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31.
Cryogels based on poly(vinyl alcohol) [PVA] and three types of bioinsertions such as scleroglucan, cellulose microfibers, and zein, respectively, have been prepared using capacity of PVA to crosslink by repeated freezing–thawing cycles. The effect of the incorporation of biopolymers on the properties of PVA cryogel has been studied by using several techniques such as: scanning electron microscopy, differential scanning calorimetry, and Fourier transform infrared studies. The obtained biobased cryogel membranes were subjected to sorption and to diffusion experiments using Crystal Violet (CV), a dye commonly used in the textile industry and in medicine. Image analysis with CIELAB system was used both to monitor the cryogels loading with CV and to gain insight in the dye state into the gel, in correlation with the bioinsertion type and gels morphology. Dye diffusion but also sorption capacity of the cryogels was found to be closely related to the type of biopolymer. In this article the equilibrium (sorption isotherms) and transport properties (diffusion and permeability coefficients) of CV, in/through physical cross‐linked PVA hydrogel membranes with bioinsertions has been reported. The highest efficiency for the CV removal from aqueous solutions was obtained for the PVA/Scl cryogels. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41838. 相似文献
32.
Combining Acoustic Emission and Vibration Technologies Harbors Huge Potential for Material Characterization 下载免费PDF全文
Karl Nienhaus Hermann Wotruba Domenic Boos Simon Klösges Tobias Vraetz Kilian Neubert 《化学工程与技术》2015,38(12):2253-2260
The demand for raw materials is growing worldwide, in step with increasing world population and rising living standards of emerging countries. It is becoming more difficult to exploit primary raw materials because of declining ore grades and increasingly complicated mineralogies. Thus, the efficient and environmentally sustainable exploitation of primary resources using innovative technologies has emerged as an important research field to address these issues. An innovative approach is introduced to optimize process and quality control by combining acoustic emission (AE) and vibration technology. The general feasibility of these two technologies for material recognition and characterization is examined. The new approach was tested to determine whether coal could be distinguished from waste rock. 相似文献
33.
《International Journal of Hydrogen Energy》2020,45(27):14119-14132
The bipolar plate (BP) material should possess contradictory properties. They should also manufacture from low-cost methods and materials. In the current investigation, thermoset-based composite materials reinforced with conductive fillers, and the compression molding process is implemented. In addition to fabricating the bipolar plates (BPs) with and without the flowing channels, alleviating the defects during the molding process is performed. The channels are perfectly formed on the plates with the designed depth of 0.65 mm and 0.5 mm of width. In the meanwhile, we alleviate different molding defects, which spoil the surface appearance and part properties. Regarding the physical properties, the water contact angle is measured to be around 85°. The through-plane electrical conductivity of molded plates showed high values up to 38 S/cm, and the interfacial contact resistance measured to be 18–24 mΩ cm2. The mean value of the flexural strength of the produced samples was equal to 47 MPa, which is almost twice the DOE target (>25 MPa). 相似文献
34.
《岩石力学与岩土工程学报(英文版)》2022,14(4):1221-1231
Characterizing spatial distribution of soil liquefaction potential is critical for assessing liquefaction-related hazards (e.g. building damages caused by liquefaction-induced differential settlement). However, in engineering practice, soil liquefaction potential is usually measured at limited locations in a specific site using in situ tests, e.g. cone penetration tests (CPTs), due to the restrictions of time, cost and access to subsurface space. In these cases, liquefaction potential of soil at untested locations requires to be interpreted from limited measured data points using proper interpolation method, leading to remarkable statistical uncertainty in liquefaction assessment. This underlines an important question of how to optimize the locations of CPT soundings and determine the minimum number of CPTs for achieving a target reliability level of liquefaction assessment. To tackle this issue, this study proposes a smart sampling strategy for determining the minimum number of CPTs and their optimal locations in a self-adaptive and data-driven manner. The proposed sampling strategy leverages on information entropy and Bayesian compressive sampling (BCS). Both simulated and real CPT data are used to demonstrate the proposed method. Illustrative examples indicate that the proposed method can adaptively and sequentially select the required number and optimal locations of CPTs. 相似文献
35.
Yu-yan Yang Lin Fan Jiao Wang Yuan-duo Zhu Xu Li Xin-qi Wang Xu Yan Li Li Yu-jing Zhang Wen-jing Yang Xiao-yuan Yao Xian-liang Wang 《Indoor air》2021,31(5):1391-1401
Household fine particulate matter (PM2.5) pollution greatly impacts residents' health. To explore the current national situation of household PM2.5 pollution in China, a study was conducted based on literature published from 1998 to 2018. After extracting data from the literature in conformity with the requirements, the nationwide household-weighted mean concentration of household PM2.5 (HPL) was calculated. Subgroup analyses of spatial, geographic, and temporal differences were also done. The estimated overall HPL in China was 132.2 ± 117.7 μg/m3. HPL in the rural area (164.3 ± 104.5 μg/m3) was higher than that in the urban area (123.9 ± 122.3 μg/m3). For HPLs of indoor sampling sites, the kitchen was the highest, followed by the bedroom and living room. There were significant differences of geographic distributions. The HPLs in the South were higher than the North in four seasons. The inhaled dose of household PM2.5 among school-age children differed from provinces with the highest dose up to 5.9 μg/(kg·d). Countermeasures should be carried out to reduce indoor pollution and safeguard health urgently. 相似文献
36.
