Wear failure of a leaded bronze bearing: Correlation between plant experience and laboratory wear test data

This paper describes an investigation on the failure of a large leaded bronze bearing that supports a nine-ton roller of a plastic calendering machine. At the end of the normal service life of a good bearing, which lasted for seven years, a new bearing was installed. However the new one failed catastrophically within a few days, generating a huge amount of metallic wear debris and causing pitting on the surface of the cast iron roller. Following the failure, samples were collected from both good and failed bearings. The samples were analyzed chemically and their microstructures examined. Both samples were subjected to accelerated wear tests in a laboratory type pin-on-disk apparatus. During the tests, the bearing materials acted as pins, which were pressed against a rotating cast iron disk. The wear behaviors of both bearing materials were studied using weight loss measurement. The worn surfaces of samples and the wear debris were examined by light optical microscope, scanning electron microscope, and energy-dispersive x-ray microanalyzer. It was found that the laboratory pin-on-disk wear data correlated well with the plant experience. It is suggested that the higher lead content (∼18%) of the good bearing compared with 7% lead of the failed bearing helped to establish a protective transfer layer on the worn surface. This transfer layer reduced metal-to-metal contact between the bearing and the roller and resulted in a lower wear rate. The lower lead content of the failed bearing does not allow the establishment of a well-protected transfer layer and leads to rapid wear.     

铜金粉的颜色及其影响因素

利用分光光度计对国内外铜金粉的颜色进行了测试，研究了铜金粉的成分、微观状态对颜色的影响。结果表明：铜金粉颜色可以用色彩三要素进行描述，其中铜金粉的色相只与合金成分有关，而与铜金粉片的大小、形状及粒度分布无关；明度和纯度与铜金粉片在油墨层中定向排列状态、片的大小、形状及粒度分布有关，而与成分无关；合金成分的微小波动不会引起铜金粉色相的明显改变。     

铍青铜倾角传感器及其线性度补偿

用弹性较好的铍青铜材料作为振动元件,设计制作了“三明治”式差动电容检测结构的倾角传感器、给出敏感头结构尺寸,利用弹性力学分析了传感器的力学特性,推导出被测倾角和铍青铜元件偏角的关系。使用单片机,通过软件线性度补偿,提高了倾角传感器的输出线性度。该传感器结构简单,成本低,稳定性好,使用方便,并经过在全量程范围内测试,最大误差为6°。     

商代青铜酒器文化研究

商朝是中国青铜时代的鼎盛时期,以青铜制作的器具众多,其中不乏大量的酒器,从酒器的造型与纹饰可以反应出商当时的一个社会文化背景,即商人好酒。     

浅析商代中后期的器物艺术

商代的器物艺术主要以青铜器为代表,本文从构图方式,虚实关系和结构线的变化三个方面,对商中后期的青铜器艺术进行分析。     

Small Changes,Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B-Site

Two novel transition metal-doped tungsten bronze oxides, Pb_2.15Li_0.85Nb_4.85Ti_0.15O₁₅ (PLNT) and Pb_2.15Li_0.55Nb_4.85W_0.15O₁₅ (PLNW), are synthesized by high-temperature solid-state reactions. The Rietveld method using the high-resolution synchrotron radiation indicates that PLNT and PLNW crystallize in the orthorhombic polar noncentrosymmetric space group, Pmn2₁ (no. 31). As a class of tungsten bronze oxide, PLNT and PLNW retain a unique rigid framework composed of d⁰ transition metal cation (Ti⁴⁺ or W⁶⁺)-doped highly distorted NbO₆ octahedra along with the subsequently generated Pb/LiO₁₂ and PbO₁₅ polyhedra. Interestingly, the d⁰ transition metal-doped tungsten bronzes, PLNT and PLNW, exhibit extremely large second-harmonic generation (SHG) responses of 56 and 67 × KH₂PO₄, respectively. The observed immeasurably strong SHG is mainly attributed to a net polarization originating from the alignment of highly distorted NbO₆ octahedra with doped transition metals in the frameworks. It is believed that doping transition metal cations at the B-site of the tungsten bronze structures should be an innovative strategy to develop novel high-performance nonlinear optical materials.     

CNT对BST陶瓷微波介电性能的影响

采用XRD及SEM研究(Ca0.61Nd0.26)TiO3对微波介质陶瓷Ba4Sm9.33Ti18O54的结构和微波介电性能的影响。获得了一些性能较好的微波介质陶瓷(1–x)Ba4Sm9.33Ti18O54-x(Ca0.61Nd0.26)TiO3,其微波介电性能如下:εr=75,Q·f为8985GHz,τf为–8.2×10–6℃–1(x?=0);εr为75,Q·f为9552GHz,τf为–14.4×10–6℃–1(x?=0.2)。     

旧料生产锡磷青铜带材急冷破鳞开裂原因及其探讨

阐述了在实际生产过程中，因大量使用镀白旧料生产锡磷青铜带材，在急冷破鳞时易出现开裂现象及其产生的原因。根据其特有的生产工艺及特点提出了相应的解决方法。     

偏铌酸铅的制备及介电性能研究

以分析纯PbO和Nb2O5为原料，采用两种不同的烧成工艺（自然冷却和快速冷却）制备了偏铌酸铅，并对其物相、孔隙率和介电性能进行了研究。结果表明：自然冷却可得到菱方相的偏铌酸铅，而快速冷却得到的是主晶相为斜方相的偏铌酸铅；自然冷却时的优化烧成温度是1240℃，此时得到的菱方偏铌酸铅的孔隙率最小（14．03％），相对介电常数值最大（71．97）；快冷获得的斜方偏铌酸铅的相对介电常数值（均值为216）大约是菱方偏铌酸铅（均值为63）的3．4倍。     

添加青铜粉对烧结316L不锈钢组织和性能的影响

研究了添加青铜粉对316L烧结不锈钢的密度、硬度和微观组织的影响。结果表明：添加青铜粉末提高了316L不锈钢的生坯密度。烧结样品的密度和硬度均随青铜粉体积分数的增大而提高，烧结温度升高也有利于316L烧结不锈钢密度和硬度的增大，最佳烧结温度为1200℃左右。当青铜粉的体积分数为30％、烧结温度为1200℃时，316不锈钢的最大相对密度和硬度分别为95．1％和HRB83。添加青铜粉引起的液相烧结使不锈钢颗粒球形化趋势明显，颗粒表面平直化。