to the thermal coupling, the required cooler and furnace for the ammonia synthesis and 2-butanol dehydrogenation conventional plants are eliminated, respectively. As a result, operational costs, energy consumption and furnace emissions are considerably decreased. Finally, a sensitivity analysis and optimization are applied to study the effect of the main process parameters variation on the system performance and obtain the minimum hydrogen make-up flow rate, respectively. 相似文献
80.
This short communication presents a generic mathematical programming formulation for computer-aided molecular design (CAMD). A given CAMD problem, based on target properties, is formulated as a mixed integer linear/non-linear program (MILP/MINLP). The mathematical programming model presented here, which is formulated as an MILP/MINLP problem, considers first-order and second-order molecular groups for molecular structure representation and property estimation. It is shown that various CAMD problems can be formulated and solved through this model. 相似文献