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31.
Controlling machining deformation of annular parts is crucial for ensuring the performance of high value products and equipment. For example, during manufacturing of critical parts in aircrafts and spacecrafts, accurate prediction of machining deformation is the basis for guiding the formulation of deformation control strategies. However, due to the complexity of the machining deformation of annular parts, existing methods still have limitations in accurate prediction. To this end, this paper proposes a mechanism informed neural network (MINN) to predict machining deformation of annular parts. MINN is realized by establishing the dual sub-networks structure and using enhanced loss functions with the consideration of the deformation mechanism model characteristics of annular parts. The deformation was decomposed into the axisymmetric portion and the non-axisymmetric portion according to the deformation superposition principle, and modeled separately based on the thin-shell theory and Fourier series. Experiment results showed that the proposed method could predict the machining deformation of annular parts more accurately and stably with a small amount of training data, compared with previous methods.  相似文献   
32.
One-dimensional porous carbons bearing high surface areas and sufficient heteroatom doped functional-ities are essential for advanced electrochemical energy storage devices, especially for developing free-standing film electrodes. Here we develop a porous, nitrogen-enriched, freestanding hollow carbon nanofiber (PN-FHCF) electrode material via filtration of polypyrrole (PPy) hollow nanofibers formed by in situ self-degraded template-assisted strategy, followed by NH3-assisted carbonization. The PN-FHCF retains the freestanding film morphology that is composed of three-dimensional networks from the entanglement of 1D nanofiber and delivers 3.7-fold increase in specific surface area (592 m2·g-1) com-pared to the carbon without NH3 treatment (FHCF). In spite of the enhanced specific surface area, PN-FHCF still exhibits comparable high content of surface N functionalities (8.8%, atom fraction) to FHCF. Such developed hierarchical porous structure without sacrificing N doping functionalities together enables the achievement of high capacity, high-rate property and good cycling stability when applied as self-supporting anode in lithium-ion batteries, superior to those of FHCF without NH3 treatment.  相似文献   
33.
《材料科学技术学报》2019,35(7):1309-1314
Degenerate pattern is a seemingly disordered morphology but it exhibits the inherently ordered crystal connected with tip-splitting and limited stability which makes it difficult to observe in the metallic system. Here we employ (100)[011] orientated planar-front seeds using directional solidification and reveal the fundamental origins of the degenerate pattern growth in an Al-4.5 wt% Cu alloy. We find that the spacing of the tip-splitting (λ) in the degenerate of the alloys followed a power law, λV−0.5, and the frequency (f) of the splitting was related to the growth velocity (V) by ƒ∝V1.5. The dimensionless growth direction (θ/θ0) increased monotonously and approached 0.6 with faster velocity, attributed to its anisotropy in the interface kinetics. Once growth velocity exceeded a threshold, two types of pattern transitions from degenerate to regular dendrites were proposed. One of them exhibited a random and chaotic mode and the other underwent a rotation in growth direction.  相似文献   
34.
Directionally solidified microstructures of Al2O3-Er3Al5O12 eutectic and off-eutectic in situ composite ceramics were explored under abrupt-change pulling rate conditions. Corresponding temperature distributions and interface locations were studied. In eutectic composition, fluctuation of eutectic spacing occurred when the pulling rate increased abruptly. A gradually increase or abrupt increase in eutectic spacing was observed when the pulling rate decreased abruptly. In hypoeutectic and hypereutectic compositions, formation of the primary phases were suppressed when the pulling rate increased abruptly from 10?µm/s to 100?µm/s, while primary phases precipitated when the pulling rate decreased abruptly from 100?µm/s to 10?µm/s. The interface altitude decreased after the pulling rate increased abruptly, but increased after the pulling rate decreased abruptly. The liquid composition restriction (around the eutectic composition) at the eutectic interface plays an important role in the suppression of the primary dendrite and coupled eutectic oxides can be obtained in off-eutectic compositions even under higher solidification rate conditions.  相似文献   
35.
《Ceramics International》2019,45(11):13726-13731
Rod-like ZrB2 crystals were synthesized at 1600 °C in Ar atmosphere by boro/carbothermal reduction using ZrOCl2⋅8H2O, B4C and carbon powders as raw materials. The optimum molar ratio of raw materials required to form pure ZrB2 grains was found to be 2: 1.2: 3. With increase in temperature and subsequent heat preservation stage, ZrB2 powders grew into a rod-like morphology along the c axis. The rod-like ZrB2 grains obtained at 1600 °C have diameters of 0.5–3 μm and high aspect ratios of >8. Effects of molar ratio of raw materials, heating temperature and holding time on the phase composition and final morphology were investigated. Growth mechanism of rod-like ZrB2 grains was also analyzed.  相似文献   
36.
To investigate the formation mechanism of the dendrites glass-ceramics and the effect of TaB2 modifier on the oxidation-inhibition ability of Si-based coatings in aerobic environment with broad temperature region for carbon materials, the Si-based coatings modified with different TaB2 content were fabricated by the liquid phase sintering method. The fabricated coatings and its corresponding composite powders were investigated in dynamic TG aerobic environments up to 1500 ℃. The initial oxidation temperatures of Si-based coatings modified with TaB2 powders are almost completely suppressed to 800 ℃. With the increase of TaB2 phase content, the relative oxygen permeability of the Si-based coatings is significantly reduced, which can be interpreted as the generation of liquid boride, silicide and Ta-Si-B-O compound glass ceramics those can improve the stability of the coating. The formation mechanism of the dendrites glass-ceramics was illustrated.  相似文献   
37.
The measurement of high phase-transition temperature is equally challenging and useful for developing high-temperature materials for critical applications. Pyrometer is a suitable option to measure the phase-transition temperature above 2300 K. In this work, Mo, Ta, and their isomorphous binary alloys are selected as the target system for high-speed pyrometer temperature measurements in the arc-melting setup. The present phase transitions (melting point, solidus, and liquidus) measurements indicate that the MoTa is an isomorphous system with a narrow freezing range (i.e., an average value < 35 K). The results from this present work would change the existing MoTa phase diagram. The Gibbs energy modeling for liquid (L) and BCC_A2 (α) phases of the MoTa system are then performed, including the latest experimental results from this work. The applications of the current experimental methodology could be extended to measure the high phase-transition temperatures in superalloys with significant commercial values.  相似文献   
38.
采用基于优化的误差反向传播(BP)神经网络的机器学习算法建模,提出了考虑材料参数、几何参数等多因素的弯管回弹精确预测和高效控制方法。该方法通过引入非线性惯性权重及遗传算法的杂交算子,改进了粒子群优化(PSO)算法,进而通过改进的PSO算法对BP神经网络进行优化,构建了基于改进的PSO-BP神经网络机器学习回弹预测和补偿模型。以多种规格的铝合金数控弯管构件为对象,将实际生产中不同规格、批次、成形参数下回弹数据作为训练样本,实现了所建机器学习预测模型的应用验证。所建模型获得的预测结果平均相对误差为6.3%,与未优化的BP神经网络等传统模型相比,预测精度最大提高了18.5%,计算时间可从1.5 h缩短至300 s,同时实现了回弹预测与补偿精度以及计算效率的显著提高。  相似文献   
39.
The facial fit of respirators is crucial for determining how effectively respirators may protect users from exposure to airborne contaminants, when their use is required in the workplace. In the Chilean market, all the respirators available have been designed and manufactured using foreign regulations. The aim of this research was to determine the facial dimensions in a sample of Chilean workers (users or potential users of respiratory protective equipment) and the possible mismatch between their anthropometric characteristics and the respirator fit test panels proposed by Los Alamos National Laboratory (LANL) and National Institute for Occupational Safety and Health (NIOSH). An anthropometric survey that included 11 measurements was conducted, based on ISO/TS 16976–2 and ISO 15535 to ensure the highest standards possible, and a total of 474 workers (female: 229, male: 245), aged 18–66 years old participated in the survey. The anthropometric measurements were then contrasted with the fit test panels used in LANL (for half and full facepieces) and NIOSH (Bivariate and Principal component analysis (PCA)), to verify the level of mismatch. The results showed that LANL panels presented a level of mismatch of 11.8% and 21% for the half-facepiece and the full-facepiece, respectively. Considering the NIOSH bivariate and PCA panels, 4.6% and 4.4% of the sample remains without an assigned cell, respectively. It can be concluded that the LANL panels for half and full facepieces do not match the facial dimensions of the Chilean working population. The panels developed by NIOSH and considered by the ISO/TS 16976–2 (bivariate and PCA), are applicable to the Chilean working population.Relevance for the IndustryThis research provides anthropometric measurements of Chilean workers, to determine the dimensions for half- and full-facepiece respirators, which are currently not available. The NIOSH or ISO fit test panels, as opposed to LANL panels, should be used when manufacturing respirators for Chilean workers.  相似文献   
40.
激光立体成形能够实现高性能复杂零件的精确成形,但成形过程中的高温度梯度极易导致残余应力和变形,最终影响构件的几何精度和力学性能。通过搭建基板单边夹持原位热变形测量系统,探究了多道多层TC4钛合金成形件在激光立体成形过程中基板温度、变形的演化规律,分析了不同扫描策略对构件热应力场的影响。研究结果表明,构件的变形发展受其热历史驱使,扫描策略对成形件的热变形具有显著影响。  相似文献   
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