Monodisperse‐porous poly(styrene‐co‐divinylbenzene) beads providing high column efficiency in reversed phase HPLC

A multistage polymerization protocol, the so‐called “modified seeded polymerization,” was developed for the production of monodisperse‐porous poly(styrene‐co‐divinylbenzene) providing high column efficiency as a packing material in reversed phase high performance liquid chromatography (RPLC). In the first stage of the multistage production, uniform polystyrene seed particles, produced by dispersion polymerization, were swollen by an organic agent (i.e., the diluent) and then by a monomer mixture containing styrene and divinylbenzene. The final porous particles were obtained in the monodisperse form by the polymerization of monomer mixture in the seed particles. By the use of a small size seed latex with low molecular weight and by the selection of the appropriate diluent, relatively small monodisperse‐porous particles with suitable pore structure could be achieved. In the reversed phase separation of alkylbenzenes, under isocratic conditions, theoretical plate numbers up to 40,000 plates/m were achieved by using 5.2 μm porous particles, obtained by a toluene‐dibutyl phthalate mixture as the diluent. No significant decrease in the resolution power was observed by the fourfold increase in the mobile phase flow rate. The column efficiency and the resolution observed with 5.2 μm monodisperse‐porous particles were significantly higher with respect to the currently available polymer based packing materials used in the reversed phase HPLC. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1430–1438, 2005     

用弯曲模型推导二组元复合材料杨氏模量新公式

用弯曲模型推导了适用于悬丝耦合弯曲共振法检测金属第二组元的杨氏模量的理论公式。通过实验数据计算。结果表明在两组元h2/h1≈1时与文献[2]的计算结果几乎接近，为用悬丝耦合弯曲共振法检测各种减振材料，陶瓷材料杨氏模量提供了理论公式；同时用改进后的弯曲模型推导出了适用于纤维复合材料横向杨氏模量的预测公式。     

Characteristics of electrical responsive chitosan/polyallylamine interpenetrating polymer network hydrogel

An interpenetrating polymer network (IPN) hydrogel composed of chitosan and polyallylamine exhibited electric‐sensitive behavior. The chitosan/polyallylamine IPN hydrogel was synthesized by radical polymerization using 2,2‐dimethoxy‐2‐phenylacetophenone (DMPAP) and methylene bisacrylicamide (MBAAm) as initiator and crosslinker, respectively. The swelling behavior of the IPN was studied by immersion of the gel samples in aqueous NaCl solutions at various concentrations and pHs. The swelling ratio decreased with increasing concentration and pH of electrolyte solution. The stimuli response of the IPN hydrogel in electric fields was also investigated. When a swollen the IPN was placed between a pair of electrodes, the IPN exhibited bending behavior in response to the applied electric field. The IPN also showed stepwise bending behavior depending on the electric stimulus. In addition, thermal properties of the IPN were investigated by differential scanning calorimetry (DSC) and dielectric analysis (DEA). © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2290–2295, 2002     

竖向荷载作用下斜桩承载特性数值分析

近年来,斜桩在桥梁、码头、海上钻井平台及大型输电线路塔架基础等工程中得到广泛应用,研究不同倾角斜桩的荷载传递及承载特性实用意义较大。基于ABAQUS软件,考虑桩土接触特性,模拟分析了不同倾角斜桩的承载特性。结果表明:桩身倾角不大于10°时,倾斜角对单桩的极限承载力影响不大,但会在桩身产生一定弯矩以及桩顶产生一定的水平位移;桩身轴力沿桩长方向的衰减速率随桩身倾角的增大而增大;斜桩桩身弯矩主要分布在桩顶下1/2桩长范围内,其最大值的位置不受桩身倾角以及桩顶竖向荷载的影响;斜桩桩身侧摩阻力沿桩长大致呈"S"型分布,其桩顶以下1/6桩长范围内侧摩阻力远远大于直桩。     

Underactuated miniature bending joint composed of serial pulleyless rolling joints

This paper proposes a miniature bending joint composed of serial rolling joints; it refers to the classification of small joints of other products and studies on surgical applications according to the structures and transmissions. To achieve this, a pulleyless rolling joint is introduced as a unit component and the basic design principle is established for the joint. A simple mechanism guarantees a smooth rolling contact using elastic fixtures. Underactuation, which prevents S-shaped curvature similar to buckling, is applied to drive the bending joint with a limited number of wire cables. Using a 1-DOF real-sized prototype, experiments were performed to measure the motion accuracy and payload capacity from various angles to evaluate the efficacy of an improved design that enhances the payload on the distal end. This novel joint is applicable to a wider variety of surgical tools and catheters relative to other candidates owing to its small constant curvature, reasonable payload capacity, and miniature size.     

硫代磷酸/伯胺N1923协同萃取锌和镉的机理

有机硫代磷酸/伯胺N1923协同萃取锌、镉的萃取率随pH的变化较为反常，可能因伯胺N1923与硫酸作用进而聚为反向胶束. 实验表明，如以(N1923)n.H2SO4表示反向胶束的实验式，N1923与H2SO4比值n多为3左右，可能与空间效应相关. 萃取机理为: M2+(a) +2BHA(o) + (2/n)SO42–(a) = MA2(o) + (2/n)(Bn.H2SO4)(o) + 2(1–2/n)H+(a)， n=3, 4, 5.     

表面处理对氮化硅陶瓷力学性能的影响

采用X射线衍射应力分析的sin2ψ法计算了Si3N4陶瓷试样的残余应力，并分别测量了表面处理前后Si3N4试样的力学性能。结果表明，经平面磨削后的Si3N4试样表面残余应力为拉应力，而抛光处理可适当降低残余应力。两种方法都使试样抗弯强度降低。     

REVERSED RESIDUALS IN AUTOREGRESSIVE TIME SERIES ANALYSIS

Abstract. Both linear and non-linear time series can have directional features which can be used to enhance the modelling and investigation of linear or non-linear autoregressive statistical models. For this purpose, reversed p th-order residuals are introduced. Cross-correlations of residuals and squared reversed residuals allow extensions of current model identification ideas. Quadratic types of partial autocorrelation functions are introduced to assess dependence associated with non-linear models which nevertheless have linear autoregressive correlation structures. The use of these residuals and their cross-correlation functions is exemplified empirically on some deseasonalized river flow data for which a first-order autoregressive model is a satisfactory second-order fit. Parallel theoretical computations are undertaken for the non-linear first-order random coefficient autoregressive model and comparisons are made. While the data are shown to be strongly non-linear, their correlational signatures are found to be convincingly different from those of a first-order autoregressive model with random coefficients.     

基于材料非线性的海洋柔性立管防弯器有限元分析

建立海洋柔性立管防弯器三维有限元模型,研究聚氨酯材料非线性对防弯器弯曲性能的影响．通过算例对比不同材料属性的计算结果,发现不考虑材料非线性的计算结果与理论分析结果吻合较好．试验结果表明考虑防弯器材料非线性的立管最大曲率比不考虑材料非线性的小10％．因此,在防弯器详细分析时很有必要考虑材料非线性．     

下喷自吸环流反应器中气-液局部相际传质模型

引言 下喷自吸环流反应器是在结合喷射、环流、自吸等优点基础上而开发出的一种新型高效反应器,开展该反应器内局部气液传质模型的研究,对于该反应器的优化设计及放大具有极重要的理论意义.多年来,经典传质理论的不足与局限都在经历不断的修正与改进.其中,激光多普勒测试在传质研究中的应用使得人们对湍流在传质中的重要性有了