集料组成对次轻混凝土宏观性能影响的研究

研究了集料组成对次轻混凝土宏观性能的影响规律，通过调整集料组成配制出了密度在2200kg／m^3左右，强度大于60MPa的次轻混凝土。结果表明，集料组成能明显地影响次轻混凝土的表观密度、抗压强度、抗拉强度和弹性模量。     

钢管膨胀混凝土力学性能及其膨胀模式的研究

配制出了强度性能和工作性能良好的膨胀混凝土,研究了该种钢管膨胀混凝土的力学性能,分析了钢管限制条件下核心混凝土的膨胀模式。研究结果表明,掺加适量膨胀剂的钢管膨胀混凝土具有较优良的力学性能,其极限承载力比普通钢管混凝土可提高8％左右。     

钢管膨胀混凝土力学性能及膨胀模式的研究

配制出了强度性能和工作性能良好的膨胀混凝土,研究了该种钢管膨胀混凝土的力学性能,分析了钢管限制条件下核心混凝土的膨胀模式。研究结果表明,掺加适量膨胀剂的钢管膨胀混凝土具有较优良的力学性能,其极限承载力比普通钢管混凝土可提高8％左右。     

Effect of corrosive solutions on C-S-H microstructure in portland cement paste with fly ash

By means of ²⁹Si and ²⁷Al magic angle spinning nuclear magnetic resonance (MAS NMR) combined with deconvolution technique, X-ray diffraction (XRD), scanning electron microscopy (SEM) as well as energy dispersive X-ray system(EDX), the effect of 5 wt% corrosive solutions (viz. 5 wt% Na₂SO₄, MgSO₄, Na2SO4+NaCl and Na₂SO₄+NaCl+Na₂CO₃) on C-S-H microstructure in Portland cement containing 30 wt% fly ash was investigated.The results show that, in MgSO₄ solution, Mg²⁺ promotes the decalcification of C-S-H by SO ₄ ^2- ,increasing silicate tetrahedra polymerization and mean chain length (MCL) of C-S-H. However, the substituting degree of Al³⁺ for Si⁴⁺ (Al[4]/Si) in the paste does not change evidently. Effect of Na²SO⁴ solution on C-S-H is not significantly influenced by NaCl solution, while the MCL and Al[4]/Si of C-S-H in fly ashcement paste slightly change. However, the decalcification of C-S-H by SO ₄ ^2- and CO ₃ ^2- attack, as well as the activation of fly ash by SO ₄ ^2- attack will increase the MCL and Al[4]/Si, which are both higher than that under Na₂SO₄ corrosion, MgSO₄ or Na₂SO₄ +NaCl coordination corrosion.     

MDF水泥的碳纤维增强研究

研究了碳纤维作为MDF水泥增强材料的可行性以及它的增强效果．探讨了各种因素对MDF水泥性能的影响,分析了碳纤维增强MDF材料的结构特征．研究结果表明,碳纤维作为MDF水泥的增强材料能够显著提高MDF水泥的抗弯强度、断裂韧性和耐水性能。碳纤维在复合材料中呈三维均匀分布．形成空间网络结构,这是碳纤维增强MDF水泥的主要原因。     

聚羧酸减水剂对不同晶型C3S早期水化放热的影响

采用水化微量热仪研究了不同类型聚羧酸减水剂对不同晶型C3S水化放热特性的影响。结果表明:单斜晶系(M)C3S、三方晶系(R)C3S的水化放热速率峰值相比三斜晶系(T)C3S显著降低,且水化放热峰出现延迟,MC3S的水化放热峰延迟最明显。三种晶型C3S的3d水化放热总量由大到小为:TC3S、MC3S、RC3S。不同分子结构的甲氧基聚乙二醇甲基丙烯酸酯系聚羧酸减水剂,主链越短,支链越长,对TC3S的水化延迟作用越大。乙烯基聚乙二醇醚系聚羧酸减水剂对三种晶型C3S的水化放热过程延迟作用由大到小为:RC3S、MC3S、TC3S。对水化放热曲线进行的Krstulovic-Dabic模型研究表明,C3S的水化过程为NG-D类型水化历程。     

Effects of molecular structure of polycarboxylate-type superplasticizer on the hydration properties of C3S

Effects of polycarboxylate-type superplasticizer(PC) molecular structure on the hydration heat of tricalcium silicate(C3S) paste and polymerization degree of hydration products(C-S-H gel) were researched by using TAM AIR isothermal microcalorimetry(TA) and 29Si nuclear magnetic resonance(NMR).Methoxy polyethylene glycol-methacrylates-based polycarboxylate superplasticizers with different side chain lengths and main chain lengths were employed.PC molecules with shorter main chain or longer side chains caused stronger retardation of C3S early hydration and lesser increase of C3S 3 d hydration degree.NMR measurement indicated that the incorporation of PC increased the hydration degree of C3S paste and the polymerization degree of silicon-oxygen tetrahedron of C-S-H gel.The tendency for C3S 7 d hydration degree to improve was more pronounced while PC molecules with longer main chain or shorter side chain were added.Whereas,PC molecules with longer main chains or longer side chains increased the 7 d polymerization degree of C-S-H gel.     

Effect of curing regime on the distribution of Al3+ coordination in hardened cement pastes

The effect of curing regime on the distribution of Al³⁺ coordination in hardened cement pastes within 28 d were investigated by ²⁹Si and ²⁷Al magic angle spinning (MAS) nuclear magnetic resonance(NMR) with deconvolution technique. The results indicate that the tetrahedral coordination Al³⁺ incorporated in C-S-H structure mainly originate from the Al³⁺ incorporated in the alite and belite phases in the Portland cement. The curing regime of constant temperature of 20 °C is beneficial to the octahedral coordination Al³⁺ transforming to tetrahedral coordination Al³⁺ incorporated in C-S-H structure. However, at curing regime of variable temperature, the temperature rising process is more advantageous to the transformation from ettringite to monosulphate, substitution of Al³⁺ for Si⁴⁺ in the C-S-H structure and the formation of the third aluminate hydrate (TAH) than that at constant temperature of 20 °C. The high temperature of 60 °C in the holding temperature process promotes the decomposition of ettringite, and enhances the consumption of the Al³⁺ incorporated in C-S-H phases and the Al³⁺ in TAH for the monosulphate forming. The temperature decreasing promotes the transformation from monosulphate to ettringite, and increases the consumption of the Al³⁺ incorporated in C-S-H phases, and then increases the quantity of the TAH.     

水泥速凝剂及其机理研究综述

阐述了国内外水泥速凝剂以及新型水泥速凝剂包括液体速凝剂概况,并对国内水泥速凝剂机理研究概况进行了综述。     

MDF水泥的玻璃纤维增强研究

研究了中碱和抗碱玻璃纤维作为ＭＤＦ水泥的增强材料的可行性以及它的增强效果，试图通过向ＭＤＦ水泥中引入玻璃纤维来改善它的耐水性能。研究结果表明：中碱和抗碱玻璃纤维作为ＭＤＦ水泥的增强材料具有较好的耐久性，并能显著提高ＭＤＦ水泥的抗弯强度、断裂韧性和耐水性能；玻璃纤维的Ｌ／Ｄ制约着其掺量Ｖｆ对ＭＤＦ水泥的物理性能的影响，并决定着该材料的结构特征；采用本文介绍的工艺，在制备ＭＤＦ水泥材料时，玻璃纤维长度以５ｍｍ为宜。