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961.
《International Journal of Hydrogen Energy》2019,44(58):30692-30704
Solid oxide fuel cell (SOFC) technology is attractive for its high-energy efficiency and expanded fuel flexibility. It is also more environmentally benign than conventional power generation systems. Recently, increasing attention has been paid to intermediate-to-low-temperature solid oxide fuel cells, which operating at 400–800 °C. Reducing its operating temperature can render SOFC more competitive with other types of fuel cells and portable energy storage system (EES) over a range of applications (eg: transportation, portable, stationary) and more conducive for commercialization. The high-performance composite anode requirements for low operating temperature (400–600 °C) demand microstructural and chemical stability, high electronic conductivity, and good electrochemical performance. The current high-temperature anode, Ni-YSZ (nickel-yttria stabilized zirconia) is generally reported with high interfacial resistance at reduced temperatures. This review highlights several potential composite anode materials (Ni-based and Ni-free) that have been developed for low-temperature SOFCs within the past 10 years. This literature survey shows that most of these anodes still exhibit relatively high polarization resistance. Focus is also given on reducing polarization resistance to maintain the cell power density. In literature, common approaches that have been adopted to enhance the performance of anodes are (i) selecting high-performance electrolyte, (ii) exploiting nanopowder properties, and (iii) adding noble metals as electrocatalysts. 相似文献
962.
《International Journal of Hydrogen Energy》2019,44(54):28668-28684
Gasification of solid waste is considered as a green and sustainable solution to perform energy recovery from several waste streams. This work aims to adapt an Euler-Euler multiphase mathematical model to understand the effects of physical and chemical factors, i.e. equivalence ratio (ER), steam to fuel ratio (SFR), and input plasma power of municipal solid waste (MSW) fixed bed gasification. The model is capable of simulating temperature and velocity fields, as well as gas and solid composition variations inside the reactor. A two-step pyrolysis model is used considering the pyrolysis mechanism of cellulose and plastic components. Drying, pyrolysis, homogeneous gas reactions, and heterogeneous combustion/gasification reactions were also included in the model. It was shown that the proposed model could provide accurate predictions against experimental data with a deviation generally lesser than 10%. Conclusion could be drawn that an ER of 0.3 and an SRF of 0.5 seems to be the most favourable conditions in order to obtain a high-quality syngas. Higher plasma power is favourable to obtain a high-quality syngas. However, the high electric power required penalizes the process efficiency and may compromise the economic viability of a plasma gasification project. 相似文献
963.
Recent work on reactive flash sintering of powders of two oxides, bismuth and of iron oxide, into pure single phase bismuth ferrite, which was accomplished in a few seconds at low furnace temperatures, is expanded to four constituents, alumina, lithia, zirconia, and lanthana, to produce reasonably dense polycrystals of a predominantly single phase, cubic LLZO(Al). Transformation and sintering occur concurrently at a furnace temperature near 700°C, in ambient atmosphere, in just a few seconds. The process may simplify the preparation of complex ceramics with new chemistries and dopants, which are predicted from ab intio calculations to have special attributes, not only because the powders sinter quickly at low temperatures, but also because the need for stoichiometric powders as starting materials is obviated. 相似文献
964.
Computing the convex hull of a set of points is a fundamental operation in many research fields, including geometric computing, computer graphics, computer vision, robotics, and so forth. This problem is particularly challenging when the number of points goes beyond some millions. In this article, we describe a very fast algorithm that copes with millions of points in a short period of time without using any kind of parallel computing. This has been made possible because the algorithm reduces to a sorting problem of the input point set, what dramatically minimizes the geometric computations (e.g., angles, distances, and so forth) that are typical in other algorithms. When compared with popular convex hull algorithms (namely, Graham’s scan, Andrew’s monotone chain, Jarvis’ gift wrapping, Chan’s, and Quickhull), our algorithm is capable of generating the convex hull of a point set in the plane much faster than those five algorithms without penalties in memory space. 相似文献
965.
Hong‐zhang Chen Qin He 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2012,87(12):1619-1625
The value‐added bioconversion of biomass is necessary due to the depletion of fossil fuels and deterioration of the global environment situation. Based on the analysis of characteristics of solid materials and the applicability of solid agro‐industrial residues used as feedstock for solid‐state fermentation (SSF), the authors established a value‐added bioconversion system for biomass using the key technology SSF. This article gives an overview of biomass bioconversion by SSF and the corresponding advances achieved in recent years. Copyright © 2012 Society of Chemical Industry 相似文献
966.
967.
C3S作为水泥熟料中最重要的矿物之一,其矿物结构和水化活性会受到固溶重金属离子的影响。利用化学分析、XRD、EDS-SEM和AFS等测试手段,研究了CdO对C3S矿物形成的影响及其在C3S中的固化能力,并探讨了镉离子在C3S中的固溶机理。研究表明:随着CdO掺量的增加,fCaO含量先减少后增加。当掺量小于1.0%时,CdO的掺入有利于C3S晶粒的形成和生长。掺杂后C3S中没有新相的行成,且C3S均为单斜结构:MⅠ型。烧成过程中,部分镉元素以CdO的形式挥发,且随着CdO掺量的提高,残留率逐渐降低。依据固溶体形成条件表明:镉离子主要取代钙离子形成置换固溶体((3-x)CaO·xCdO·SiO2),极少量的镉离子可能会进入钙氧八面体空隙形成间隙型固溶体(3CaO·yCdO·SiO2)。 相似文献
968.
《国际计算机数学杂志》2012,89(11):1329-1339
Drawing graphs on a 2D grid with prescribed size is NP-complete, even if we restrict ourselves to planar orthogonal grid drawings of trees. In this paper, we introduce a new algorithm for polyline drawing of free trees on 2D grids which are bounded by rectilinear polygons. Our algorithm uses straight skeleton and simulated annealing and aims to distribute the vertices of the given trees uniformly on the given bounded grids. Our experimental results show that our algorithm is relatively successful to achieve uniform distribution of the nodes of the given trees. To our knowledge, this paper is the first attempt to develop algorithms that draw trees on restricted 2D grids which are bounded by simple rectilinear polygons. 相似文献
969.
970.
Like in the case of macro deep drawing, the sheet thickness of mini drawn parts, with dimensions smaller than 20 mm and made from very thin sheets, is unevenly distributed and varies from minimum values resulted in the zone of part edge radius to maximum values in the upper zone of part vertical walls. Such variation of sheet thickness can cause for the resulted drawn parts some geometric deviations from their theoretic geometry or it can determine the parts failure. Hence, the main objective of the mini scale deep drawing processes is to obtain an increased accuracy by reducing the sheet thickness variation, or in other words to minimize the values of sheet thinning and thickening. The present paper analyses the results of investigations made by experiment and simulation concerning the use of different geometries of the tool components that permit to control and minimize the sheet thickness variation in the mini cylindrical drawn part zones where this phenomenon can generate negative effects and determine the part inaccuracy. The new geometries of tools were obtained by modifying the state of stress in the deformed sheet using adequate geometries of active surfaces of the die cavity and blank holder plate. 相似文献