铌含量对Fe-Cr-C熔敷金属组织与性能的影响

采用埋弧自动焊的方法制备出不同铌含量的Fe-Cr-Nb-C堆焊层,研究了铌含量对堆焊层微观组织结构和性能的影响,焊接过程中铌和碳发生反应生成NbC,随着铌含量的增加NbC数量增多,尺寸有所增大,堆焊层硬度和耐磨性能先增加后降低.当铌含量增加到一定程度时堆焊层中硬质相M7C3的数量减少,基体含碳量降低,组织软化.试验结果表明,铬含量在15 %左右、碳含量在4 %左右的情况下,铌含量为5 %左右最为合适,Fe-Cr-Nb-C堆焊层表现出优良的综合性能.     

NbC含量对烧结NbC/ASP2080高速钢复合材料组织及性能的影响

为了提升高速钢的红硬性及韧性,通过粉末球磨(碳化物及金属粉末)加真空烧结工艺制备了不同含量的NbC颗粒增强ASP2080高速钢复合材料。利用XRD、SEM、EDS、万能拉伸试验机等对NbC/ASP2080高速钢复合材料的微观组织及力学性能进行了表征分析。结果表明：NbC的添加不会改变复合材料的相结构,并且随着NbC含量的增加,热处理态复合材料的基体晶粒尺寸明显减小;热处理能显著提升复合材料的硬度、抗弯强度及冲击韧性;热处理态复合材料的硬度、抗弯强度及冲击韧性随着NbC含量的增加均出现先增大后减小的趋势。NbC含量为4%时的热处理态复合材料拥有最佳的综合性能,其平均晶粒尺寸为6.52μm,硬度、抗弯强度和冲击韧性分别为71.7 HRC、825.3 MPa、6.75 J/cm²。     

Comparison of plasma sprayed NbB2-NbC coatings obtained by ex-situ and in-situ approaches

NbB₂-NbC composite coatings were fabricated on the surface of TC4 by plasma spraying NbB₂-NbC and Nb-B₄C composite powders. The microstructure and properties of the as-prepared coatings were investigated, and the reaction mechanism of the Nb-B₄C composite powder in the plasma jet and the formation mechanism of the NbB₂-NbC coatings were revealed. During the plasma spraying process, NbB₂-NbC composite powder underwent melting-depositing and no phase transformation occurred. The formation mechanism of the coating by plasma spraying Nb-B₄C composite powder was solid phase diffusion-reaction-melting-deposition, and NbB₂ and NbC were formed in situ by the solid phase diffusion reaction between Nb and B₄C in the plasma jet. The coating obtained by reactive plasma spraying Nb-B₄C composite powder has obvious lamellar structure, low porosity, high density, higher microhardness, good toughness, and better wear resistance compared with the coating prepared by NbB₂-NbC composite powder, which is attributed to the exothermic reaction between Nb and B₄C.     

Comparing ablation properties of NbC and NbC-25 mol.% ZrC coating on SiC-coated C/C composites

In this work, ablation properties of NbC and NbC-25 mol.% ZrC coating, deposited on SiC-coated C/C composites by supersonic atmospheric plasma spraying, were tested by an oxyacetylene torch. Results showed that, for NbC coating, an unexpected smooth liquid film mostly composed of niobium suboxides (such as NbO₂ and NbO), rather than pure Nb₂O₅, generated during ablation for 45 s. Mechanical erosion resulted from the molten SiO₂, and the relatively low viscosity of the outer oxide layer owing to insufficiently high melting point of niobium suboxides were the key factors for the failure mechanism of NbC coating. While NbC–ZrC coating abated for 90 s has a 97.49 and 66.53% decrease of linear and mass ablation rate relative to NbC coating ablated for 45 s, since ZrO₂ hindering the evaporation of SiO₂ droplets, and more thermal-stable Nb–O–Zr liquid film endow (NbC–ZrC)/SiC/C/C composites with an outstanding anti-ablation property.     

锻造工艺对2Cr11Mo1VNbN钢横纵向组织及性能的影响

 为了解决2Cr11Mo1VNbN钢横纵向性能差异大的问题，采用OM、SEM等手段研究了不同墩拔工艺下超(超)临界叶片用2Cr11Mo1VNbN马氏体耐热钢的组织、室温力学性能及短时持久性能。结果表明，增加墩拔次数，对合金纵向的强度、塑性及冲击性能影响不明显；对合金的横向性能的影响主要体现在冲击性能和断面收缩率，当二次墩粗和二次拔长以后，横向冲击性能和断面收缩率明显提升。这主要是因为在经过多道次的墩拔工艺后，大颗粒的一次NbC析出破碎，同时在多次加热过程中进一步回溶，使NbC长度方向尺寸明显降低，降低了裂纹形成和扩展速率，性能得到提升。     

氩弧熔覆原位自生NbC增强镍基复合涂层分析

以碳粉、铌粉和Ni60A粉为原料,利用氩弧熔覆技术在Q345钢基材表面原位合成了NbC增强Ni基复合涂层,应用SEM,XRD对涂层的显微组织和物相进行了分析,并测试了涂层显微硬度和常温耐磨性.结果表明,复合涂层与基体界面无气孔、裂纹,呈冶金结合;涂层组织由γ-Ni,Cr23C6和NbC颗粒相组成.涂层的显微硬度HV0.2达到1 000,较基体提高3倍左右;耐磨性较基体Q345钢提高近11倍.     

