Effect of Ti content on the microstructure and mechanical behavior of (Fe36Ni18Mn33Al13)100−xTix high entropy alloys

The microstructure and mechanical properties studies of a series of two-phase f.c.c./B2 (ordered b.c.c.) lamellar-structured, high entropy alloys (HEA) Fe₃₆Ni₁₈Mn₃₃Al₁₃Ti_x with x up to 6 at. % Ti have been investigated. X-ray microanalysis in a TEM showed that the Ti resided mostly in the B2 phase. The lamellar spacing decreased significantly with increasing Ti content from 1.56 μm for the undoped alloy to 155 nm with an addition of 4 at. % Ti, leading to a sharp increase in room-temperature yield strength,σ_y, from 270 MPa to 953 MPa, but with a concomitant decrease in ductility from 22% elongation to 2.3%. Annealing at 1173 K for 20 h greatly increased the lamellar spacing of Fe₃₆Ni₁₈Mn₃₃Al₁₃Ti₄ to 577 nm, producing a corresponding decrease in σ_y to 511 MPa. The yield strengths of all the doped alloys decreased significantly when tensile tested at 973 K with a concomitant increase in ductility due to softening of the B2 phase. The fracture mode changed from cleavage at room temperature to a ductile dimple-type rupture at 973 K. The results are discussed in terms of the Hall-Petch-type relationship.     

生物基异己糖醇聚酯的制备及其构效关系研究进展

异己糖醇是一类碳水化合物衍生二元醇,具有高刚性、手性、亲水性和低毒等特性,在制备新型生物基、生物可降解高分子材料方面具有广阔的发展前景。围绕近年来研究较为充分的全脂肪型及半芳香型异己糖醇基均聚酯与共聚酯,综述了其合成、热学性能、力学性能、生物降解性能及潜在应用,探讨此类聚酯的高效聚合反应工艺及构效关系。异己糖醇结构单元的引入可有效提高聚合物的玻璃化转变温度,以及促进其水解和生物降解性能,在构建具有更高性能的环境友好型聚酯方面具有较高潜力,有望应用于工程塑料、纤维、生物医药等领域。此类生物基聚酯的大规模商业化需进一步开发更高效、温和的聚合反应工艺以攻克其热敏感和热降解问题。     

Exploring place attachment and visions of nature of water-based recreationists: the case of the longitudinal dams

This study concerns an innovative project in the Dutch river Waal: the construction of longitudinal dams. By splitting the river into a main and secondary channel, these dams significantly impact the river landscape and the way it is used by different stakeholders. We report the results of a baseline study of the expectations local water-based recreationists (fishermen and boaters) had of the longitudinal dams before they were constructed. In addition, we explore their levels of place attachment, and use the visions of nature approach to elicit their lay philosophy of nature. We found that fishermen were more strongly attached to the area than boaters. Though expectations of the dams were generally negative, this differed significantly between fishermen and boaters, and between different dimensions of landscape change. We demonstrate the relevance of place attachment and visions of nature for understanding how recreationists perceive landscape change.     

Stability and antioxidant activity of anthocyanins from purple sweet potato (Ipomoea batatas L. cultivar Eshu No. 8) subjected to simulated in vitro gastrointestinal digestion

The study was aimed to investigate the stability and antioxidant activities of anthocyanins obtained from purple sweet potato via an in vitro digestion system. Three fractions of anthocyanin-rich extracts were obtained via ODS packing column. Anthocyanins and copigment (primary phenolic acids) of fraction 2 were investigated during simulated an in vitro gastrointestinal digestion. Anthocyanins and copigment were recognised by UPLC-LTQ-MS/MS. Besides, anthocyanins were found effectively stable under the acidic gastric digestion conditions. However, the anthocyanins recovery was greatly decreased at around 10% after intestinal digestion. An association between the type, number of acylated group and stability to intestinal digestion was found. Di-acylated anthocyanins possessed higher stability compared with mono-acylated anthocyanins and the stability of acylated group in digestion process followed the order of p-hydroxybenzoyl > feruloyl > caffeoyl. However, there was no much difference in copigment content which was found during digestion process. Moreover, the radical scavenging ability and xanthine oxidase (XO) inhibition showed that the digestion products possessed good biological activities mainly due to its anthocyanin composition.     

