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31.
William Huddleston Frederick Dynys Alp Sehirlioglu 《Journal of the American Ceramic Society》2020,103(3):1527-1535
Sintering of LiNi0.33Mn0.33Co0.33O2 cathode material was investigated for potential application in all-electric aerospace propulsion systems utilizing new architectural concepts. All-solid-state batteries, while inherently safe, may not reach the high energy density required for next generation propulsion systems. To meet this performance requirement, multifunctionality of sintered active material may achieve systems level weight savings through simultaneous load bearing and electrochemical energy storage performance. The effects of sintering conditions on structural stability, chemistry, densification, grain size, fracture strength and electrical conductivity were quantified for the active cathode material. X-ray diffraction and inductively coupled plasma results indicated the structure and stoichiometry were maintained across the range of processing conditions to facilitate intercalation. Densification was achieved by sintering at 1050°C in ambient atmosphere, but grain coarsening was observed for higher temperatures and longer hold times. Mechanical strength was improved with reduction in porosity, but excessive grain growth decreased strength, providing a maximum of 50 MPa for samples sintered at 1050°C for 10 hours. Electrical conductivity initially improved with densification, but significantly diminished as the microstructure coarsened. The optimal sintering condition of 1050°C maximized mechanical fracture strength and electrical conductivity, with shorter sintering times preferred. 相似文献
32.
针对传统隐伏型导水地质裂缝勘探方法存在勘测精度较差的问题,提出电磁精细探测法探析隐伏型导水地质裂缝。依照屏蔽系数、实测场强和理论场强数据绘制综合曲线图,通过该图获取隐伏型导水地质裂缝所处位置几何阴影范围,采用层析成像法得到网格化的工作面,获取隐伏型导水地质图像。通过图像直接观测隐伏型导水地质工作面裂缝所处位置,在此基础上,观测四个电磁场分量,采用正交电磁场分量计算介质视电阻率,依据计算视电阻率数值和视电阻率分布状态研究裂缝发育情况和裂缝富水程度。结果表明:采用该方法能较为精准地获取隐伏型导水地质裂缝位置。通过裂缝位置进一步检测出隐伏型导水地质裂缝最大发育高度为63.5 m。当视电阻数值不断增加时,隐伏型导水地质裂缝和裂缝富水性逐渐减小,与实际情况较为相符,说明该种方法探析效果较好。 相似文献
33.
为了研究大采高工作面断层破碎带围岩控制技术,采用UDEC分别模拟工作面揭露断层前后围岩应力变化规律、揭露断层时覆岩运移规律。根据模拟结果可知,断层导致工作面应力呈"几"字型分布及顶底板变形量增大。在断层影响区域采用锚网索、单体液压支柱挑棚联合支护取得了良好的效果。 相似文献
34.
K. Abburi Venkata S. Dey H. E. Coules C. E. Truman T. Pirling 《Energy Materials: Materials Science and Engineering for Energy Systems》2018,13(2):492-499
Residual stresses in welds pose a significant threat to the structural integrity of a component, especially in the presence of defects and are required to be accounted for in assessing component safety. Although the R6 assessment procedure suggests various approximate methods for incorporating these effects in defect assessment, most of them are overly conservative and not very cost-effective. A more reliable approach is to characterise the weld residual stresses around a defect and study how they interact with primary load. The current paper analyses the effects of weld residual stresses on the fracture of a dissimilar weld in the presence of defect. The weld is made between modified 9Cr–1Mo steel and 316LN stainless steel using autogenous electron beam welding. A C(T) specimen was extracted from the centre of the weld and a crack introduced in the fusion zone using electro-discharge machining. The residual stresses around the crack were measured on a grid of measurement points at mid-thickness of the C(T) specimen using neutron diffraction on the strain diffractometer SALSA at ILL, Grenoble. The measured residual stresses around the crack-tip were incorporated into a finite element model and the interaction of these with applied load was predicted under fracture. 相似文献
35.