Effect of Niobium on the Microstructure and Wear Resistance of Nickel-Based Alloy Coating by Laser Cladding

The nickel-based alloys with different Nb contents were deposited on AISI 1045 carbon steel by laser cladding. The effect of Nb on the microstructures of the nickel-based alloy coatings was investigated using scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. The result show that the microstructures of the Nb-modified nickel-based alloy coatings are mainly composed of γ-Ni dendrites, interdendritic eutectics, CrB type chromium borides, and dispersed NbC particles. It is found that the addition of Nb will lead to the precipitation of the NbC particles and M23C6 type carbides instead of the M7C3, and M23C6 type carbides can be observed in the Nb-free nickel-based alloy coating. The microhardness and wear resistance of the coatings increase with the increase of Nb contents. The improvement of the wear resistance of the Nb-modified nickel-based alloy coatings is attributed to the microstructural change and phase variation.     

激光熔覆(Ni60+NbC)+h-BN@Cu涂层组织与性能研究

目的 通过添加铜包覆六方氮化硼(h-BN@Cu)粉末,改善激光熔覆Ni基NbC涂层的性能。方法 采用激光熔覆技术,使用添加不同质量分数铜包覆六方氮化硼的镍基碳化铌复合粉末,在45钢基体表面沉积镍基复合涂层。利用扫描电子显微镜(SEM)和X射线衍射(XRD)设备,研究h-BN@Cu对Ni60/NbC的激光熔覆镍基复合涂层微观结构的影响,利用显微硬度计和布鲁克UMT-2摩擦磨损试验机及白光干涉模块,测量熔覆层的显微硬度、摩擦磨损系数和磨痕宽度。结果 熔覆层中的主相为Ni-Cr-Fe,除此之外还存在FeNi3、CrB、M7C3、NbC、M23C6、Cr2Nb等多种相。研究发现,添加的润滑相h-BN@Cu与硬质相NbC会发生部分分解,Nb原子和B原子进入熔池,与熔池中的Cr原子反应,生成CrB、Cr2Nb等,这些金属间化合物具有硬度高、耐磨性好等特点。当h-BN@Cu的质量分数为10%时,熔覆层的显微硬度为650HV1.0,摩擦系数为0.4,磨痕宽度为0.406 mm。结论 相比于不添加h-BN@Cu的Ni60/NbC熔覆层,添加h-BN@Cu的Ni60/NbC熔覆层的平均硬度略微下降,但熔覆层硬质相分布更加均匀,此时硬度仍为45钢基体硬度的3.1倍,摩擦系数降低约27%,磨痕宽度减小约21%。     

316L不锈钢表面NbC涂层的制备与性能评价

目的探究NbC涂层作为惰性涂层在模拟体液中的耐腐蚀性能及血液相容性能,并为NbC涂层作为生物惰性涂层改善316L不锈钢心血管支架的表面性能提供参考依据。方法采用物理气相沉积法制备NbC涂层,并通过优化工艺参数改善涂层性能。采用扫描电子显微镜(SEM)、原子力显微镜(AFM)、X射线衍射仪(XRD)、纳米压痕仪和原位纳米划痕仪,对涂层的微观结构及性能进行研究。采用循环伏安法对涂层的耐腐蚀性能进行表征。采用血小板粘附实验对涂层的血小板粘附行为进行了评价。结果制备的涂层具有结合性能强和致密度高等优点。随着基体温度的升高,NbC涂层的力学性能、耐腐蚀性能及血小板粘附特性均得到明显改善,硬度及弹性模量分别由(12.5±0.2)GPa和(213±0.8)GPa上升到(24.5±0.4)GPa和(275±1.1) GPa,自腐蚀速率优化明显,由8.76×10~(-6)A/cm~2降到1.98×10~(-8)A/cm~2。结论 NbC涂层在模拟体液中具备与316L不锈钢相当的稳定性,但其腐蚀速率远低于316L不锈钢,血小板粘附数量及变形较基体316L不锈钢得到显著改善,有望成为改善316L不锈钢表面性能的惰性涂层。     

间接碳还原法生产铌时原料粒度对还原周期的影响

研究了间接碳还原生产铌时原料粒度对还原周期的影响。结果表明：原料粒度是影响还原周期的主要因素，合理Ｎｂ２Ｏ５与ＮｂＣ的粒度，可以加快还原反应速度，使还原周期从平均２６小时降至１６小时。