PEG20000中试放大的工艺研究

在一定温度和催化剂作用下 ,分别利用本体聚合和溶剂聚合的方法 ,在 1L、10 0L不锈钢高压反应釜中合成了相对分子质量为 2 0 0 0 0的聚乙二醇 ,并讨论了聚合反应机理 ,研究了催化剂用量、反应温度、反应时间对聚合反应的影响。经过红外、核磁共振、凝胶色谱、化学分析等方法对产物进行了表征。     

高温预析出对Al-Zn-Mg系铝合金时效硬化和应力腐蚀的影响

研究了高温固溶后降温处理工艺对中强可使预析出LC52和7039铝合金的组织、时效硬化和应力腐蚀的影响。金相观察发现,高温预析出可优先在晶界处产生,并提高随后时效状态下晶界析出相的不连续分布程度,温度降低到一定程度晶内和晶界产生大量析出。合金拉伸性能和应力腐蚀结果表明,预析出在保持强度和塑性的同时,可提高抗应力腐蚀性能。而预析出温度降低,合金强度呈下降趋势。     

Grain Growth Behavior of 5Cr21Mn9Ni4N Steel Micro-Alloyed by Rare Earth

Grain growth behavior of 5Cr21Mn9Ni4NRE steel was experimentally studied at various solid solution treatment temperatures and holding for different times. The experimental results show that the 5Cr21Mn9Ni4NRE steel has the feature of sharp austenite grain coarsening after solid solution treatment at the temperature above 1150 ℃. RE added in the steel has the benefit to restrain grain growth and increase grain growth activation energy.     

LW15-252型SF_6断路器存在的问题和对策

国产SF6断路器已在电力系统中得到了广泛的应用,随着时间的推移,这种断路器存在的问题也逐渐地暴露出来。笔者介绍了LW15-252型SF6断路器在实际运用中存在的问题和采取的对策。     

离散事件系统状态反馈控制的几何理论的进一步拓广

本文研究了定义在状态-事件序列上的谓词的离散事件系统的状态反馈控制问题。离散事件系统的数学模型是自动机。状态反馈与闭环过程的关系及许多基本的几何性质得到了详细的阐明;在这些几何背景下,解决了离散事件系统状态反馈控制的拓广问题,包括关于简单谓词与一般谓词的问题。     

The Transport Properties of Hot Electrons in a Xenon/Methane Mixture

The results are given of numerical solution of the Boltzmann equation in a binomial approximation in view of elastic and inelastic electron collisions in Xe+CH₄ mixtures and in pure methane. The electron energy distribution functions obtained are used to calculate the electron transport coefficients for E/N values of up to several Townsends, i.e., the drift velocity, mobility, average and characteristic energies, diffusion coefficient. The results of calculation for pure methane fit the available experimental data. A similarity rule is found for the electron transport coefficients in a Xe+CH₄ mixture with different concentrations of methane molecules, which enables one to determine the values of transport coefficients in a mixture with a minor (less than 30 percents) methane content.     

Midplane-symmetry breaking in the flow between two counter-rotating disks

This paper considers the axisymmetric steady flow driven by exact counter rotation of two co-axial disks of finite radius. At the edges of the rotating disks one of three conditions is (typically) imposed: (i) zero velocity, corresponding to a stationary, impermeable, cylindrical shroud (ii) zero normal velocity and zero tangential fluid traction, corresponding to a (confined) free surface and (iii) an edge constraint that is consistent with a similarity solution of von Kármán form. The similarity solution is valid in an infinite geometry and possesses a pitchfork bifurcation that breaks the midplane symmetry at a critical Reynolds number. In this paper, similar bifurcations of the global (finite-domain) flow are sought and comparisons are made between the resulting bifurcation structure and that found for the similarity solution. The aim is to assess the validity of the nonlinear similarity solutions in finite domains and to explore the sensitivity of the solution structure to edge conditions that are implicitly neglected when assuming a self-similar flow. It is found that, whilst the symmetric similarity solution can be quantitatively useful for a range of boundary conditions, the bifurcated structure of the finite-domain flow is rather different for each boundary condition and bears little resemblance to the self-similar flow.     

On a three-dimensional axisymmetric boundary-value problem of nonlinear elastic deformation: Asymptotic solution and exponentially small error

In this paper, we study a three-dimensional axisymmetric boundary-value problem of a slender cylinder composed of a nonlinearly elastic material subjected to an axial force. Starting from the field equations, after a transformation and proper scalings, we identify a small variable and two small parameters, which characterize the present problem. Then, by an approach involving compound series-asymptotic expansions, a nonlinear ODE is derived, which governs the axial strain (the first-term in the series expansion). By imposing the zero radial displacement conditions at two ends, we manage to get the analytical solution of the axial strain, from which all other physical quantities can be deduced and thus the three-dimensional displacement field can be determined. Graphical results are presented, which show that there are two boundary layers near the two ends while the middle part is in a state of almost uniform extension. The asymptotic structure of the analytical solution is derived, which offers clear explanations to the structure of the deformed configuration and shows that the thickness of both boundary layers is of the order of the radius. We also point out the relevance of the present results to the St. Venant’s problem. In particular, we obtain the explicit uniformly-valid exponentially small error term, when the obtained deformed configuration is compared to the configuration of a uniform extension.     

化学还原法制备纳米铜粉的研究

本文采用KBH4在液相中化学还原CuSO4,并加入KOH和络合剂EDTA ,制得了纳米级的纯净的铜粉 ,通过调整反应物的浓度 ,可以消除Cu2 O等杂质。制备的纳米铜粉还存在一定程度的团聚 ,需试验加入分散剂来改善。     

求非线性方程近似解的逐次迭代法

本文提出了求解非线性问题的一种新方法——逐次迭代法，本方法先是给出一个初始近似解，然后将这个近似解进行校正迭代，使之接近于真实解，把一个非线性问题转化为一个线性问题来解决。