PP－g－AA的制备和表征

用熔融接枝方法制备了聚丙烯－ｇ－丙烯酸（ＰＰ－ｇ－ＡＡ）。用光电子能谱，广角Ｘ射线衍射，红外光谱和化学滴定方法对接枝物进行了定性和定量表征。讨论了单体和引发剂浓度对接枝率的影响，确定了用红外光谱法测定接枝物含量的经验公式     

氢电弧等离子体法制备的纳米镍铈粒子的催化特性

利用氢电弧等离子法制备具有储氢特性纳米镍铈粒子，并在气相苯加氢反应中研究了其催化特性，发现其催化活性与储氢特性及表面层中ＮｉＣｅ合金存在有关，且具有高的选择性和热稳定性，这与纳米粒子独特的结构及铈的加入有关。     

纳米级BaAl_2O_4微粉的制备和性质

分别用溶胶 -凝胶法、低温固相反应法 ,制得了纳米级BaAl2 O4微粉 ,用电镜观察了其形貌和粒径的大小 ,用X-射线衍射仪进行了物相分析 ,测定了其纯度与晶型 ,讨论了制备方法与粒度大小的相互影响     

Effect of γ-Irradiation on Phenolic Acids in Strawberries

ABSTRACT: The content of phenolic acids in strawberries was determined before and after gamma-irradiation in the dose range 1 to 10 kGy. Fresh whole strawberries were irradiated, acid-base-hydrolyzed, and purified on polyamide columns. The compounds were analyzed by reversed-phase chromatography and detected with a diode-array detector. Dose/concentration relationships were obtained for gallic acid, 4-hydroxybenzoic acid, cinnamic acid, p-coumaric acid, and caffeic acid. Whereas radiolysis of the individual acids in aqueous solutions led to their efficient degradation and to a notable hydroxylation, in the complex matrix of food no hydroxylation products were formed and only the amount of 4-hydroxybenzoic acid was affected by irradiation (build up: 0.68 ± 0.04 mg kg⁻¹kGy⁻¹).     

异丙苯在Cu-HMS分子筛上的催化氧化

以含Cu的中孔分子筛(Cu-HMS)为催化剂,研究异丙苯的催化氧化。研究发现,Cu-HMS催化剂的加入使异丙苯氧化的诱导期显著缩短。在75℃下,以Cu-HMS为催化剂,O2为氧化剂的纯异丙苯氧化反应,苯乙酮为主要副产物,反应的选择性和转化率都很高。当催化剂用量为1 5×10-4mol/ml时,反应8h后,异丙苯转化率为32 7%,目的产物的累积浓度(质量分数)为37 7%,选择性为99%;反应12h后,异丙苯转化率为42 4%,目的产物的累积浓度为46 3%,选择性为95 6%。     

以齐聚副产物制备耐高温泡沫剂

以齐聚副产物为原料在实验室分别以AlCl3、AlCl3络合物和杂多酸为催化剂合成并经磺化制备了用于提高石油采收率的耐高温泡沫剂，试验结果说明烷基碳数为16的异构烷基苯磺酸盐常温发泡性能最佳，烷基碳数大于20的正构烷基苯磺酸盐高温发泡性能最佳，后者特别适合高温蒸汽驱油。加入适当的非离子助剂及无机盐能够提高磺酸盐的水溶性，改善发泡剂溶液的稳定性。     

甲醇氧化羰化制碳酸二甲酯产物气相色谱分析

以Chromosorb 10 1为固定相 ,气相色谱法分析甲醇氧化羰化制碳酸二甲酯产物中水、甲醇、乙酸甲酯和碳酸二甲酯等组份的含量 ,考察了柱温 ,载气流量对分离度的影响 ,确定了适宜的分析条件 ,并用校正面积归一化法定量。该方法操作简便 ,快速 ,精度高 ,重现性好     

提高催化裂化柴油和液化气收率的方法及措施

介绍了利用现有的催化裂化装置 ,通过优化操作及运用MGD技术提高柴油和液化气收率的方法和技术措施。     

Asymmetric Hydrogenation of Activated Ketones on Platinum: Relevant and Spectator Species

The heterogeneous enantioselective hydrogenation of activated ketones over chirally modified platinum is reviewed with emphasis on identifying the role of the various species observed in this catalytic system. The past years have witnessed a continuous broadening of the scope of this catalytic system including new reactants and modifiers affording over 97% ee. New reaction pathways have been uncovered and the kinetic and mechanistic studies have been faced with a number of complicating factors caused by spectator species and interactions in solution and on the Pt surface. The previously proposed mechanistic models are critically assessed in the light of these new findings.     

三水草酸铀酰的红外激光化学

文章研究了三水草酸铀酰(UO_2C_2O_4·3H_2O)在兆瓦脉冲二氧化碳激光辐照下的红外激光化学反应,它与草酸铀酰的热分解反应不同,反应产物是二氧化铀和二氧化碳。反应的量子效率随激光波长不同而变化。