Sequential batch reactor for eucalypt kraft pulp effluent treatment with Trametes versicolor

BACKGROUND: A sequential batch reactor (SBR) was used for eucalypt kraft pulp effluent treatment with Trametes versicolor. A 2³ full factorial design and response surface methodology were applied to optimise the batch fermentation conditions. Effluent concentration, culture medium and inoculum age were the factors selected for this study in order to optimise the reduction of chemical oxygen demand (COD). RESULTS: The presence of Trametes Defined Medium (TDM) in the fermentation was required to obtain a significant COD reduction. Experiments in the batch reactor confirmed, in general, the predicted results of optimisation developed from Erlenmeyer batch assays. The T. versicolor culture remained active during 42 days of study in the SBR, providing approximately 80% of COD reduction. CONCLUSION: Trametes versicolor may be considered as very promising for the biological treatment of effluents from kraft pulp mills in an SBR system instead of the activated sludge mixed cultures traditionally used. Copyright © 2008 Society of Chemical Industry     

60Si2Mn合金钢发蓝泛红的分析研究

本文探讨了60Si2Mn合金钢发蓝原理，针对其膜层泛红问题，分析了热处理、表面前处理、发蓝及浸油等过程对发蓝质量的影响，由此采取了相应的技术措施，生产实践证明发蓝质量稳定，生产效率明显提高。     

Simultaneous sulfide and acetate oxidation under denitrifying conditions using an inverse fluidized bed reactor

BACKGROUND: Simultaneous removal of sulfur, nitrogen and carbon compounds from wastewaters is a commercially important biological process. The objective was to evaluate the influence of the CH₃COO^?/NO₃^? molar ratio on the sulfide oxidation process using an inverse fluidized bed reactor (IFBR). RESULTS: Three molar ratios of CH₃COO^?/NO₃^? (0.85, 0.72 and 0.62) with a constant S^2?/NO₃^? molar ratio of 0.13 were evaluated. At a CH₃COO^?/NO₃^? molar ratio of 0.85, the nitrate, acetate and sulfide removal efficiencies were approximately 100%. The N₂ yield (g N₂ g^?1 NO₃^?‐N consumed) was 0.81. Acetate was mineralized, resulting in a yield of 0.65 g inorganic‐C g^?1 CH₃COO^?‐C consumed. Sulfide was partially oxidized to S⁰, and 71% of the S^2? consumed was recovered as elemental sulfur by a settler installed in the IFBR. At a CH₃COO^?/NO₃^? molar ratio of 0.72, the efficiencies of nitrate, acetate and sulfide consumption were of 100%, with N₂ and inorganic‐C yields of 0.84 and 0.69, respectively. The sulfide was recovered as sulfate instead of S⁰, with a yield of 0.92 g SO₄^2?‐S g^?1 S^2? consumed. CONCLUSIONS: The CH₃COO^?/NO₃^? molar ratio was shown to be an important parameter that can be used to control the fate of sulfide oxidation to either S⁰ or sulfate. In this study, the potential of denitrification for the simultaneous removal of organic matter, sulfide and nitrate from wastewaters was demonstrated, obtaining CO₂, S⁰ and N₂ as the major end products. Copyright © 2008 Society of Chemical Industry     

服装低密度聚乙烯热熔胶化学粉碎的研究

服装粘合衬布的生产需要低密度聚乙烯热熔胶的微细粉末,介绍了对该热熔胶的化学粉碎技术所进行的实验研究,表明采用适当的助剂种类和用量以及适宜的工艺过程,通过化学粉碎可以得到合格的粉末产品。     

化学事故危害评估

根据化学事故危害的主要影响因素对化学事故进行危害评估,考查了危害纵深、人员杀伤率、危害地域估算、爆炸燃烧事故危害等内容。     

反应器和钢烟囱整体吊装的难点和对策

介绍了在金陵石化炼油厂200万t/a柴油加氢装置建设中,将质量为237t的反应器和高60m的钢烟囱成功进行整体吊装过程中的关键技术.通过此项工程实践得出以下结论象钢烟囱这样细长重物的整体吊装,由两台吊车抬立起后,再由主吊车独立吊装就位的施工方法简单易行,安全可靠,应用范围广;结构复杂细长杆的吊装强度和挠度计算比较复杂,在计算过程中可以忽略部分次要件的质量,分别以两吊点为支点计算上下吊点所受的力,然后再按比例放余量,使两吊点受力之和等于细长杆的重力,计算挠度时,可以适当地把问题夸大化,从而建立近似的力学模型;高压厚壁重型容器的吊装,宜直接设置专门吊盖与大法兰用螺栓把紧起吊;施工现场地基坚实是保证吊车站位和吊装施工的前提条件.     

Two‐phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone^®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone^® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone^® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry     

Al-Zn-Ce非晶合金的相选择与组织结构演化

本文研究了具有典型分解特征的Al-Zn-Ce非晶合金的形成和晶化过程，探讨了各种相的生成顺序。XRD和DSC测试结果表明强烈的化合物短程序有利于Al-Zn-Ce非晶合金的形成。在Al-Zn-Ce非晶合金的晶化过程中存在复杂的相选择行为，多种相的竞争形核和有限生长使其具有复杂的结构特点。同时，结果也表明冷速对该体系非晶的形成有很大影响。     

Mechanism and Optimal Application of Chemical Additives for Accelerating Early Strength of Lime-flyash Stabilized Soils

1IntroductionLime-flyashstabilizedsoil as a semi-rigid base mate-rial in highwayis widely usedin China.The goodintegri-ty,great bearing capacity,highstiffness and water-proof-ing quality areits special advantages.But itsinherent lowearly strength makes it…     

Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry