高Al2O3含量高炉渣的脱硫行为

针对高炉炉渣中Al₂O₃含量(质量分数)偏高导致炉渣黏度增大、流动性变差、脱硫能力下降的问题,利用双层石墨坩埚模拟铁液滴下穿过炉渣的过程,探究了R[w(CaO)/w(SiO₂)],w(MgO)/w(Al₂O₃)和w(Al₂O₃)对高Al₂O₃型CaO-SiO₂-MgO-Al₂O₃四元高炉渣系脱硫能力的影响.当w(MgO)/w(Al₂O₃)=0.50,w(Al₂O₃)=20%时,R由1.05提高到1.35,炉渣的脱硫能力增强;当w(Al₂O₃)=20%,R=1.30时,w(MgO)/w(Al₂O₃)由0.25提高到0.55,炉渣的脱硫能力增强;当w(MgO)/w(Al₂O₃)=0.40,R=1.30时,w(Al₂O₃)由12%提高到20%,炉渣的脱硫能力下降.     

过渡金属改性对MgO/ZSM-5催化剂苯-甲醇烷基化性能的影响

采用过渡金属对2.5%Mg O/ZSM-5催化剂进行负载改性,考察其苯-甲醇烷基化性能,结果表明,Ni和Fe改性催化剂因改性后弱酸量大幅增加,苯转化率提高,分别为56.6%和55.8%;W和Mn改性催化剂二甲苯选择性较高,约为35%;与其他改性催化剂相比,Co和Mo改性催化剂上的苯转化率和二甲苯选择性没有明显优势。选择改性效果较好的双金属催化剂进行苯-甲醇烷基化高空速(15 h-1)长时间运转实验,催化剂初始活性均大于57%,反应20 h时,苯转化率约50%,20 h后烷基化活性迅速下降,是由于催化剂积炭失活所致。     

Effect of MgO on the composition and properties of alite-sulphoaluminate cement

The effect of MgO on the composition and properties of alite-sulphoaluminate cement clinker with commercial-grade raw materials such as limestone, clay, gypsum and fly ash as starting materials has been investigated in order to confirm results previously obtained with pure raw materials. The experiment results confirm that the addition of MgO at about 2-5% can improve the burnability of raw meal, promote the absorption of free lime and the formation of C₃S and C₄A₃S¯. In addition, it is shown that this can also increase the strength development of the cement and shorten the setting time. When the content of MgO reaches about 8%, the strength of the cement decreases slightly and the setting time is extended.     

Syngas production from methane reforming with CO2/H2O and O2 over NiO–MgO solid solution catalyst in fluidized bed reactors

Catalyst performance of NiO–MgO solid solution catalysts for methane reforming with CO₂ and H₂O in the presence of oxygen using fluidized and fixed bed reactors under atmospheric and pressurized conditions was investigated. Especially, methane and CO₂ conversion in the fluidized bed reactor in methane reforming with CO₂ and O₂ was higher than those in the fixed bed reactor over Ni_0.15Mg_0.85O catalyst under 1.0 MPa. In contrast, conversion levels in the fluidized and fixed bed reactor were almost the same over MgO-supported Ni and Pt catalysts. It is suggested that the promoting effect of catalyst fluidization on the activity is related to the catalyst reducibility. On a catalyst with suitable reducibility, the oxidized and deactivated catalyst can be reduced with the produced syngas and the reforming activity regenerates in the fluidized bed reactor during the catalyst fluidization. In addition, the catalyst fluidization inhibited the carbon deposition.     

溶胶-凝胶法合成Ba0.6Sr0.4TiO3/MgO及介电性能研究

采用溶胶-凝胶法合成了Ba_(0.6)Sr_(0.4)TiO_3/MgO复合粉体,研究了烧结温度和合成工艺对陶瓷样品介电性能的影响。研究结果表明,经650℃热处理即可得到颗粒细小均匀的超细Ba_(0.6)Sr_(0.4)TiO_3/MgO粉体,平均粒径在200 nm左右。烧结温度对陶瓷样品的介电生能有明显的影响,1300℃烧结的陶瓷样品具有优良的性能。与二步合成工艺相比,一步合成工艺制备的陶瓷样品具有更好的介(?)性能。     

The effect of Al content on the wettability between liquid iron and MgOAl2O3 binary substrate

In the present study, the wettability between liquid iron with two different Al contents and MgOAl₂O₃ binary substrates was studied in reducing atmosphere. The contact angles between liquid iron with 18?ppm Al and MgO, MgO·Al₂O₃, Al₂O₃ were 133.5°, 113.7°, 126.9° respectively. With the variation of the substrate composition, the contact angles for the intermediate binary phases of the three components (MgO, MgO·Al₂O₃, Al₂O₃) obeyed the Cassie theory. In the experiment using iron with 370?ppm Al, all the contact angles were higher than that using low Al-containing iron. The surface of the iron drop was covered with an oxide layer, which mainly consisted of many small particles. With the variation of the substrate gradually from MgO to Al₂O₃, the composition of the oxide layer changed from MgO·Al₂O₃ to CaOAl₂O₃. The formation of the oxide layer prevented the spreading of liquid iron, leading to the increase of the contact angle.     

MgO单晶

透明MgO单晶的熔点高达2800℃,是无残留气孔的高致密性材料。因其光透过率、折射率、热导率、电绝缘性、化学稳定性、机械强度等方面性能优异,具有广泛的用途:(1)可作为光学透明材料。由于从紫外到红外的宽范围内,光透过率Τ≥80％,可用于普通照相、紫外照相、特殊光学系统、光纤以及特殊机械光学装置;(2)可作为耐高温、高压窗口材     

Influence of MgO on the formation of Ca3SiO5 and 3CaO·3Al2O3·CaSO4 minerals in alite-sulphoaluminate cement

The influence of MgO on the formation of Ca₃SiO₅ and 3CaO·3Al₂O₃·CaSO₄ minerals in alite-sulphoaluminate cement is reported in this paper. The results show that adding a suitable amount of MgO can lower the clinkering temperature, promote the formation of Ca₃SiO₅ and 3CaO·3Al₂O₃·CaSO₄ minerals, and help in the coexistence of the two minerals in the clinker. MgO may obviously decrease the formation of Ca₃Al₂O₆, and increase the SiO₂ content incorporated into the interstitial phase.     

烧成镁尖晶石滑板的研制与使用

研究了不同组成尖晶石、氧化铝微粉对镁尖晶石滑板性能的影响。以优质高纯镁砂、合成尖晶石为主要原料 ,加入适量氧化铝微粉 ,选用有机结合剂 ,经高温烧成、浸油、热处理制成的镁尖晶石滑板 ,在国外 16 0t钢包上的使用寿命达到 2次。