球形聚合物刷对卟啉镍的脱除规律研究

以八乙基镍卟啉（OEP-Ni）为模型物，探究聚乙烯基咪唑刷（PVIm@SiO₂）、聚乙烯基吡咯烷酮刷（PVP@SiO₂）和聚丙烯酸刷（PAA@SiO₂）对OEP-Ni的脱除差异性。结果表明，当脱镍温度为110℃、时间为3 h、脱镍剂质量分数为6 000μg/g时，PVIm@SiO₂、PVP@SiO₂和PAA@SiO₂对OEP-Ni的脱除率分别为28.9%、15.7%和9.8%;同时，3种聚合物刷对模拟原油的脱除率分别为9.9%、6.8%和5.8%。DFT计算结果表明，3种单体对镍的螯合能力为乙烯基咪唑（VIm）>乙烯基吡咯烷酮（VP）>丙烯酸（AA）,与聚合物刷对OEP-Ni的脱除效果一致。以四苯基镍卟啉（TPP-Ni）为模型物，研究PVIm@SiO₂、PAA@SiO₂和5%醋酸溶液对TPP-Ni的脱除效果，结果表明，PVIm@SiO₂和PAA@SiO₂对T...     

2021年《电源技术》新年寄语

2020年,对中国乃至世界,是新冠疫情肆虐的一年,也是中国民众抗疫之年。中国人民在党中央领导下万众一心、同舟共济、守望相助,实现了精准防疫、严格控疫,中国取得了阶段性抗疫重大胜利,社会生活和经济生活得到了迅速恢复。纵观世界,风景这边独好!     

Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe49.5Mn30Co10Cr10C0.5 multicomponent alloy

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0％respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2％were observed for fractured sample tested at-40℃,compared with 6.3％in fractured room temperature sample.     

Methods and mechanisms for uniformly refining deformed mixed and coarse grains inside a solution-treated Ni-based superalloy by two-stage heat treatment

The uniform refinement mechanisms and methods of deformed mixed and coarse grains inside a solution-treatment Ni-based superalloy during two-stage annealing treatment have been investigated.The two-stage heat treatment experiments include an aging annealing treatment(AT)and a subsequent recrystallization annealing treatment(RT).The object of AT is to precipitate some δ phases and consume part of storage energy to inhibit the grain growth during RT,while the RT is to refine mixed and coarse grains by recrystallization.It can be found that the recrystallization grains will quickly grow up to a large size when the AT time is too low or the RT temperature is too high,while the deformed coarse grains cannot be eliminated when the AT time is too long or the RT temperature is too low.In addition,the mixed microstructure composed of some abnormal coarse recrystallization grains(ACRGs)and a large number of fine grains can be observed in the annealed specimen when the AT time is 3 h and RT tem-perature is 980℃.The phenomenon attributes to the uneven distribution of δ phase resulted from the heterogeneous deformation energy when the AT time is too short.In the regions with a large number of δ phases,the recrystallization nucleation rate is promoted and the growth of grains is limited,which results in fine grains.However,in the regions with few δ phases,the recrystallization grains around grain boundaries can easily grow up,and the new recrystallization nucleus is difficult to form inside grain,which leads to ACRGs.Thus,in order to obtain uniform and fine annealed microstructure,it is a prereq-uisite to precipitate even-distributed δ phase by choosing a suitable AT time,such as 12 h.Moreover,a relative high RT temperature is also needed to promote the recrystallization nucleation around δ phase.The optimal annealing parameters range for uniformly refining mixed crystal can be summarized as:900℃×12 h+990℃×(40-60 min)and 900℃×12 h+1000℃×(10-15 min).     

CIT培训学院2021线上培训系列报道(十二)

五月的CIT线上培训基本围绕着"室内灯光照明设计"主题展开.有的讲师从自己多年做照明设计方案的经验出发,向学员们说明照明设计的作用和注意事项、灯光参数要点、照明设计所需图纸、表格和主要步骤、全宅各区域的照明设计思路和实施要点,以及如何通过各种照明技术和灯具来实现全宅不同区域的照明设计.有的讲师则以全宅灯光美学设计的关键点为核心,讲述如何同时满足普通照明与美学设计的要求,从而打造一个充满美感的全宅/定制影院灯光美学设计方案.当然,在整个方案的设计和施实行过程中,与客户、智能集成商和影音集成商的沟通问题也至关重要,讲师们分享的"经验教训",对学员们而言,也有助于提升日常的工作和客户服务质量. 到目前为止,CIT培训学院已经连续举办了近一年的线上培训,总共直播了将近五十场线上课程,涵盖的课程主题超过十个,涉及家用音频、家用视频、全宅智能、多房间影音解决方案、声学设计与处理、管理与市场推广等多个领域.考虑到与"管理与市场推广"相关的课程相对较少,CIT培训学院接下来将开展《中小型定制公司的管理与运营》《如何高效管理全宅项目》等课程,给予学员一些提高管理效率和项目质量的有效建议,包括如何改善人员架构、提高成单率、降低售后服务成本、监督和跟踪项目进度的注意事项、及时修正项目中的错误等等.另外,CIT培训学院也将再次聚焦"全宅智能"板块,举办以"全宅智能中控系统新思路"为主题的线上培训课程.     

欢迎订阅《锻压技术》杂志(月刊)

国内外公开发行,全国各地邮局均可订阅,逾期未订上者可与编辑部联系邮购《锻压技术》杂志1958年创刊,中国机械工业联合会主管、北京机电研究所有限公司和中国机械工程学会塑性工程分会主办。本刊是全国锻压行业会刊,全国中文核心期刊,被国内外多个著名检索系统收录。突出技术内容,注重技术和信息相结合,全面反映锻压行业的技术进步和发展趋势。     

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《锻压技术》杂志自2008年起设立"读者信息反馈卡",旨在加强刊物与读者的交流,促进刊物质量的提高,并竭诚为读者服务。反馈卡填写要求:内容填写完整、没有遗漏,提供的信息准确、详细,字迹书写清晰、整洁。如收到的反馈卡内容填写不完整,字迹不清、无法辨认,通讯地址模糊、不详细等,编辑部将不予邮寄杂志,特此声明。     

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