透明叠层结构Ag/MoO_3/Ag阳极对绿光OLED器件性能的影响

本文采用一种结构为Ag/MoO_3/Ag的金属/氧化物/金属(M_1/O/M_2)叠层替代ITO作为OLED器件的阳极,研究Ag/MoO_3/Ag叠层结构变化对于OLED器件电极透过率、亮度、光谱等性能的影响。实验采用真空蒸镀方法制备了一系列器件,器件结构为Ag/MoO_3/Ag/MoO_3(10nm)/NPB(40nm)/Alq_3(60nm)/LiF(1nm)/Al(150nm)。对比器件的电压-电流密度、电压-亮度、光谱特性等数据,表明Ag/MoO_3/Ag的结构为20/20/10(nm)时,器件性能较好。在驱动电压为11V时,其亮度达到18 421cd/m~2,电流效率为2.45cd/A;且因器件中存在微腔效应,其EL光谱蓝移,半高宽变窄。但考虑到530nm处其电极透过率仅为17%,所以经换算该器件实际发光亮度比ITO电极器件更高。该Ag/MoO_3/Ag叠层阳极制作相对简单,经优化后在顶发射和柔性OLED器件方面将具有一定的应用前景。     

新型减反屏蔽膜系的模拟设计

为解决航空条件下复杂外界环境对液晶显示器的各种干扰,本文设计了一种新型减反屏蔽膜系结构,将ITO透明导电膜层作为减反膜系中的一层,使膜系在达到减反效果的同时还具有屏蔽功能,大大降低了ITO作为屏蔽膜层单独使用时在可见光部分的剩余反射率。通过TFCalc光学膜系设计软件进行模拟．结果表明该膜系结构在可见光部分的剩余反射率明显下降,其中最优膜系的平均剩余反射率为0．43％,面电阻率达到11．8Ω／□,使得液晶显示器在航空环境条件下的工作性能有了显著提高。     

基于单片机的全彩OLED静态显示驱动接口电路

针对奇晶公司生产的CMEL CO283QGLD-T型OLED显示模块的特性,以宏晶科技的STC11L60XE单片机为主控制器,进行OLED显示模块与单片机在SPI模式下的硬件接口设计和软件设计,并实现了分辨率为240×320的全彩图片静态显示。所设计的OLED驱动电路具有通用性,且可显示多种测试图片用于中小尺寸OLED的显示性能测试和评定。     

Effects of transparent MPTMS/Ag/MoO3 structure as anode on the performance of green organic light-emitting diodes

A transparent 3-mercaptopropyl trimethoxysilane (MPTMS)/Ag/MoO3 composite anode is introduced to fabricate green organic light-emitting diodes (OLEDs). Effects of the composite anode on brightness and operating voltage of OLEDs are researched. By optimizing the thickness of each layer of the MPTMS/Ag/MoO3 structure, the transmittance of MPTMS/Ag (8 nm)/MoO3 (30 nm) reaches over 75% at about 520 nm. The sheet resistance is 3.78 Ω/□, corresponding to this MPTMS/Ag (8 nm)/MoO3 (30 nm) structure. For the OLEDs with the optimized anode, the maximum electroluminescence (EL) current efficiency reaches 4.5 cd/A, and the maximum brightness is 37 036 cd/m2. Moreover, the OLEDs with the optimized anode exhibit a very low operating voltage (2.6 V) for obtaining brightness of 100 cd/m2. We consider that the improved device performance is mainly attributed to the enhanced hole injection resulting from the reduced hole injection barrier height. Our results indicate that employing the MPTMS/Ag/MoO3 as a composite anode can be a simple and promising technique in the fabrication of low-operating voltage and high-brightness OLEDs.     

眼科准分子激光实时监控能量计

利用激光感生热电电压(LITV)效应制成了激光功率/能量计,它不仅能测量和记录每个脉冲的能量值及实时施加的脉冲总能量等信息,也能记录每个入射脉冲的响应波形,实现了对激光能量的实时监控。用此功率/能量计对248 nm准分子激光器进行模拟实验。测量结果表明,在1~50 Hz重复频率下,激光器输出能量的相对标准偏差在8.6%~10.7%。在模拟屈光手术设置参数下,对193 nm准分子激光器进行测量,表明此激光器输出能量的相对标准偏差在8.3%。将这种激光功率/能量计用于激光近视眼科手术中,对提高激光的切削质量和手术质量有重要意义。     

Research on the impact of spin coating silver nano clusters on the performance of OLED devices

To achieve uniform distribution of silver nano clusters (SNCs) on substrate and reveal its effect on the performance of organic light-emitting diode (OLED), the SNCs incorporated OLED was fabricated and SNCs were coated by multi-step spin coating. Compared with the device without SNCs film, the brightness and current efficiency of the OLED devices with SNCs film were highly raised. The enhancement is attributed to SNCs induced local surface plasmon (LSP) oscillation, which can increase the radiative rate of excitons on Alq₃ molecules.     