基于高斯混合模型和AdaBoost的夜间车辆检测

针对夜间车辆检测精度相对不高的问题，提出通过构建车头灯对空间几何关系的高斯混合模型（GMM）和采用逆投影车辆样本的AdaBoost分类器准确检测夜间车辆的方法。首先，在交通场景中根据车头灯对的空间位置关系设置逆投影面，通过图像预处理粗定位车灯区域；其次，在逆投影图像下利用车头灯对的空间几何关系构建车灯对的高斯混合模型，初步匹配车头灯对；最后，采用逆投影车辆样本，利用AdaBoost分类器进一步准确检测车辆。实验在3个交通场景的检测结果表明，与原始图像下的AdaBoost方法相比，所提方法的检测率提高了1.93%，漏检率降低了17.83%，误检率降低了27.61%；与D-S （Dempster-Shafer）证据理论方法相比，检测率提高了2.03%，漏检率降低了7.58%，误检率降低了47.51%。所提方法提高了相对检测精度，减少了地面反光和影子等的干扰，满足交通场景中夜间车辆检测的可靠性和准确性的要求。     

The relationship between refractive index and optical properties of absorbing nanoparticle

This article represents an analytical formulation for optical properties of absorbing metallic nanoparticles in visible region of electromagnetic spectrum based on Mie theory, in order to find a clear relationship between fundamental characteristics of nanoparticles with their spectral behavior and color coordinate in CIELAB color space. Calculations were performed on nanoparticles with various diameters (d = 50, 100, and 200 nm), as well as complex refractive index with different real (n = 1.5, 2.0, 2.5, and 3.0) and imaginary (k = 0.001 and 0.1) parts. Obtained results reveal that scattering phenomena in nanoparticles are strongly linked to the particle size parameter and complex index of refraction. The results indicate that the reflectance and lightness (L*) of nanoparticles increases as a result of increase in their size and real part of complex refractive index and decrease with increasing the imaginary part of complex refractive index. The CIELAB colorimetric system was used for analysis the color of nanoparticles. According to obtained results, all nanoparticles have greenish‐blue color, and undergo color change as a result of varying in their size and the complex refractive index. © 2015 Wiley Periodicals, Inc. Col Res Appl, 41, 477–483, 2016     

Innovative Work Behaviour: The Impact of Comprehensive HR System Perceptions and the Role of Work–Life Conflict

Human resource (HR) systems have the potential to both foster innovative work behaviour (IWB) and reduce work–life conflict (WLC)—enabling employees to engage in IWB. We investigate the proposed relationships between comprehensive HR systems, WLC and IWB using variance-based structural equation modelling. We found that HR systems that are perceived as comprehensive significantly enhance IWB and decrease feelings of WLC. Contrary to our expectation, we found a significant yet positive effect of WLC on IWB. Employees may respond to WLC constructively by being innovative, improving their environment and making the work–life interface manageable. By promoting IWB, HR systems might also help employees to deal with residual—and, perhaps, unavoidable—levels of WLC.     

Effects of specimen and grain sizes on compression strength of annealed wrought copper alloy at room temperature

Variations in compression yield strength of annealed wrought CuAl7 copper alloy with specimen diameter (t) in 1–10 mm range and grain size (D) in 24–172 μm range were investigated. Both grain size effect and feature size effect could be observed. The compression yield strength increased with a reduction in grain size or specimen diameter, and varied with the t/D ratio in no particular manner. However, when t was held constant, the compression yield strength increased as the ratio increased. When D was held constant, the strength decreased as the ratio increased. The Hall–Petch relationship between the compression yield strength and the grain size was found to depend on the specimen diameter. The effect of feature size was greater than that of grain size. A new model of the relationship between the compression yield strength and the grain size, specimen diameter, and size factor has been built. The predicted results of the model agreed well with the experimental results. The fit of the model was better than that of a model based on the relationship between the compression yield strength and the grain size and specimen diameter only.     

Highly refractive polyimides containing pyridine and sulfur units: synthesis and thermal,mechanical, solubility and optical properties

Two series of isomers containing pyridine and sulfur unit aromatic diamine monomers, 4,4′‐bis(5‐amino‐2‐pyridinylsulfanyl)diphenyl sulfide ( 2a ), 4,4′‐bis(6‐amino‐3‐pyridinylsulfanyl)diphenyl sulfide ( 2b ) and 4,4′‐bis(5‐amino‐6‐methyl‐2‐pyridinylsulfanyl)diphenyl sulfide ( 2c ), 4,4′‐bis(5‐amino‐4‐methyl‐2‐pyridinylsulfanyl)diphenyl sulfide ( 2d ), were designed and synthesized. Aimed at clarifying the structure–property relationships of pyridine‐ and sulfur‐containing high refractive polymers, 2a was polymerized with various dianhydrides to prepare polyimides PI ‐1?PI ‐7 and 2b , 2c , 2d were reacted with 4,4′‐[p ‐thiobis(phenylenesulfanyl)]diphthalic anhydride to prepare polyimides PI ‐8?PI ‐10. The polyimides showed excellent optical properties with average refractive indices ranging from 1.7006 to 1.7620 and birefringence as low as 0.0056. Meanwhile, comparative studies on their properties including solubility, thermal and mechanical, and optical transparency properties were performed. Some property differences of the isomers caused by the sequence changes were found. © 2017 Society of Chemical Industry