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991.
Titanium aluminides have become promising materials for high-temperature applications, but the relatively poor oxidation resistance
and elevated- temperature strength of these alloys limit their application to temperatures lower than 1000 °C. Niobium addition
improves the properties of titanium aluminide. However, the mechanical, metallurgical, and corrosion properties of Ti- Al-
Nb may be improved by treatment with a laser beam. Consequently, the present study examines the properties of Ti- 15Al- 20Nb
alloy subjected to the Nd:YAG laser melting process. Hardness in the surface region increases to twice the base material hardness,
and corrosion resistance improves considerably after laser treatment. 相似文献
992.
本文研究了激光微熔处理和高频感应加热淬火对球墨铸铁表面组织、接触疲劳强度和接触疲劳破坏过程的影响。结果表明,激光处理和高频淬火均可提高球铁的接触疲劳强度,但其接触疲劳破坏过程和形式却不同,前者是由于硬化层与基体间裂纹扩展造成大块深层剥落,后者则是表层裂纹在油楔作用下造成小块浅层脱落。 相似文献
993.
利用射频磁控溅射技术,以Ar和O2气混合气体为溅射气体在载玻片上制备了锐钛相TiO2薄膜。为了提高Ti02薄膜的光催化活性,在TiO2薄膜表面进行了钽修饰。利用X射线衍射(XRD),原子力显微镜(AFM)和UV-VIS-NIR分光光度计等技术对薄膜进行了表征。结果表明:对TiO2薄膜的表面进行适量的Ta元素修饰可以提高其光催化活性。 相似文献
994.
MA Guang LUO Yu CHEN Chun-huan REN Rui-ming WU Wei LI Zhi-qiang ZENG Yan-song 《中国有色金属学会会刊》2004,14(Z1)
The surface nanostructures of commercial pure titanium was realized by the modified shot peening equipment commonly used in industry through the special treatment process. The results show that high-energy-shot-peening(HESP) commonly used to prepare nanostructured surface layers can be achieved by the increase of pill size, pill speed, and treatment time in the commercial shot peening equipment. XRD, SEM and TEM were used to characterize the surface layer microstructure of treated specimens. The analytic results show that the main deformation mode of commercial pure Ti is twinning. At the beginning of deformation, the dislocations are formed and twins occur within or on plane, then twins in intersection plane appear, and at last the twin characteristics disappear in the surface layer after longer treatment time. The deformation layer depth increases with treatment time in a certain period when the pill size and speed are unchanged. And in the severe plastic deformation (SPD) layer in which the twins are not identified easily by using SEM, the nanocrystalline microstructures are found under TEM. The finest grain size in the surface layer is about 40 nm, and the depth of nanostructured layers is over 60 μm. The microhardness of the nanostructured surface layers is enhanced significantly after shot peening compared with that of the initial simple. 相似文献
995.
黄铁矿微生物浸出体系中的表面热力学和扩展DLVO理论 总被引:3,自引:1,他引:3
根据Young s方程的推导公式结合接触角的测定结果计算黄铁矿和氧化亚铁硫杆菌的表面能参数。结果表明,氧化亚铁硫杆菌的表面能明显高于黄铁矿的表面能。应用热力学计算氧化亚铁硫杆菌在黄铁矿表面吸附的自由能,发现其吸附自由能为正值,无法解释氧化亚铁硫杆菌在黄铁矿表面的吸附现象,而通过扩展DLVO理论建立的Lifshitz-van der Waals(LW)、Lewis acid-base(AB)和静电(EL)作用自由能与作用距离(d)之间的势能曲线,能够准确的预言氧化亚铁硫杆菌在黄铁矿表面的吸附现象。 相似文献
996.
核电工程材料的应力腐蚀破裂研究 总被引:3,自引:0,他引:3
杨武 《腐蚀科学与防护技术》1995,7(2):87-92
采用慢应变速率试验(SSRT)和U型弯曲试验技术研究了水中杂质离子、溶解氧(DO)、外加电位以及温度等对核电工程材料304不锈钢(SS)、316SS以及A533B压力容器用钢在高温水中应力腐蚀破裂(SCC)的影响,并结合电化学测试和表面膜分析结果进行了讨论,还根据304SS的U型弯曲和SSRT结果的差异提出了SCC加速试验的选择原则建议。 相似文献
997.
The early stages of corrosion of AISI 314, HK 40, and Alloy 800H have been studied in a strongly carburizing (aC=0.8), weakly oxidizing
atmosphere at 1098 K. Samples with electropolished and cold-worked surfaces were exposed for up to 400 min. at temperature, in a conventional corrosion rig or in a reaction vessel which was installed within an X-ray photoelectron spectrometer. The latter facility allowed the effects of the specimen heating rate and the rat of gas flow to be investigated. Examination of the corrosion products was accomplished with the aid of XPS, SEM, TEM, and conventional metallography. Initially, surface layers comprised of -Cr2O3, (Mn, Cr)3O4, and SiO2 formed, with layer structure, microstructure, and composition being functions of alloy composition and surface condition. Only on the cold-worked surfaces did a well-developed duplex oxide, consisting of an outer, Cr-rich oxide layer and an inner, SiO2 layer, form. In good agreement with the predicted value of 1.9 wt.%, between 1.4 and 2 wt.% Si in the alloy was required to form a complete SiO2 layer. After an incubation period, -Cr2O3 became unstable and transformed to M7C3; the carbides then grew by diffusion of metal from the alloy substrate. The presence of manganese, as (Mn, Cr)3O4, in the surface oxide influenced the mode of carbide growth, whereas the rate of carbide growth was severely suppressed by a continuous SiO2 layer which acted as a diffusion barrier both to metal and to carbon. It is argued that the SiO2 layer is most effective in reducing carburization when it is free from or contains very few structural defects. 相似文献
998.
电解充氢实验表明,随充氢时间的延长,ZL107合金试样中的含氢量增多,力学性能(尤其是抗拉强度)下降.但ZL102个别试样出现随充氢时间延长,含氢量反而降低的反常现象.初步分析认为,这与表面粗糙度有关.用机械加工制备了几种表面粗糙度Ra值不同的ZL102合金试样,在设定条件下作电解弃氢.结果表明,试样表面粗糙度的确影响充氢行为.随试样表面粗糙度值增加,其含氢量有相应增加的倾向. 相似文献
999.
1000.