Research on flexible silver nanowire electrode for organic light-emitting devices

By spin-coating silver nanowires(AgNWs) and polymethyl methacrylate(PMMA), applying pressure imprint and plasma treatment, we obtained flat Ag NW thin film with a sheet resistance of 20 Ω/sq and a transmittance of 78% at 550 nm with low surface roughness. No significant change in sheet resistance was observed after cyclic bending(bending radius is 5 mm) test and tape test. After 1 000 bending tests, the change rate of sheet resistance was only 8.3%. The organic light-emitting devices(OLEDs) were prepared by using such Ag NW electrodes and a maximum brightness of 5 090 cd/m² was obtained. Compared with the Ag NWs electrode without any treatment, the present Ag NW electrodes have lower sheet resistance and better hole injection. Our results show spin-coated with flat layers, embossed and plasma-treated Ag NW electrodes are suitable for manufacturing flexible organic optoelectronic devices.     

便携式机动车超细颗粒物粒径谱仪研制 #br#

精确测量机动车排放尾气中的超细颗粒物粒径分布, 对于大气污染和人体健康风险评估意义重大。基于之前 研发的单极性荷电器、平板差分电迁移分析仪 (PDMA) 和法拉第杯静电计 (FCE) 等模块, 研制了一款便携式超细颗 粒物粒径谱仪, 可实时监测机动车排放尾气中 20∼500 nm 的超细颗粒物粒径分布。开展了自研粒径谱仪的标定实验, 结果表明该粒径谱仪所测得的粒径峰值与 TSI 3081A/3082 筛选出的 40 nm 和 100 nm 的单粒径颗粒物相差 ±5% 以内, 同时所测得数浓度与毕加索 (Pegasor) 颗粒物数浓度监测仪 (PPS-M) 测得的数浓度相差 ±10%。进而针对不同型号机 动车进行了外场实验, 实验结果表明汽油和柴油机动车排放尾气中的颗粒物数浓度主要集中在小于 40 nm 的粒径范 围。此外在与商业仪器的比对实验中, 自研粒径谱仪测得峰值的中值粒径为 20 nm, 商业化的静电低压撞击器 (ELPI) 测得峰值的中值粒径为 17 nm, 二者相差 15%, 表明二者具有良好的一致性。     

有机酸修饰ITO对OLED器件性能的影响

分别采用二氯苯氧乙酸和溴乙酸对ITO表面进行修饰,研究其对OLED器件(ITO/PVK/ FIrPic:SimCP/TPBi/LiF/Al)性能的影响.结果显示,相较于未修饰的器件,采用二氯苯氧乙酸修饰后的器件最大亮度由673.4 cd/m2提升至1 875.2 cd/m2,同时器件的启亮电压由6.2V降至5.3V.研究发现,有机酸处理能够改变ITO的表面能和功函数,一方面改变ITO和后续膜层的接触性能,影响后续膜层的成膜;另一方面也可以有效减少ITO与有机层间的势垒,提升载流子注入.这种用有机酸修饰ITO阳极的方法工艺简单,能有效降低空穴注入势垒,优化ITO和有机层的接触性能,对器件性能的提升起到一定的促进作用.     

发光层厚度对基于CdSSe/ZnS量子点LED性能的影响

采用粒径约为10 nm的CdSSe/ZnS量子点层作为发光层,制备了叠层结构的量子点发光器件,研究了量子点层厚度对其薄膜形貌及量子点发光二极管性能的影响.原子力显微镜测试结果表明:量子点层过厚时,量子点颗粒发生团聚,且随着厚度的降低,团聚现象减弱;当量子点层厚度和量子点粒径相当时(约为10 nm),量子点呈单层排列且团聚现象基本消失;而量子点层厚度低于10 nm时,薄膜出现孔洞缺陷.器件的电流-电压-亮度等测试结果表明:量子点发光二极管中量子点层厚度与器件的光电特性密切相关,量子点层厚度为10 nm的器件光电性能最优,具有最低的启亮电压4.2V,最高的亮度446 cd/m2及最高的电流效率0.2 cd/A.这种通过控制旋涂转速改变量子点层厚度的方法操作简单、重复性好,对QD-LED的研究具有一定应用价值.