B对FeCoCrNiSiBx高熵合金激光熔覆层组织和硬度的影响

采用激光熔覆制备了FeCoCrNiSiB_x高熵合金熔覆层,利用光学显微镜、扫描电镜、X射线衍射仪和显微硬度计研究微量硼元素(摩尔比x=0、0.02、0.04、0.06、0.08)对FeCoCrNiSiB_x高熵合金熔覆层组织和硬度的影响。结果表明:无B高熵合金涂层组织主要为胞状晶。B的添加会促进枝晶的生成,逐渐形成鱼骨状树枝晶,但过量的B会破坏枝晶完整性,形成蠕虫状晶。此外,高熵合金熔覆层组织为FCC和BCC双相结构,B元素的添加会形成大量0.1~2.6 μm的Cr₂B第二相,有助于提高熔覆层硬度,其中x=0.06时激光熔覆层的硬度最高,约为537 HV0.2。     

A local view on the Hudetz correction of the Yager entropy of dynamical systems

In this paper, we define a local version of Hudetz correction for the Yager entropy of dynamical systems. It is proved that the introduced function is indeed a local entropy map for the Hudetz correction of the Yager entropy, in the sense that, the Hudetz correction of the Yager entropy of a continuous map on a compact metric space is attained by integrating the introduced local entropy.     

Microstructure and hydrogen storage properties of Ti–V–Cr based BCC-type high entropy alloys

In this work, the crystal structure and hydrogen storage properties of V₃₅Ti₃₀Cr₂₅Fe₁₀, V₃₅Ti₃₀Cr₂₅Mn₁₀, V₃₀Ti₃₀Cr₂₅Fe₁₀Nb₅ and V₃₅Ti₃₀Cr₂₅Fe₅Mn₅ BCC-type high entropy alloys have been investigated. It was found that high entropy promotes the formation of BCC phase while large atomic difference (δ) has the opposite effect. Among the four alloys, the V₃₅Ti₃₀Cr₂₅Mn₁₀ alloy shows the highest hydrogen absorption capacity while the V₃₅Ti₃₀Cr₂₆Fe₅Mn₅ alloy exhibits the highest reversible capacity. The cause of the loss of desorption capacity is mainly due to the high stability of the hydrides. The higher room-temperature desorption capacity of the V₃₅Ti₃₀Cr₂₅Fe₅Mn₅ alloy is due to higher hydrogen desorption pressure. After pumping at 400 °C, the hydrides can return to the original BCC structure with only a small expansion in the cell volume.     

基于熵权物元模型的长三角幸福河层次评价

将幸福河概念与长江三角洲区域一体化发展战略相结合，基于自然、人类社会、人水关系3个系统构建了包含24个指标的长三角幸福河层次评价指标体系；引入需求层次理论，以基础Ⅰ层次、基础Ⅱ层次、提升Ⅰ层次、提升Ⅱ层次、幸福层次5个层次作为幸福河的层次评价等级，运用熵权物元模型，建立了长三角幸福河层次评价模型，并对2018年长三角三省一市幸福河层次等级进行了评价。结果表明，三省一市均处于转化中的中间状态，其中江苏省向提升Ⅰ层次转化，浙江省、安徽省向提升Ⅱ层次转化，上海市向幸福层次转化，说明区域整体幸福河层次处于较高水平，但稳定性较差。     

Information system business affecting impact evaluation method

To effectively analyze the impact of continuous business interruption on the information system,an information system business affecting impact evaluation method (IBAIE) is proposed.First,we identify the main businesses of the system and quantify their vulnerability.Then,we take the businesses as the nodes of network topology and weight nodes based on the business significance.The orderly association between businesses is taken as the edges which are weighted based on the association between asset and business,and the directed weighted business network topology is obtained.Finally,the method of directed weighted network structure entropy is used to evaluate the change of system business network structure during the period from business interruption to recovery.Experiments show that this method has obvious advantages in evaluating accuracy compared to other methods,and can be applied in ensuring information system security.     

Study on the friction interface evolution during rotary friction welding of tube

In this study, evolution characteristics of the friction interface during rotary friction welding of tube were investigated. The friction interface that obtained at different welding stage were observed by confocal laser scanning microscopy. The results show that the friction interface transforms from sliding friction state to visco-plastic deformation state when the welding torque reaches the peak value. In addition, based on the thermodynamic framework extracted from the maximum entropy production principle, an analytical model for transition criterion from sliding friction to visco-plastic deformation was established. The model was verified by the corresponding experimental results of eight alloys, which indicated that the accuracy and generality of the model is satisfactory.     

