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(2)从 Frank-Thompson 公式出发,在只存在一种电解质的情况下,赵慕愚认为对阴阳离子价态相等的电解质,其单个离子活度系数评算公式可表达如下: 相似文献
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A new model for the surface tension of binary and ternary liquid mixtures based on Peng- Robinson equation of state 下载免费PDF全文
Based on the surface chemical potential and Peng-Robinson equation of state,a newmodel is proposed to predict and correlate the surface tensions of binary and ternary liquid mix-tures.Using this method,the surface tensions of 73 binary and 8 ternary systems are calculatedwith average relative deviations 1.35% and 3.52% respectively.The proposed model is simple, re-liable and accurate. 相似文献
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本文提出了一个简易的热力学方程式,式中仅包含一个表示长程作用力的静电项,再加上一个表示两粒子间的短程作用项,即可用以计算温度为373—573K,压力为0.1—100MPa、氯化钠浓度为0—10.4mol/kgH_2O的水溶液中氯化钠和水两者的活度系数,计算简便,易于推广使用. 相似文献
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本文将(I)报中提出的简易方程式推广应用到823K和100MPa的NaCl水溶液,NaCl的最高浓度达65.2wt%(三相点时的饱和溶解度)下热力学性质的计算.这些热力学性质包括溶液中水的活度、氯化钠的平均离子活度系数、溶液的Gibbs自由能,计算值与实验值吻合较好.文中列出了不同温度压力下的w和△_8G_2~0/RT值及其变化曲线、和本文提出的参考压力值P_r,为高温高压下电解质水溶液的研究作了初步的探索. 相似文献
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In the design of chemical processes, such as catalytic cracking of bitumen and heavy oil, the knowledge of phase behavior at the critical endpoint is essential. Based on the PR equation of state, the algorithm developed by Heidemann and Khalil for calculating critical properties was used to compute critical points. An algorithm for determining the equilibrium phase of the critical point using the tangent plane criterion was developed, and was used to calculate the critical endpoints of different mixtures, including non-polar, polar and associating systems. The critical endpoint, representing the type of the phase behavior, was employed to fit the interaction parameter of mixtures in critical state at high pressure. Lines of critical endpoints for ternary mixtures were also determined with the algorithm. 相似文献
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An interracial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By comblninE the interracial equation of state with Boudh-Hir and IViansoori‘s model, a molecular thermodynamic model has been proposed. The interracial tension of surfactant-oil-water systems can be calculated from the surface tensions of pure oil and water by this model. The interfacial tension data for sodium dodecyl sulphate-heptane-water system, polyoxyethylene n-octylphenol-heptane-water system and hexadecyl trimethyl ammonium bromide-heptane-water system have been correlated. By using the adjustable parameters obtained, the interfacial tensions of these systems at other temperatures have been predicted. Both the correlated and the predicted values are sstisfactorv. 相似文献