HEp-2 cell pattern classification with discriminative dictionary learning

The paper presents a supervised discriminative dictionary learning algorithm specially designed for classifying HEp-2 cell patterns. The proposed algorithm is an extension of the popular K-SVD algorithm: at the training phase, it takes into account the discriminative power of the dictionary atoms and reduces their intra-class reconstruction error during each update. Meanwhile, their inter-class reconstruction effect is also considered. Compared to the existing extension of K-SVD, the proposed algorithm is more robust to parameters and has better discriminative power for classifying HEp-2 cell patterns. Quantitative evaluation shows that the proposed algorithm outperforms general object classification algorithms significantly on standard HEp-2 cell patterns classifying benchmark¹ and also achieves competitive performance on standard natural image classification benchmark.     

过渡金属离子掺杂纳米TiO2的相变与光催化活性

采用溶胶-凝胶法制备了掺杂Mo⁶⁺、Cr³⁺、Fe³⁺的改性纳米TiO₂光催化剂，并分别在550℃和580℃下对其进行了热处理，考察了热处理温度对掺杂纳米TiO₂相变和光催化活性的影响.通过光催化降解染料罗丹明B实验，对在不同热处理温度下Mo⁶⁺、Cr³⁺、Fe³⁺改性以及不同Mo⁶⁺掺杂量的TiO₂光催化活性进行了评价，发现掺杂离子对TiO₂光催化活性的影响与其对TiO₂相转变的作用是一致的，即抑制相转变的同时也提高了光催化活性.实验结果也进一步表明，Mo⁶⁺掺杂量为0.05％（摩尔分数）时的TiO₂具有最佳光催化活性.     

钛酸铝材料研究进展及应用

钛酸铝是一种优异的高熔点、低膨胀无机非金属材料。主要阐述了钛酸铝材料的微观结构，以及热分解、热膨胀及其影响因素。简述了钛酸铝材料的制备方法。讨论了合成的工艺条件及添加剂对钛酸铝材料性能的影响，并对其应用作了简单介绍。最后提出了改善钛酸铝材料性能的技术途径。     

1,4-二硝基咪唑的合成及其热分解

用二步反应合成1,4-二硝基咪唑(1,4-DN I),即先用乙酸酐对4-硝基咪唑3位上的N进行N-酰化,再通过硫酸-乙酸酐-硝酸钠混合液对酰化产物进行硝化合成1,4-二硝基咪唑,通过正交实验对合成工艺进行了优化,得到了较优的工艺条件:4-硝基咪唑、浓硫酸、硝酸钠、乙酸酐的摩尔比为2∶3∶8∶15,反应温度30~40℃,反应时间3 h。用DSC研究了1,4-DN I的热分解。     

Well defined CuI(NO), CuI(NO)2 and CuII(NO)X (X = O− and/or NO 2 − ) complexes in CuI-ZSMS prepared by interaction of H-ZSM5 with gaseous CuCl

In this note an exchange procedure of the acidic protons of H-ZSM5 by Cu^I ions through reaction with CuCl in the gas phase is described. In the so obtained Cu^I-ZSM5 exchanged zeolite the Cu^I ions are in well defined configuration and form with NO mono and di-nitrosyl complexes of high structural and spectroscopic quality. The Cu^I(NO)₂ species are transformed at RT into Cu^II(NO)X (X=O^– and/or NO ₂ ^– ) species which could represent an intermediate in NO decomposition.     

影响医疗垃圾热解特性的主要因素

用TG-DTA差热热重联用分析仪对影响医疗垃圾热解特性的主要因素,包括垃圾种类、升温速率、试样质量、实验终温和保温时间等进行了实验研究。结果表明,垃圾种类不同,表现出的起始温度、终止温度、峰温和失重率等反映医疗垃圾热解特性的主要参数不同;升温速率和试样质量对医疗垃圾热解特性的影响主要表现在起始温度和终止温度方面,而对峰温和失重率的影响较小;实验终温和保温时间的影响则主要表现在医疗垃圾的失重率上,即实验终温越高、保温时间越长,医疗垃圾的失重率越高,而对起始温度和终止温度的影响则可以忽略。     

热分解法制备纳米WO_3的结构特征及其分散行为研究

以钨酸铵为原料,在350～600℃不同温度下,用热分解法制备了纳米WO3。用透射电子显微镜、X射线衍射与电子衍射并结合热分析法,研究了热分解温度对纳米WO3的粒径大小、形状、晶型的影响,发现钨酸铵在225～375℃吸热分解,在400℃时完全分解为简单六方结构WO3和简单单斜结构WO3两相混合物,简单六方结构WO3在404℃左右向简单单斜结构WO3转变,500℃与600℃热分解产物都是简单单斜结构WO3。WO3粒径随温度升高而增大,分解温度从400℃升至600℃时,WO3粒径从20nm增大到100nm左右。用表面活性剂对纳米WO3进行表面修饰,发现两性型十二烷基二甲基甜菜碱可提高纳米WO3在水溶液与甲苯中的分散稳定性,沉降速度降低50%。     

城市径流总量控制指标分解及实现路径探索与实践

针对海绵城市径流总量控制目标,提出一种在城市规划体系中控制性详细规划和修建性详细规划阶段分解落实年径流总量控制率的方法。在控制性详细规划阶段分解径流总量控制指标时,分步骤先后确定各项低影响开发措施的面积率和下沉深度;在修建性详细规划阶段,配合径流总量控制指标分解结果,给出适宜的各项低影响开发措施的技术实施导则,以保证各单项指标的正确实施,并以某项目为例介绍了技术实施导则的构建方法。     

A study of PtRuO2 catalysts thermally formed on titanium mesh for methanol oxidation

Platinum-based catalysts, for the electro-oxidation of methanol, have been made by thermal decomposition of chloride precursors onto titanium mesh. The catalysed electrodes were successfully operated in acidic methanol electrolytes. Electrochemical characterisation has been carried out using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic polarisations. A complete analysis of the electrochemical results showed that the preliminary performance of the catalysed titanium mesh was comparable to that achieved with carbon-supported PtRu catalysts. The catalysts formed on titanium mesh by thermal decomposition also exhibited dimensional stability. Catalysed titanium mesh therefore appears to be a promising alternative to carbon-supported catalysts for certain fuel cell applications.     

由粗氧化锌制备纳米活性氧化锌的研究

采用碳酸氢铵法由粗氧化锌制备纳米活性氧化锌。研究了用碳酸氢铵法由粗氧化锌制备活性氧化锌的热力学、中间体碱式碳酸锌的主要组成和碱式碳酸锌热分解的温度对形貌的影响;考察了中间体碱式碳酸锌的热分解温度和时间对纳米活性氧化锌的纯度、白度、比表面积和表观密度的影响。碱式碳酸锌焙解生成纳米活性氧化锌适宜的温度和时间分别为600℃和1h时,产品中氧化锌的质量分数为97.6%,粒度<100nm,比表面积50m2/g,表观密度0.21g/cm3。