加权信息熵与增强局部二值模式结合的人脸识别

针对人脸识别因光照、姿态、表情、遮挡及噪声等多种因素的影响而导致的识别率不高的问题，提出一种加权信息熵（IEw）与自适应阈值环形局部二值模式（ATRLBP）算子相结合的人脸识别方法（IE （w） ATR-LBP）。首先，从原始人脸图像分块提取信息熵，得到每个子块的IEw；然后，利用ATRLBP算子分别对每个人脸子块提取特征从而得到概率直方图；最后，将各个块的IEw与概率直方图相乘，再串联成为原始人脸图像最后的特征直方图，并利用支持向量机（SVM）对人脸进行识别。在AR人脸库的表情、光照、遮挡A和遮挡B四个数据集上，IE （w） ATR-LBP方法分别取得了98.37%、94.17%、98.20%和99.34%的识别率。在ORL人脸库上，IE （w） ATR-LBP方法的最大识别率为99.85%；而且在ORL人脸库5次不同训练样本的实验中，与无噪声时相比，加入高斯和椒盐噪声后的平均识别率分别下降了14.04和2.95个百分点。实验结果表明，IE （w） ATR-LBP方法能够有效提高人脸在受光照、姿态、遮挡等影响时的识别率，尤其是存在表情变化及脉冲类噪声干扰时的识别率。     

基于熵加权K-means全局信息聚类的高光谱图像分类

目的 高光谱图像波段数目巨大，导致在解译及分类过程中出现“维数灾难”的现象。针对该问题，在K-means聚类算法基础上，考虑各个波段对不同聚类的重要程度，同时顾及类间信息，提出一种基于熵加权K-means全局信息聚类的高光谱图像分类算法。方法 首先，引入波段权重，用来刻画各个波段对不同聚类的重要程度，并定义熵信息测度表达该权重。其次，为避免局部最优聚类，引入类间距离测度实现全局最优聚类。最后，将上述两类测度引入K-means聚类目标函数，通过最小化目标函数得到最优分类结果。结果 为了验证提出的高光谱图像分类方法的有效性，对Salinas高光谱图像和Pavia University高光谱图像标准图中的地物类别根据其光谱反射率差异程度进行合并，将合并后的标准图作为新的标准分类图。分别采用本文算法和传统K-means算法对Salinas高光谱图像和Pavia University高光谱图像进行实验，并定性、定量地评价和分析了实验结果。对于图像中合并后的地物类别，光谱反射率差异程度大，从视觉上看，本文算法较传统K-means算法有更好的分类结果；从分类精度看，本文算法的总精度分别为92.20%和82.96%， K-means算法的总精度分别为83.39%和67.06%，较K-means算法增长8.81%和15.9%。结论 提出一种基于熵加权K-means全局信息聚类的高光谱图像分类算法，实验结果表明，本文算法对高光谱图像中具有不同光谱反射率差异程度的各类地物目标均能取得很好的分类结果。     

First principles computational studies of spontaneous reduction reaction of Eu(III) in eutectic LiCl‐KCl molten salt

Using first principles calculations, we study fundamental mechanism of spontaneous reduction reaction of Eu³⁺ to Eu²⁺ in eutectic LiCl‐KCl molten salt. We decouple the reaction Gibbs free energy into enthalpy and entropy contributions by using rigorous thermodynamic formalism. Key structural features of the solvation shell are characterized by the radial distribution function and the coordination number. Compared with Eu²⁺, the Eu³⁺ ion has a more rigid framework of the solvation shells, corroborating its stronger electrostatic interaction with neighboring ligands of Cl^? ions and a more favorable state on the aspect of enthalpy. Computations on vibrational frequency, however, pose significant contribution of vibrational entropy to the reaction Gibbs free energy for the reduction. Vibration frequency of Eu²⁺ is smaller than that of Eu³⁺, driving a more positive change of the entropy in the reduction reaction. Furthermore, an Eu²⁺ diffuses more quickly than an Eu³⁺ in the LiCl‐KCl molten salt with switching mechanism of ligand Cl^? ions in the solvation shell. Our results propose that the spontaneity of the reduction reaction is driven by the entropic contribution by overcoming the penalty of the reaction enthalpy.