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采用双螺杆熔融共混工艺路线,通过选用合适牌号的聚甲基丙烯酸甲酯及ABS为基本原料,通过控制合适共混工艺条件,制备了一系列不同配比的聚甲基丙烯酸甲酯/ABS塑料合金材料。采用电子万能试验机、悬臂梁冲击实验机等测试手段对合金的力学性能进行了研究,结果表明:聚甲基丙烯酸甲酯/ABS合金材料的拉伸强度随聚甲基丙烯酸甲酯含量的增加而增大,断裂伸长率随着聚甲基丙烯酸甲酯含量的增加而减小,缺口冲击强度随聚甲基丙烯酸甲酯含量的增加而减小。 相似文献
65.
Anja S. GoldmannLeonie Barner Michael KauppAndrew P. Vogt Christopher Barner-Kowollik 《Progress in Polymer Science》2012,37(7):975-984
Modular ligation strategies for the functionalization of polymeric microspheres provide new perspectives for their applications in material science. In the current trend article we highlight variable synthetic procedures for generating functional microspheres via orthogonal modular conjugation chemistries. An overview of the different surface chemistries available is provided, followed by surface-sensitive characterization techniques relevant for the microparticles. Finally, we explore future trends in modular orthogonal modification approaches on microparticles and provide an outlook on the perspectives that the field of surface-modification of polymeric microparticles holds. 相似文献
66.
Antoine Debuigne Marie HurtgenChristophe Detrembleur Christine JérômeChristopher Barner-Kowollik Thomas Junkers 《Progress in Polymer Science》2012,37(7):1004-1030
The current review focuses on the relevance and practical benefit of interpolymer radical coupling methods. The latter are developing rapidly and constitute a perfectly complementary macromolecular engineering toolbox to the controlled radical polymerization techniques (CRP). Indeed, all structures formed by CRP are likely to be prone to radical coupling reactions, which multiply the available synthetic possibilities. Basically, the coupling systems can be divided in two main categories. The first one, including the atom transfer radical coupling (ATRC), silane radical atom abstraction (SRAA) and cobalt-mediated radical coupling (CMRC), relies on the recombination of macroradicals produced from a dormant species. The second one, including atom transfer nitroxide radical coupling (ATNRC), single electron transfer nitroxide radical coupling (SETNRC), enhanced spin capturing polymerization (ESCP) and nitrone/nitroso mediated radical coupling (NMRC), makes use of a radical scavenger in order to promote the conjugation of the polymer chains. More than a compilation of macromolecular engineering achievements, the present review additionally aims to emphasize the particularities, synthetic potential and present limitations of each system. 相似文献
67.
《国际聚合物材料杂志》2012,61(8):691-711
ABSTRACT The equilibrium ground state geometric parameters of N,N,N′,N′,-tetraoxaloylsulphanilamide (Ligand I), N,N-dioxaloylbenzenesulpony-N′,N′,-dioxaloylthiocarbazide (Ligand II) and p-N,N-dioxaloylaminobenzene-N′,N′-dioxaloylbenzenesulphonyloxamide (Ligand III) as polyfunctional ligands were investigated theoretically using AM1-MO method. The expected biradicals formed after gamma radiolysis for each ligand can be detected. The radiation protection of the PMMA matrix from gamma rays, using the biradicals formed of ligands (I), (II), and (III), can be considered theoretically. The structure of the protected chains formed after recombination of two symmetric chains with biradical are theoretically modelled, because in the reaction medium the chain of PMMA formed is asymmetric. All interpretations concerning the ground state properties of the protected chains are qualitative. The thionyl, phenyl, and benzenesulphonyl biradicals are more efficient than carbonyl, thioamides, and sulphonyl biradicals as indicated from the MO-results, molecular weight investigation, and infrared spectroscopy. The protection of PMMA by the formed biradicals is confrmed by proton NMR spectroscopy. 相似文献
68.
SiO2 and Si3N4, are usually used to mask the selected portions during etching of silicon in anisotropic etchants like KOH but polymers are expected to be very good alternative to SiO2 and Si3N4 as masking materials for MEMS applications. An adherent spin coated PMMA layer is reported to work as a mask material. It is a low temperature process, cheaper and films can be easily deposited and removed. One of the problems in its use is its adhesion to the substrate. Our previous experience in the field made us feel that sputtered PMMA will act as better mask because of its better adhesion to silicon. In the present article, a comparative study of spin coated PMMA with sputtered PMMA as an etch mask for silicon micromachining is reported. Structural and adhesive characteristics of the films are determined and compared with those available in the literature. These films deposited on silicon wafer were exposed to anisotropic etchant, KOH, to estimate the masking behavior. The maximum masking time of 32 min in 20 wt.% KOH at 80 °C was obtained for spin coated PMMA samples, which were prebaked at 90 °C. Masking time of sputter deposited PMMA films was found to be 300 min under similar conditions such as 20 wt.% KOH at 80 °C. This masking time is sufficient for fabrication of various MEMS structures, thus indicating candidature of sputtered PMMA as masking material. Various properties of the films are discussed and compared with the ones obtained through literature. 相似文献
69.
选择两组分玻璃化温度较远的PEO/PMMA以及玻璃化温度相近的SAN/PMMA两个均相共混体系为研究对象 ,考察了组分组成对共混物α内耗峰峰高、峰宽以及温频关系的影响 .结果表明 ,共混物α内耗峰峰高及温频关系介于纯组分之间 ,随组分组成有规律地变化 ;PEO/PMMA体系的弛豫谱明显地比纯组分的宽 ,而SAN/PMMA体系的弛豫谱宽度跟纯组分的相差不多 .认为由于PEO/PMMA两组分的玻璃化温度相差甚远 ,组成涨落造成玻璃化温度及弛豫时间的分布变宽 ,因而弛豫谱也很宽 相似文献
70.
Plasticized polymer electrolytes composed of poly(methylmethacrylate) (PMMA) as the host, propylene carbonate (PC) or ethylene carbonate (EC) as a plasticizer and LiX (X: CF3SO3− or N(CF3SO2)2−) as a salt were prepared by the solution cast technique. Impedance spectroscopy was performed in the temperature range between 303 and 383 K. In this paper, we report the electrical properties of polymer electrolytes with different lithium salts and plasticizers. The polymer electrolytes investigated exhibited high ionic conductivity at room temperature in the range of 10− 6 to 10− 4 S cm− 1. The temperature dependence studies showed that the samples were ionic conductors and seemed to obey the Vogel-Tamman-Fulcher (VTF) rule. FTIR spectroscopy studies confirmed the polymer-salt interaction. 相似文献