Panos A. Gourgiotis 《Journal of the European Ceramic Society》2018,38(8):3025-3036
The propagation of in-plane shear cracks is investigated in brittle microstructured materials modeled by the constrained Cosserat elasticity. This theory introduces characteristic material lengths in order to describe the scale effects that emerge from the underlying microstructure and has proved to be very effective for modeling complex microstructured materials. An exact solution is obtained based on integral transforms and the Wiener-Hopf technique. Numerical results are presented illustrating the dependence of the stress intensity factor and the energy release rate upon the loading profile, the propagation velocity, and the characteristic material lengths of Cosserat elasticity. It is shown that depending on the Cosserat microstructural lengths the limiting crack propagation velocity can be significantly lower than the classical Rayleigh limit. Moreover, strengthening effects are observed when the characteristic material lengths become comparable to the geometrical lengths of the problem, a behavior that has been experimentally verified in fracture of ceramics. 相似文献
36.
A simple interface fracture test for ceramic environmental barrier coatings (EBCs) on ceramic matrix composites (CMCs) was developed. A variation on the asymmetric double cantilever beam (ADCB) test was proposed so that the interface toughness could be measured in a small specimen of simple shape without applying interlaminar loading to the CMC substrate. The proposed test was applied to an EBC consisting of a mullite layer and Si bond coat on a monolithic SiC substrate. A pre-crack was introduced by pop-in cracking, and then a notch overlapping the pre-crack was machined. The pre-crack was opened by inserting a wedge into the notch. From the critical notch opening displacement the crack starts to propagate, interface toughness is calculated. The measured interface toughness was 4.1?J/m2. Finally, the application range of the test was discussed and suggestions were made for introduction of the notch and pre-crack. 相似文献
37.
采用毛细管流变仪,研究了超高分子量聚乙烯(UHMWPE)/高密度聚乙烯(HDPE)/纳米二氧化硅(SiO2)共混体系,及其对照组的流变行为和挤出过程中的不稳定流动现象,分析了共混物发生鲨鱼皮畸变和整体破裂的临界剪切应力和临界剪切速率的变化情况。结果表明,经过偶联剂改性的纳米SiO2粒子,在PE基质的共混体系中存在一定的界面黏附作用,降低了纳米共混体系的挤出胀大比,弹性特征减轻。这种界面相互作用限制了纳米共混材料在口模区域的黏性流动以及分子链离开口模后的构象恢复,降低了发生流动不稳定现象的临界剪切速率,发生鲨鱼皮畸变的临界剪切应力增大,整体破裂后,形成交替出现"鲨鱼皮-破裂"的振荡性变化外观。 相似文献
38.
39.
为了有效解决某轻型载货车储气罐支架的断裂故障,首先基于建立的储气罐支架有限元模型进行振动特性分析,分析结果表明其前三阶固有频率接均处于发动机激励频率范围之外,不会产生共振。其次测试各种道路的时域载荷,测试结果表明其中角度搓板路的激励频率与储气罐支架第一阶固有频率相接近,从而引起共振,不满足振动特性要求。然后对其进行振动强度分析,分析结果表明其应力水平不达标,其最大应力点与开裂处一致。再对其进行振动疲劳寿命预测分析,分析结果表明其疲劳寿命也不达标,其危险点也与失效位置相同。再采用集成平台对储气罐支架的结构进行优化设计,优化之后其模态频率、振动强度和振动疲劳均符合性能要求,并且其重量也有所减轻,总体优化效果较佳。最后整车试验结果表明优化之后储气罐支架的振动大幅度降低,并且没有发生失效。 相似文献
40.
《Ceramics International》2020,46(13):20751-20768
“Weibull statistics” for strength distribution analysis refers to either the ordinary Weibull distribution function or the Weibull statistical fracture theory. The ordinary Weibull distribution function is an empirical distribution function on an equal footing with other type of classical empirical distributions such as normal and log-normal distributions for fitting the statistical data of various random variables nonexclusive to materials strength. It has no explicit physical meaning and cannot be used for size scaling and prediction of strength. The Weibull statistical fracture theory is a weakest-link statistical fracture model for a solid with the strength distribution of an elemental volume being described by the ordinary Weibull distribution function. It has the capability of size scaling and prediction of strength for specimens with different geometries and different loading modes. The three-parameter Weibull statistical fracture theory in uniaxial flexure of prismatic beams is reformulated and validated by both numerical and real strength experiments of different ceramics. 相似文献