Time dependent crystal-smectic transformation in perylene-containing polyimides

The crystalline conformations of perylene polyimides (PPIs), with alkyl spacers varying in length from C₃ to C₁₂ are discussed. Although modeling of single chains would suggest the possibility that those with odd number of CH₂ groups adopt a flat helical shape, X-ray diffraction suggests that the chains with odd and even spacers have the same conformation, due to the necessity to pack the perylene units. Upon annealing, the UV-vis absorption maximum red-shifts by about 10 nm, indicating enhanced π-stacking between the perylenes. Several changes in the spectra are seen with an increase in annealing time, at a given temperature. With an increase in annealing time, X-ray diffraction patterns show changes in the number of reflections, indicative of a crystal to mesogenic transition. The time required for this transition increases with a decrease in the spacer length, and annealing temperature, suggesting that the dynamics of this transition is very slow.     

离散事件系统状态反馈控制的几何理论的进一步拓广

本文研究了定义在状态-事件序列上的谓词的离散事件系统的状态反馈控制问题。离散事件系统的数学模型是自动机。状态反馈与闭环过程的关系及许多基本的几何性质得到了详细的阐明;在这些几何背景下,解决了离散事件系统状态反馈控制的拓广问题,包括关于简单谓词与一般谓词的问题。     

Observer design for autonomous discrete-time nonlinear systems

We obtain a necessary and sufficient condition for a discrete-time nonlinear system to be locally state equivalent to the nonlinear observer form. The result looks similar to the continuous counterpart except for the fact that Ad-operation is utilized instead of ad-operation.     

PTA压力离心机转子的改造

介绍了PTA压力离心机的主要性能参数、工作原理、分离效果的影响因素。为了增大沉渣在过渡区及脱水区滞留的时问，同时为达到在过渡区及脱水区对沉渣加入纯净水进行再冲洗的目的，对螺旋送料转子、挡液环、进料管进行了改造。改造后，沉渣在脱水区的停留时间由0．44a增至0．72s，2．5～3t／h的冲洗水对脱水区的沉渣进行冲洗效果较好。产品中的杂质质量分数较改造前减少15％，产品优等品率提高到99％。     

Total simulation model of the thermo-mechanical process in shape rolling of steel rods

The production of steel reinforcing bars for civil engineering is investigated by means of FEM-simulation. An integrated system for computing appropriate thermo-mechanical parameters of the rolling process is proposed. Generalized plane strain approach and coupled thermal-mechanical solution are applied. The microstructural model combines both the effect of the recrystallization mechanisms (static, dynamic and metadynamic) upon the austenite grain forming in hot rolling and that of phase transformation upon the final microstructure. The phases are created during interrupted below the temperature of martensite transition cooling. Thus a typical industrial process for thermo-mechanical strengthening of reinforcing bars, known as Tempcor-process is considered. Computational results are validated to experimental measured mechanical properties of the steel. By means of computer simulation the system can perform different solutions, giving the possibility to obtain a reasonable choice of different thermo-mechanical rolling conditions.     

Vibration cavitation behaviour of selected Ni-Mn-Ga alloys

Vibration cavitation erosion tests were carried out on Ni-Mn-Ga alloys of three different crystal structures: (1) the cubic austenite, (2) the non-modulated tetragonal martensite (T) and (3) the five-layered martensite (5M). All Ni-Mn-Ga alloys exhibited cavitation behaviour characterized by a step-wise curve of mass loss versus test time. This behaviour is correlated to the microstructural nature of the alloys as well as the surface conditions of the pre-test samples. The type and concentration of the defects at the surfaces were critical to the cavitation resistance of the alloys. The best cavitation resistant alloy was of a cubic austenitic structure, followed with the alloy of a tetragonal T-martensite. The largest material loss was found in the alloy with a 5M martensite. All the studied Ni-Mn-Ga alloys had an excellent cavitation resistance compared to that of the reference stainless steel, and they even excelled some NiTi alloys found in literature. This may be due to the superelasticity of the cubic austenite and the twinning of the martensitic phases.     

Structural transformation of FePt nanocomposite films during annealing and its effects on magnetic properties

Fe100-xPtx(x=30at.%-60at.% ) nanocomposite films were deposited on natural-oxidized Si(100) substrates by magnetron sputtering. The as-deposited films were annealed between 373 and 1073 K. In situ X-ray diffraction shows that the FePt nanocomposite films undergo a phase transformation from a disordered FCC phase to an ordered L10 phase between 673 and 773 K. The coercivity is 306 kA·m-1 whiles the average grain sizes is about 10 nm in the optimized FePt alloy film sample annealed at 673K. The adjustable coercivity and fine grain size suggest that this FePt nanocomposites system is suitable as recording media at extremely high areal density.     

水利水电的社会政策

首先研究中国水利水电未来研究的重点和方向:①社会变迁的环境效应;②水利水电社会影响评价;③多角度的生态———社会互动研究;④水利水电“社会经济”;⑤水利水电的“社会技术”进步;⑥水利水电规划的战略环境影响评价。接着,探讨社会政策原理、方法和技术,研究水利水电社会政策的重点和难点,策略。     

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白马庙气田蓬莱镇气藏储层致密 ,孔隙结构复杂 ,非均质性强 ,单井产能低 ,研究储层特征和受控因素 ,加强储层改造方是气藏效益开发的出路。储层精细研究揭示 ,气井产能受沉积相和构造条件控制 ;高、中产井与大而厚、物性好的河口坝、河道砂坝沉积微相有关 ,纵向上具很强的层段性 ,主产层集中在Ⅳ～③、Ⅲ～③两套砂组 ,其钻探成功率分别达 82 %和 10 0 % ;平面上多分布于主体构造和东南鼻状突起 ,二者高、中产能井分别占 30 %和 70 %。在深入的地质研究和储层压裂评层选井的基础上 ,采用多层打开、分层压裂、多层合采的方法可提高气井产能 ,并形成了一套行之有效的压裂评层选井的综合配套技术。采用该技术优选出 19口井 ,已实施 5口井全获成功 ,气产量成倍或十几倍增加 ,其中白浅 4 5井气无阻流量高达 18× 10 4m3 /d ,白浅 38井投产 16 5d净增产值 10 0余万元     

基于算术傅里叶变换的小波变换快速算法

利用算术傅里叶变换(AFT)计算离散傅里叶变换(DFT)可使其乘法计算量仅为D(N）。文章根据这一特点，结合Mallat算法原理及离散傅里叶算法结构特征，提出了一种离散小波变换的快速算法，给出了数学推导过程，并对实验结果进行了分析。