Low-Loss Organic Hyperbolic Materials in the Visible Spectral Range: A Joint Experimental and First-Principles Study

Hyperbolic media strengthen numerous attractive applications in optics such as super-resolution imaging, enhanced spontaneous emission, and nanoscale waveguiding. Natural hyperbolic materials exist at visible frequencies; however, implementations of these materials suffer substantial compromises resulting from the high loss in the currently available candidates. Here, the first experimental and theoretical investigation of regioregular poly(3-alkylthiophenes) (rr-P3ATs), a naturally low-loss organic hyperbolic material (OHM) in the visible frequency range, is shown. These hyperbolic properties arise from a highly ordered structure of layered electron-rich conjugated thiophene ring backbones separated by insulating alkyl side chains. The optical and electronic properties of the rr-P3AT can be tuned by controlling the degree of crystallinity and alkyl side chain length. First-principles calculations support the experimental observations, which result from the rr-P3AT's structural and optical anisotropy. Conveniently, rr-P3AT-based OHMs are facile to fabricate, flexible, and biocompatible, which may lead to tremendous new opportunities in a wide range of applications.     

Photophoretic Levitation of Macroscopic Nanocardboard Plates

Scaling down miniature rotorcraft and flapping-wing flyers to sub-centimeter dimensions is challenging due to complex electronics requirements, manufacturing limitations, and the increase in viscous damping at low Reynolds numbers. Photophoresis, or light-driven fluid flow, was previously used to levitate solid particles without any moving parts, but only with sizes of 1–20 µm. Here, architected metamaterial plates with 50 nm thickness are leveraged to realize photophoretic levitation at the millimeter to centimeter scales. Instead of creating lift through conventional rotors or wings, the nanocardboard plates levitate due to light-induced thermal transpiration through microchannels within the plates, enabled by their extremely low mass and thermal conductivity. At atmospheric pressure, the plates hover above a solid substrate at heights of ≈0.5 mm by creating an air cushion beneath the plate. Moreover, at reduced pressures (10–200 Pa), the increased speed of thermal transpiration through the plate's channels creates an air jet that enables mid-air levitation and allows the plates to carry small payloads heavier than the plates themselves. The macroscopic metamaterial structures demonstrate the potential of this new mechanism of flight to realize nanotechnology-enabled flying vehicles without any moving parts in the Earth's upper atmosphere and at the surface of other planets.     

A brief review of dynamic mechanical metamaterials for mechanical energy manipulation

In the past decades, many mechanical metamaterials with uncommon static properties have been reported. On the other hand, mechanical metamaterials possessing extraordinary dynamic performance, also referred to as acoustic/elastic metamaterials, have gained more and more attractions. Examples include acoustic cloaking metamaterials that can generate an invisible region for acoustic waves, zero-stiffness metamaterials that can isolate vibrating mechanical energy, origami-based metamaterials that can realize the directional transmission of elastic waves and so on. To better understand the mechanisms adopted in dynamic mechanical metamaterials and present a general view about the existing works, we have reviewed some representative works and categorized them based on the ways of how these mechanical metamaterials manipulate the interactions between matters and mechanical energy. To distinguish the different categories of the dynamic mechanical metamaterials, we use a pair of binary numbers to measure the changing states of the magnitude and direction of the energy flow, respectively. A summary of some research works with associated reference numbers is presented in this paper with emphasis on the operating frequency, working bandwidth, and characteristic size of the element.     

Spontaneous emission from a three-level atom placed in three-dimensional photonic crystals in the long-time limit

The paper describes the spontaneous emission from a three-level atom placed in a periodic dielectric microstructure which exhibits a complete three-dimensional photonic band gap. By using the Euler approach, the upper level population of the atom is calculated for a wide range of relationships between the Rabi frequency and the detuning of the atomic transition frequency from the upper band edge. The results indicate that there are three cases of the relationship between Rabi frequency and detuning, which determine distinctive states of the atomic population in the long-time limit. When the detuning is greater than the Rabi frequency, the upper level has a zero steady-state atomic population, which leads to enhancement of spontaneous emission. When the magnitude of the detuning is less than the Rabi frequency, the upper level has a nonzero steady-state atomic population, which leads to suppression of spontaneous emission. When the negative detuning is greater than the Rabi frequency, the upper level has a nondecaying oscillatory-state atomic population due to long-time atomic splitting. These three properties of the spontaneous emission are relevant to several optical devices on an atomic scale, such as optical memories, switches and clocks.