采用硝酸铁与硫脲在溶剂热反应条件下制备FeS2,利用物理浸渍法将FeS2负载至多壁碳纳米管(MWCNTs)上,借助扫描电镜(SEM)、X射线衍射(XRD)、X光电子能谱(XPS)等分析测试手段对制备样品的结构特性进行探究,通过固定床反应器研究模拟烟气氛围下吸附剂对烟气中单质汞的吸附特性。实验考察了不同FeS2负载量、烟气初始汞浓度、床层温度以及O2、NO和SO2对吸附剂脱汞效率的影响。结果表明,制备出的FeS2分散性较好,呈球状晶体,表面均匀覆盖着MWCNTs,成团簇状。当负载量为10%、反应温度为70℃时,FeS2/MWCNTs的吸附效果最好,最高脱除效率能达到100%,60min后脱除效率仍有80.3%。TPD脱附曲线和XPS分析结果进一步表明烟气中的Hg0被氧化成Hg2+以HgS的形式附着在吸附剂表面,证实吸附剂以化学吸附为主。此外,汞脱除效率随初始汞浓度的增加而降低,汞吸附容量却随之增加,60min最高能达到5.1μg/g。酸性气体NO和SO2的存在,占据了吸附剂表面的活性点位,不利于Hg0的吸附,但低浓度NO对吸附剂的整体效果影响不大,抗NO性能较好。 相似文献
37.
For the successful application of boundary lubrication, detailed investigations about the influence of preparation process on molecular films are needed. In this paper, a specially designed device was used for the film preparation. The scanning electron microscope (SEM) combined with atomic force microscope (AFM) was employed to characterize the surface morphology and nanotribological behavior of molecular films. After the liquid phase deposition, molecular films are randomly and densely distributed over Ti-doped diamond-like carbon (Ti-DLC) substrates. Through rigorous surface treatments, island-like molecular films were finally achieved on substrate surfaces. The surface friction of molecular films is obviously lower than that of Ti-DLC surfaces. Then, pin-on-disk tribotests were performed to study the macrofriction behavior of molecular films under different preparation parameters. Based on the orthogonal experiment, the effect of five preparation parameters (solution weight percent, smearing force and processing time of three smearing steps) on initial friction coefficient of molecular films was investigated. The results indicated that the order of significance levels is as follows: processing time of the second smearing step > solution weight percent > processing time of step 1 > processing time of step 3 > smearing force. For the purpose of friction reduction, the appropriate level ranges are 0.75% (Solution), 2.5 N–15 N (Force), 1 min–10 min (Step 1), 1 min–2 min (Step 2) and 1 min, 2 min, 5 min and 15 min (Step 3). The initial friction coefficient under the optimized conditions is around 0.112, and the equilibrium friction coefficient is around 0.162, which is lower than that of unlubricated Ti-DLC substrates. 相似文献
38.
In this study, polypropylene (PP) nonwoven fabric which can be used as topsheet layer of an absorbent hygienic product was modified by natural based antibacterial agents. Antibacterial herbal agents (cinnamaldehyde, geraniol, phenylethyl alcohol) were sprayed by ethanol or applied by means of polylactic acid (PLA) and polycyclohexene oxide (PCHO) based polymers prepared by three different chemical methods. Characterization of synthesized materials was conducted via thermogravimetric analysis (TGA), differential thermal analysis (DTA), and scanning electron microscopy–energy dispersive X–ray spectroscopy (SEM-EDX). Besides characterization, antibacterial and pH buffering performances of antibacterial polymers alone and on PP fabric were tested by antibacterial and pH tests. Effects of antibacterial treatments on air permeability and absorption period of nonwoven fabrics were also analyzed. According to the results, biopolymers changed the thermal stability of PP nonwoven fabric. Antibacterial performances can be ranked as cinnamaldehyde, geraniol, and phenylethyl alcohol from the best. Besides a slight decrease about liquid absorption performance, all of the treated topsheet fabrics are sufficient for an absorbent hygienic product. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48302. 相似文献
39.
Sandrine Gomes Elodie Petit Lawrence Frezet Jean-Marie Nedelec Ameni Gharzouni Sylvie Rossignol Guillaume Renaudin 《Journal of the American Ceramic Society》2020,103(10):5813-5824
The thermal behavior of a model MK-based K-geopolymer was investigated between room temperature and 1400°C in order to evaluate its potentiality for high-temperature applications. The purpose of our study was to monitor the behavior of a geopolymer during a temperature rise in order to better understand its variations with respect to temperature. The works from the present paper focus only changes in the porous network; it follows a first part devoted to variations in the mineral matrix. The results obtained here show that the geopolymer material preserves its porous integrity up to 800°C, while maintaining the reversibility of water exchanges corresponding to about 25 weight percent. Together with the results of part 1, the findings of this study allow us to affirm that geopolymer materials are only very little affected by temperatures up to 800°C, or even 900°C (keeping its mesoporous amorphous structure). 相似文献
40.
Phase behaviour modelling of reservoir fluid is a fundamental step for reservoir simulation. Furthermore, as the complexity of the recovery process increases, the fluid model plays a more important role in the reliability of the simulation outputs. Although the in situ combustion enhanced oil recovery method (ISC) is one of the most complex recovery techniques available in the petroleum engineering literature, for most of the simulation jobs related to this elaborate process only simple and rudimentary fluid characterization layouts are considered. In this work, the principal fluid properties of Athabasca bitumen with regard to the ISC process are recognized, extracted from the literature, validated for consistency, and used for the development of an inclusive and accurate fluid model. Then the fluid model is fully developed while considering the ISC reaction kinetics so that the model has both accuracy, indispensable for phase behaviour modelling, and consistency, essential for the reactions definitions. 相似文献